Startseite CFD simulation of ultrasonic atomization pyrolysis reactor: the influence of droplet behaviors and solvent evaporation
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CFD simulation of ultrasonic atomization pyrolysis reactor: the influence of droplet behaviors and solvent evaporation

  • Jian Wang , Jichuan Wu , Shouqi Yuan und Wei-Cheng Yan EMAIL logo
Veröffentlicht/Copyright: 8. Februar 2021
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Abstract

Previous work showed that particle behaviors in ultrasonic atomization pyrolysis (UAP) reactor have a great influence on the transport and collection of particles. In this study, the effects of droplet behaviors (i.e. droplet collision and breakage) and solvent evaporation on the droplet size, flow field and collection efficiency during the preparation of ZnO particles by UAP were investigated. The collision, breakage and solvent evaporation conditions which affect the droplet size distribution and flow pattern were considered in CFD simulation based on Eulerian-Lagrangian method. The results showed that droplet collision and breakage would increase the droplet size, broaden the droplet size distribution and hinder the transport of droplets. Solvent evaporation obviously changed the flow pattern of droplets. In addition, both droplet behaviors and solvent evaporation reduced the collection efficiency. This study could provide detail information for better understanding the effect of droplet behaviors and solvent evaporation on the particle production process via UAP reactor.


Corresponding author: Wei-Cheng Yan, School of Chemistry and Chemical Engineering, Jiangsu University, Zhenjiang, Jiangsu, 212013, China; and Research Center of Fluid Machinery Engineering and Technology, Jiangsu University, Zhenjiang, Jiangsu, 212013, China, E-mail:
Jian Wang and Jichuan Wu contributed equally to this work.

Award Identifier / Grant number: 21808088

Award Identifier / Grant number: 2019M650104

Funding source: Innovation and Entrepreneurship program of Jiangsu province of China

Award Identifier / Grant number: 2018

Award Identifier / Grant number: 2020

Funding source: startup funding for high-level talent of Jiangsu University of China

Award Identifier / Grant number: 18JDG022

Funding source: Natural Science Foundation of Jiangsu Province of China

Award Identifier / Grant number: BK20180868

Acknowledgements

Acknowledgements are also given to the China Academy of Engineering Physics and the high-performance computing center in Jiangsu University for the platform supports in simulation.

  1. Author contributions: All the authors have accepted responsibility for the entire content of this submitted manuscript and approved submission.

  2. Research funding: The authors acknowledge the support from the National Natural Science Foundation of China (21808088), the Innovation and Entrepreneurship program of Jiangsu province of China (2018, 2020), the Natural Science Foundation of Jiangsu Province of China (BK20180868), the China Postdoctoral Science Foundation (2019M650104), and the startup funding for high-level talent of Jiangsu University of China (18JDG022).

  3. Conflict of interest statement: The authors declare no conflicts of interest regarding this article.

References

Brutin, D., and V. Starov. 2018. “Recent Advances in Droplet Wetting and Evaporation.” Chemical Society Reviews 47 (2): 558–85, https://doi.org/10.1039/C6CS00902F.Suche in Google Scholar

Chen, B., B. Ge, S. Fu, Q. Li, X. Chen, L. Li, J. Wang, Z. Yang, J. Ding, W. Fan, B. Mao, and W. Shi. 2020. “Ex-situ Flame Co-doping of Tin and Tungsten Ions in TiO2 Nanorod Arrays for Synergistic Promotion of Solar Water Splitting.” Chemical Engineering Science 226: 115843, https://doi.org/10.1016/j.ces.2020.115843.Suche in Google Scholar

Christopher, P., and S. Linic. 2008. “Engineering Selectivity in Heterogeneous Catalysis: Ag Nanowires as Selective Ethylene Epoxidation Catalysts.” Journal of the American Chemical Society 130 (34): 11264–5, https://doi.org/10.1021/ja803818k.Suche in Google Scholar

Du, X., and J. He. 2011. “Spherical Silica Micro/nanomaterials with Hierarchical Structures: Synthesis and Applications.” NANOHL 3 (10): 3984–4002, https://doi.org/10.1039/C1NR10660K.Suche in Google Scholar

