Startseite Experimental research on the cook-off energy release of Al/PTFE mixed powder in closed container
Artikel
Lizenziert
Nicht lizenziert Erfordert eine Authentifizierung

Experimental research on the cook-off energy release of Al/PTFE mixed powder in closed container

  • Zepeng Duan , Shenghai Xiang , Enling Tang ORCID logo EMAIL logo , Chuang Chen und Yafei Han
Veröffentlicht/Copyright: 28. September 2020

Abstract

To evaluate the reactive energy release of the Al/Polytetrafluoroethylene (PTFE) mixed powder (Al and PTFE with a mass percentage of 26.5%/73.5%). Based on the traditional formula, three kinds of Al/PTFE test samples with different dosages (4, 6.5, and 9 g) were mixed. By using the self-designed airtight container, and combining with the overpressure sensor, the transient optical fiber pyrometer, and the infrared thermography. The overpressure , the visible light radiation temperature in the closed container, and the infrared light radiant temperature of the container’s outer wall have been obtained by real-time measurements during the process of cooking off, and the reaction products are analyzed by X-ray energy spectrum (EDS) and X- ray diffraction (XRD). The experimental results show that most of the solid products of Al/PTFE powder in the closed container are AlF3 and a small number of intermediate carbon compositions. The released energy during the firing process of the active material Al/PTFE increases with the increase of the mixing amount; The bake-off energy of active material Al/PTFE mixture per unit mass in a closed container is about 10.2 kJ/g, and when the oxygen content in the closed container is sufficient, active material Al/PTFE per unit mass releases more energy.


Corresponding author: Enling Tang, School of Equipment Engineering, Shenyang Ligong University, Shenyang 110159, China, E-mail:

Award Identifier / Grant number: 11472178

Funding source: Foundation of National Key Laboratory of Shock Wave and Detonation Physics

Award Identifier / Grant number: 11802182

Award Identifier / Grant number: 2019-ZD-0262

Acknowledgments

The research was supported by National Science Foundation of China (11472178, 11802182) and Liaoning Province Natural Fund Guidance Plan (2019-ZD-0262), Foundation of National Key Laboratory of Shock Wave and Detonation Physics (Grant No. 6142A03182009) to provide fund for conducting experiments.

  1. Author contribution: All the authors have accepted responsibility for the entire content of this submitted manuscript and approved submission.

  2. Research funding: The research was supported by National Science Foundation of China (11472178, 11802182) and Liaoning Province Natural Fund Guidance Plan (2019-ZD-0262), Foundation of National Key Laboratory of Shock Wave and Detonation Physics (Grant No. 6142A03182009) to provide fund for conducting experiments.

  3. Conflict of interest statement: The authors declare no conflicts of interest regarding this article.

  4. Data availability: The data that support the findings of this study are available from the corresponding author upon reasonable request.

References

Alexander, K., K. Gibson, and B. Baudler. 1996. “Development of the Variable Confinement Cook-off Test.” Discover the World’s Research. 9 (4).Suche in Google Scholar

Catalano, E., R. Mc Guire, E. Lee, E. Wrenn, and J. Walton. 1976. “The Thermal Decomposition and Reaction of Confined Explosives.” In The 6th International Detonation Symposium, 214–22. CA: Symposium on Combustion.Suche in Google Scholar

Feng, C., R. Zhang, and L. Chen. 2004. “The Cook-off Test and its Numerical Simulation of RDX.” Energetic Materials 12 (4): 193–8.Suche in Google Scholar

Hu, X., and C. Feng. 1998. “Study on Design of the Cook-off Test for Explosives Used in In-Line System.” Journal of Beijing Institute of Technology (Social Sciences Edition) 18 (5): 268–71.Suche in Google Scholar

Huston, M. R., and T. R. Sippel. 2019. “Confined Flame Propagation of Al/PTFE Mechanically Activated Composites.” Combustion and Flame 203: 83–91, https://doi.org/10.1016/j.combustflame.2018.08.024.Suche in Google Scholar

