Startseite Synergistic effects of hierarchical porous structure, acidity and nickel metal for hydro-liquefaction of thermal extracts from lignite over Ni/ZSM-5
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Synergistic effects of hierarchical porous structure, acidity and nickel metal for hydro-liquefaction of thermal extracts from lignite over Ni/ZSM-5

  • Ning Li , Shibiao Ren EMAIL logo , Tao Jiang , Jingchong Yan , Zhicai Wang , Zhiping Lei , Chunxiu Pan , Shigang Kang , Zhanku Li und Hengfu Shui EMAIL logo
Veröffentlicht/Copyright: 31. Mai 2022
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International Journal of Chemical Reactor Engineering
Aus der Zeitschrift International Journal of Chemical Reactor Engineering Band 20 Heft 12

Abstract

Hydro-liquefaction of the thermal extracts (HPC) from lignite was investigated over ZSM-5 and Ni/ZSM-5 with hierarchical pores or not. The thermal extracts dissolved (HPC-S) and deposited (HPC-D) at room temperature were prepared to compare their hydro-liquefaction performances. Combined to the hydrogenation properties of ZSM-5 and Ni/ZSM-5 catalysts for tetralin as a model compound, the roles of the porous structure, acidity and hydrogenation component in Ni/ZSM-5 for hydro-liquefaction of HPC were investigated. A synergy of the porous structures, nickel metal and acidity for hydro-liquefaction of HPC-S over Ni/ZSM-5 catalyst was found. During hydro-liquefaction, it is essential for the presence of nickel in the catalyst, since the parts of the benzene rings in HPC-S are first saturated by hydrogen under the role nickel. Then a certain acidity especially Brønsted acid is required in the catalyst to open the saturated benzene rings. Since there are the macromolecular organic compounds in the HPC-S, the hierarchical porous structures are required in the catalyst to promote the hydro-liquefaction performance due to their improvement on the mass transfer diffusion efficiency.

Keywords: hierarchical pores; hydro-liquefaction; lignite; Ni/ZSM-5; thermal extracts
Corresponding authors: Shibiao Ren and Hengfu Shui, School of Chemistry and Chemical Engineering, Anhui Province Key Laboratory of Coal Clean Conversion and High Valued Utilization, Anhui University of Technology, Ma’anshan, Anhui 243002, China, E-mail: ,

Funding source: National Natural Science Foundation of China

Award Identifier / Grant number: 21776001

Award Identifier / Grant number: 21808002

Award Identifier / Grant number: 21875001

Award Identifier / Grant number: 21878001

Award Identifier / Grant number: 21978002

Award Identifier / Grant number: 22008001

Award Identifier / Grant number: 22078002

  1. Author contributions: All the authors have accepted responsibility for the entire content of this submitted manuscript and approved submission.

  2. Research funding: This work was supported by the National Natural Science Foundation of China (Grants 21978002, 21878001, 22078002, 21776001, 21875001, 21808002 and 22008001).

  3. Conflict of interest statement: The authors declare no conflicts of interest regarding this article.

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Received: 2021-12-17
Accepted: 2022-05-16
Published Online: 2022-05-31

© 2022 Walter de Gruyter GmbH, Berlin/Boston

Artikel in diesem Heft

  1. Frontmatter
  2. Articles
  3. Performance of Pd catalyst supported on trimetallic nanohybrid Zr–Al–La in hydrogenation of ethylanthraquinone
  4. Enhanced degradation of Rhodamine B dye by Fenton/peracetic acid and photo-Fenton/peracetic acid processes
  5. Optimization of electrocoagulation process for treatment of rice grain-based biodigester distillery effluent using surface response methodology approach
  6. Numerical simulation of collision removal of inclusion in swirling flow tundish
  7. Fabrication of superhydrophobic and flame-retardant polyethylene terephthalate fabric through a fluorine-free layer-by-layer technique
  8. Investigation on the atomization characteristics and structure parameters of alcohol-based fuel in small stove
  9. Metal-exchanged phosphotungstate nanoparticles with improved acidity as the catalyst for esterification of glycerol with acetic acid
  10. Synergistic effects of hierarchical porous structure, acidity and nickel metal for hydro-liquefaction of thermal extracts from lignite over Ni/ZSM-5
  11. A novel equilibrium optimized double-loop control scheme for unstable and integrating chemical processes involving dead time
https://doi.org/10.1515/ijcre-2021-0296
Schlagwörter für diesen Artikel
hierarchical pores; hydro-liquefaction; lignite; Ni/ZSM-5; thermal extracts

Artikel in diesem Heft

  1. Frontmatter
  2. Articles
  3. Performance of Pd catalyst supported on trimetallic nanohybrid Zr–Al–La in hydrogenation of ethylanthraquinone
  4. Enhanced degradation of Rhodamine B dye by Fenton/peracetic acid and photo-Fenton/peracetic acid processes
  5. Optimization of electrocoagulation process for treatment of rice grain-based biodigester distillery effluent using surface response methodology approach
  6. Numerical simulation of collision removal of inclusion in swirling flow tundish
  7. Fabrication of superhydrophobic and flame-retardant polyethylene terephthalate fabric through a fluorine-free layer-by-layer technique
  8. Investigation on the atomization characteristics and structure parameters of alcohol-based fuel in small stove
  9. Metal-exchanged phosphotungstate nanoparticles with improved acidity as the catalyst for esterification of glycerol with acetic acid
  10. Synergistic effects of hierarchical porous structure, acidity and nickel metal for hydro-liquefaction of thermal extracts from lignite over Ni/ZSM-5
  11. A novel equilibrium optimized double-loop control scheme for unstable and integrating chemical processes involving dead time
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