Habibzadeh, S., O. Zabeida, A. Argoitia, R. Sargent, J. Klemberg-Sapieha, J. Chaouki, and L. Martinu. 2018. “Conformal Multilayer Photocatalytic Thin Films on Fine Particles by Atmospheric Pressure Fluidized Bed Chemical Vapor Deposition.” Industrial & Engineering Chemistry Research 57 (31): 10345–53, https://doi.org/10.1021/acs.iecr.8b00756.Suche in Google Scholar

Hokenek, S., and J. N. Kuhn. 2012. “Methanol Decomposition over Palladium Particles Supported on Silica: Role of Particle Size and Co-feeding Carbon Dioxide on the Catalytic Properties.” ACS Catalysis 2 (6): 1013–9, https://doi.org/10.1021/cs200689k.Suche in Google Scholar

Hong, Y., C. Li, B. Yin, D. Li, Z. Zhang, B. Mao, W. Fan, W. Gu, and W. Shi. 2018. “Promoting Visible-Light-Induced Photocatalytic Degradation of Tetracycline by an Efficient and Stable beta-Bi2O3@g-C3N4 Core/Shell Nanocomposite.” Chemical Engineering Journal 338: 137–46, https://doi.org/10.1016/j.cej.2017.12.108.Suche in Google Scholar

Khatami, N., O. Ilegbusi, and L. Trakhtenberg. 2015. “Mathematical Modeling and Experimental Validation of Mixed Metal Oxide Thin Film Deposition by Spray Pyrolysis.” Materials Sciences and Applications 06: 68–77, https://doi.org/10.4236/msa.2015.61009.Suche in Google Scholar

Lenggoro, I. W., T. Hata, F. Iskandar, M. M. Lunden, and K. Okuyama. 2011. “An Experimental and Modeling Investigation of Particle Production by Spray Pyrolysis Using a Laminar Flow Aerosol Reactor.” Journal of Materials Research 15 (3): 733–43, https://doi.org/10.1557/JMR.2000.0106.Suche in Google Scholar

Lin, H., C. P. Huang, W. Li, C. Ni, S. I. Shah, and Y.-H. Tseng. 2006. “Size Dependency of Nanocrystalline TiO2 on its Optical Property and Photocatalytic Reactivity Exemplified by 2-chlorophenol.” Applied Catalysis B 68 (1): 1–11, https://doi.org/10.1016/j.apcatb.2006.07.018.Suche in Google Scholar

Liu, J., Y. Zhang, M. I. Ionescu, R. Li, and X. Sun. 2011. “Nitrogen-doped Carbon Nanotubes with Tunable Structure and High Yield Produced by Ultrasonic Spray Pyrolysis.” Applied Surface Science 257 (17): 7837–44, https://doi.org/10.1016/j.apsusc.2011.04.041.Suche in Google Scholar

Lu, Z., F. Chen, M. He, M. Song, Z. Ma, W. Shi, Y. Yan, J. Lan, F. Li, and P. Xiao. 2014. “Microwave Synthesis of a Novel Magnetic Imprinted TiO2 Photocatalyst with Excellent Transparency for Selective Photodegradation of Enrofloxacin Hydrochloride Residues Solution.” Chemical Engineering Journal 249: 15–26, https://doi.org/10.1016/j.cej.2014.03.077.Suche in Google Scholar

Murdoch, M., G. I. N. Waterhouse, M. A. Nadeem, J. B. Metson, M. A. Keane, R. F. Howe, J. Llorca, and H. Idriss. 2011. “The Effect of Gold Loading and Particle Size on Photocatalytic Hydrogen Production from Ethanol over Au/TiO2 Nanoparticles.” Nature Chemistry 3 (6): 489–92, https://doi.org/10.1038/nchem.1048.Suche in Google Scholar

O’Rourke, P. J. 1981. Collective Drop Effects on Vaporizing Liquid Sprays. NM (USA): Los Alamos National Lab.Suche in Google Scholar