Kappagantula, K., and M. L. Pantoya. 2012. “Experimentally Measured Thermal Transport Properties of Aluminum–Polytetrafluoroethylene Nanocomposites with Graphene and Carbon Nanotube Additives.” International Journal of Heat and Mass Transfer 55 (4): 817–24, https://doi.org/10.1016/j.ijheatmasstransfer.2011.10.026.Suche in Google Scholar

Li, W. F., Y. G. Yu, and R. Ye. 2018. “Effects of Charge Size on Slow Cook-Off Characteristics of AP/HTPB Composite Propellant in Base Bleed Unit.” Propellants, Explosives, Pyrotechnics 43 (4): 404–12, https://doi.org/10.1002/prep.201700270.Suche in Google Scholar

Pakulak, J. M. 1984. “USA Small-Scale Cook-off Bomb(SCB) Test.” In Minutes of 21th Department of Defense Explosives Safety Board Explosives, 539–48.Suche in Google Scholar

Rubio, M. A., I. E. Gunduz, L. J. Groven, T. R. Sippel, C. W. Han, R. R. Unocic, V. Ortalan, and S. F. Son. 2017. “Microexplosions and Ignition Dynamics in Engineered Aluminum/polymer Fuel Particles.” Combustion and Flame 176: 162–71, https://doi.org/10.1016/j.combustflame.2016.10.008.Suche in Google Scholar

Sippel, T. R., S. F. Son, and L. J. Groven. 2014. “Aluminum Agglomeration Reduction in a Composite Propellant Using Tailored Al/PTFE Particles.” Combustion and Flame 161 (1): 311–21, https://doi.org/10.1016/j.combustflame.2013.08.009.Suche in Google Scholar

Sippel, T. R., S. F. Son, L. J. Groven, S. Zhang, and E. L. Dreizin. 2015. “Exploring Mechanisms for Agglomerate Reduction in Composite Solid Propellants with Polyethylene Inclusion Modified Aluminum.” Combustion and Flame 162 (3): 846–54, https://doi.org/10.1016/j.combustflame.2014.08.013.Suche in Google Scholar

Wang, X., R. Dai, and J. Tu. 2001. “Cookoff Tests of Booster Explosives.” Initiators & Pyrotechnics (02): 6–8.Suche in Google Scholar

Wenfeng, L., Y. Yonggang, Y. Rui and Y. Yang. 2017. “Simulation of Cook-Off for AP/HTPB Composition Propellant in Base Bleed Unit at Different Heating Rates.” Explosion and Shock Waves (1): 46–52.Suche in Google Scholar

Wilson, E., M. Gross, E. Washburn, D. Wooldridge, J. and S. Barry. 2010. “Cookoff Results of Sub-scale Hazard Division 1.3 Propellant Samples.” ADA532227.Suche in Google Scholar

Yang, J. L., S. P. Wang, and H. X. Chen. 2016. “Effect of Interface Thermal Resistance on Ignition of Reactive Material by a Hot Particle.” International Journal of Heat and Mass Transfer 97: 146–56, https://doi.org/10.1016/j.ijheatmasstransfer.2016.01.070.Suche in Google Scholar

Yi, J. H., F. Q. Zhao, R. Z. Hu, L. Xue, and S. Y. Xu. 2010. “Thermal Safety Study on TEGDN/NG/NC Gun Propellant.” Journal of Energetic Materials 28 (4): 285–98, https://doi.org/10.1080/07370651003785695.Suche in Google Scholar

Yoh, J. J. 2006. “High-end Modeling and Simulation of Cookoff of HMX-Based Energetic Materials.” Lecture Notes In Computer Science-2006: 484–90, https://doi.org/10.1007/11751649_53.Suche in Google Scholar

Zinn, J., and C. L. Mader. 1960. “Thermal Initiation of Explosives.” Journal of Applied Physics 31 (2): 323–8, https://doi.org/10.1063/1.1735565.Suche in Google Scholar

Received: 2020-04-28
Accepted: 2020-09-12
Published Online: 2020-09-28

© 2020 Walter de Gruyter GmbH, Berlin/Boston

Heruntergeladen am 3.10.2025 von https://www.degruyterbrill.com/document/doi/10.1515/ijcre-2020-0072/html
Button zum nach oben scrollen