O’Rourke, P. J., and A. A. Amsden. 1987. “The TAB Method for Numerical Calculation of Spray Droplet Breakup.” SAE International.10.4271/872089Suche in Google Scholar

Ranz, W. E., and W. R. Marshall. 1952a. “Evaporation from Drops.” Chemical Engineering Progress 48 (3): 141–6.Suche in Google Scholar

Ranz, W. E., and W. R. Marshall. 1952b. “Evaporation from Drops, Part I.” Chemical Engineering Progress 48 (3): 173–80.Suche in Google Scholar

Rudolf, R., B. Friedrich, S. Stopić, I. Anžel, S. Tomić, and M. Čolić. 2012. “Cytotoxicity of Gold Nanoparticles Prepared by Ultrasonic Spray Pyrolysis.” Journal of Biomaterials Applications 26 (5): 595–612, https://doi.org/10.1177/0885328210377536.Suche in Google Scholar

Shao, M., A. Peles, and K. Shoemaker. 2011. “Electrocatalysis on Platinum Nanoparticles: Particle Size Effect on Oxygen Reduction Reaction Activity.” Nano Letters 11 (9): 3714–9, https://doi.org/10.1021/nl2017459.Suche in Google Scholar

Shi, W.-D., J. Wang, S. You, and W.-C. Yan. 2019. “Numerical Simulation of Particle Focusing Dynamics of DNA-Laden Fluids in a Microtube.” Chemical Engineering Science 209: 115213, https://doi.org/10.1016/j.ces.2019.115213.Suche in Google Scholar

Shi, W., Y. Yan, and X. Yan. 2013. “Microwave-assisted Synthesis of Nano-Scale BiVO4 Photocatalysts and Their Excellent Visible-Light-Driven Photocatalytic Activity for the Degradation of Ciprofloxacin.” Chemical Engineering Journal 216: 740–6, https://doi.org/10.1016/j.cej.2012.10.071.Suche in Google Scholar

Somorjai, G. A., and Y. Li. 2010. Introduction to Surface Chemistry and Catalysis. Hoboken, NJ: John Wiley & Sons.Suche in Google Scholar

Stopić, S., B. Friedrich, T. Volkov Husovic, and K. Raic. 2010. “Mechanism and Kinetics of Nanosilver Formation by Ultrasonic Spray Pyrolysis-Progress Report after Successful Up-Scaling (Part 1).” Metall 64: 474–7.Suche in Google Scholar

Suh, W. H., and K. S. Suslick. 2005. “Magnetic and Porous Nanospheres from Ultrasonic Spray Pyrolysis.” Journal of the American Chemical Society 127 (34): 12007–10, https://doi.org/10.1021/ja050693p.Suche in Google Scholar

Tsung, C.-K., J. N. Kuhn, W. Huang, C. Aliaga, L.-I. Hung, G. A. Somorjai, and P. Yang. 2009. “Sub-10 nm Platinum Nanocrystals with Size and Shape Control: Catalytic Study for Ethylene and Pyrrole Hydrogenation.” Journal of the American Chemical Society 131 (16): 5816–22, https://doi.org/10.1021/ja809936n.Suche in Google Scholar

Wagemaker, M., W. J. H. Borghols, and F. M. Mulder. 2007. “Large Impact of Particle Size on Insertion Reactions. A Case for Anatase LixTiO2.” Journal of the American Chemical Society 129 (14): 4323–7, https://doi.org/10.1021/ja067733p.Suche in Google Scholar

Wang, J., F. Feng, C. Wang, W.-C. Yan, and W. Shi. 2020a. “Experimental and Numerical Study of the Ultrasonic Atomization Pyrolysis Process toward Mass Production of Photocatalysts.” Industrial & Engineering Chemistry Research 59 (25): 11777–89, https://doi.org/10.1021/acs.iecr.0c00925.Suche in Google Scholar

Wang, Y., F. Zhang, S. Yuan, K. Chen, X. Wei, and D. Appiah. 2020b. “Effect of URANS and Hybrid RANS-Large Eddy Simulation Turbulence Models on Unsteady Turbulent Flows inside a Side Channel Pump.” Journal of Fluids Engineering 142 (6), https://doi.org/10.1115/1.4045995.Suche in Google Scholar

Widiyastuti, W., W.-N. Wang, I. W. Lenggoro, F. Iskandar, and K. Okuyama. 2011. “Simulation and Experimental Study of Spray Pyrolysis of Polydispersed Droplets.” Journal of Materials Research 22 (7): 1888–98, https://doi.org/10.1557/jmr.2007.0235.Suche in Google Scholar

Xu, X., X. Shen, G. Zhu, L. Jing, X. Liu, and K. Chen. 2012. “Magnetically Recoverable Bi2WO6–Fe3O4 Composite Photocatalysts: Fabrication and Photocatalytic Activity.” Chemical Engineering Journal 202: 521–31, https://doi.org/10.1016/j.cej.2012.06.104.Suche in Google Scholar

Yan, W.-C., Z.-H. Luo, Y.-H. Lu, and X.-D. Chen. 2012a. “A CFD-PBM-PMLM Integrated Model for the Gas–Solid Flow Fields in Fluidized Bed Polymerization Reactors.” AIChE Journal 58 (6): 1717–32, https://doi.org/10.1002/aic.12705.Suche in Google Scholar

Yan, W.-C., Y. Shen, S. You, S. Sim, Z.-H. Luo, Y. Tong, and C.-H. Wang. 2018. “Model-based Downdraft Biomass Gasifier Operation and Design for Synthetic Gas Production.” Journal of Cleaner Production 178, https://doi.org/10.1016/j.jclepro.2018.01.009.Suche in Google Scholar

Yan, Y., X. Liu, W. Fan, P. Lv, and W. Shi. 2012b. “InVO4 Microspheres: Preparation, Characterization and Visible-Light-Driven Photocatalytic Activities.” Chemical Engineering Journal 202: 310–6, https://doi.org/10.1016/j.cej.2012.05.102.Suche in Google Scholar

Yi, J., J. Liao, K. Xia, Y. Song, J. Lian, X. She, Y. Liu, S. Yuan, F. Dong, H. Xu, and H. Li. 2019. “Integrating the Merits of Two-Dimensional Structure and Heteroatom Modification into Semiconductor Photocatalyst to Boost NO Removal.” Chemical Engineering Journal 370: 944–51, https://doi.org/10.1016/j.cej.2019.03.182.Suche in Google Scholar

Yu, Y., K. Ma, R. Zhuang, K. Wu, Q. Liao, S. Zhong, H. Yue, C. Liu, S. Tang, and B. Liang. 2019. “Hydroxyl-mediated Formation of Highly Dispersed SnO2/TiO2 Heterojunction via Pulsed Chemical Vapor Deposition to Enhance Photocatalytic Activity.” Industrial & Engineering Chemistry Research 58 (32): 14655–63, https://doi.org/10.1021/acs.iecr.9b02360.Suche in Google Scholar

Zhang, Z., C.-C. Wang, R. Zakaria, and J. Y. Ying. 1998. “Role of Particle Size in Nanocrystalline TiO2-based Photocatalysts.” Journal of Physical Chemistry B 102 (52): 10871–8, https://doi.org/10.1021/jp982948+.10.1021/jp982948+Suche in Google Scholar

Zhao, Y., and L. Jiang. 2009. “Hollow Micro/Nanomaterials with Multilevel Interior Structures.” Advances in Materials 21 (36): 3621–38, https://doi.org/10.1002/adma.200803645.Suche in Google Scholar

Zhu, Z., P. Huo, Z. Lu, Y. Yan, Z. Liu, W. Shi, C. Li, and H. Dong. 2018. “Fabrication of Magnetically Recoverable Photocatalysts Using g-C3N4 for Effective Separation of Charge Carriers through like-Z-scheme Mechanism with Fe3O4 Mediator.” Chemical Engineering Journal 331: 615–25, https://doi.org/10.1016/j.cej.2017.08.131.Suche in Google Scholar

Received: 2020-11-25
Accepted: 2021-01-23
Published Online: 2021-02-08

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