Abstract
To evaluate the reactive energy release of the Al/Polytetrafluoroethylene (PTFE) mixed powder (Al and PTFE with a mass percentage of 26.5%/73.5%). Based on the traditional formula, three kinds of Al/PTFE test samples with different dosages (4, 6.5, and 9 g) were mixed. By using the self-designed airtight container, and combining with the overpressure sensor, the transient optical fiber pyrometer, and the infrared thermography. The overpressure , the visible light radiation temperature in the closed container, and the infrared light radiant temperature of the container’s outer wall have been obtained by real-time measurements during the process of cooking off, and the reaction products are analyzed by X-ray energy spectrum (EDS) and X- ray diffraction (XRD). The experimental results show that most of the solid products of Al/PTFE powder in the closed container are AlF3 and a small number of intermediate carbon compositions. The released energy during the firing process of the active material Al/PTFE increases with the increase of the mixing amount; The bake-off energy of active material Al/PTFE mixture per unit mass in a closed container is about 10.2 kJ/g, and when the oxygen content in the closed container is sufficient, active material Al/PTFE per unit mass releases more energy.
Funding source: National Natural Science Foundation of China
Award Identifier / Grant number: 11472178
Funding source: Foundation of National Key Laboratory of Shock Wave and Detonation Physics
Award Identifier / Grant number: 11802182
Funding source: Liaoning Province Natural Fund Guidance Plan
Award Identifier / Grant number: 2019-ZD-0262
Acknowledgments
The research was supported by National Science Foundation of China (11472178, 11802182) and Liaoning Province Natural Fund Guidance Plan (2019-ZD-0262), Foundation of National Key Laboratory of Shock Wave and Detonation Physics (Grant No. 6142A03182009) to provide fund for conducting experiments.
Author contribution: All the authors have accepted responsibility for the entire content of this submitted manuscript and approved submission.
Research funding: The research was supported by National Science Foundation of China (11472178, 11802182) and Liaoning Province Natural Fund Guidance Plan (2019-ZD-0262), Foundation of National Key Laboratory of Shock Wave and Detonation Physics (Grant No. 6142A03182009) to provide fund for conducting experiments.
Conflict of interest statement: The authors declare no conflicts of interest regarding this article.
Data availability: The data that support the findings of this study are available from the corresponding author upon reasonable request.
References
Alexander, K., K. Gibson, and B. Baudler. 1996. “Development of the Variable Confinement Cook-off Test.” Discover the World’s Research. 9 (4).Suche in Google Scholar
Catalano, E., R. Mc Guire, E. Lee, E. Wrenn, and J. Walton. 1976. “The Thermal Decomposition and Reaction of Confined Explosives.” In The 6th International Detonation Symposium, 214–22. CA: Symposium on Combustion.Suche in Google Scholar
Feng, C., R. Zhang, and L. Chen. 2004. “The Cook-off Test and its Numerical Simulation of RDX.” Energetic Materials 12 (4): 193–8.Suche in Google Scholar
Hu, X., and C. Feng. 1998. “Study on Design of the Cook-off Test for Explosives Used in In-Line System.” Journal of Beijing Institute of Technology (Social Sciences Edition) 18 (5): 268–71.Suche in Google Scholar
Huston, M. R., and T. R. Sippel. 2019. “Confined Flame Propagation of Al/PTFE Mechanically Activated Composites.” Combustion and Flame 203: 83–91, https://doi.org/10.1016/j.combustflame.2018.08.024.Suche in Google Scholar
Kappagantula, K., and M. L. Pantoya. 2012. “Experimentally Measured Thermal Transport Properties of Aluminum–Polytetrafluoroethylene Nanocomposites with Graphene and Carbon Nanotube Additives.” International Journal of Heat and Mass Transfer 55 (4): 817–24, https://doi.org/10.1016/j.ijheatmasstransfer.2011.10.026.Suche in Google Scholar
Li, W. F., Y. G. Yu, and R. Ye. 2018. “Effects of Charge Size on Slow Cook-Off Characteristics of AP/HTPB Composite Propellant in Base Bleed Unit.” Propellants, Explosives, Pyrotechnics 43 (4): 404–12, https://doi.org/10.1002/prep.201700270.Suche in Google Scholar
Pakulak, J. M. 1984. “USA Small-Scale Cook-off Bomb(SCB) Test.” In Minutes of 21th Department of Defense Explosives Safety Board Explosives, 539–48.Suche in Google Scholar
Rubio, M. A., I. E. Gunduz, L. J. Groven, T. R. Sippel, C. W. Han, R. R. Unocic, V. Ortalan, and S. F. Son. 2017. “Microexplosions and Ignition Dynamics in Engineered Aluminum/polymer Fuel Particles.” Combustion and Flame 176: 162–71, https://doi.org/10.1016/j.combustflame.2016.10.008.Suche in Google Scholar
Sippel, T. R., S. F. Son, and L. J. Groven. 2014. “Aluminum Agglomeration Reduction in a Composite Propellant Using Tailored Al/PTFE Particles.” Combustion and Flame 161 (1): 311–21, https://doi.org/10.1016/j.combustflame.2013.08.009.Suche in Google Scholar
Sippel, T. R., S. F. Son, L. J. Groven, S. Zhang, and E. L. Dreizin. 2015. “Exploring Mechanisms for Agglomerate Reduction in Composite Solid Propellants with Polyethylene Inclusion Modified Aluminum.” Combustion and Flame 162 (3): 846–54, https://doi.org/10.1016/j.combustflame.2014.08.013.Suche in Google Scholar
Wang, X., R. Dai, and J. Tu. 2001. “Cookoff Tests of Booster Explosives.” Initiators & Pyrotechnics (02): 6–8.Suche in Google Scholar
Wenfeng, L., Y. Yonggang, Y. Rui and Y. Yang. 2017. “Simulation of Cook-Off for AP/HTPB Composition Propellant in Base Bleed Unit at Different Heating Rates.” Explosion and Shock Waves (1): 46–52.Suche in Google Scholar
Wilson, E., M. Gross, E. Washburn, D. Wooldridge, J. and S. Barry. 2010. “Cookoff Results of Sub-scale Hazard Division 1.3 Propellant Samples.” ADA532227.Suche in Google Scholar
Yang, J. L., S. P. Wang, and H. X. Chen. 2016. “Effect of Interface Thermal Resistance on Ignition of Reactive Material by a Hot Particle.” International Journal of Heat and Mass Transfer 97: 146–56, https://doi.org/10.1016/j.ijheatmasstransfer.2016.01.070.Suche in Google Scholar
Yi, J. H., F. Q. Zhao, R. Z. Hu, L. Xue, and S. Y. Xu. 2010. “Thermal Safety Study on TEGDN/NG/NC Gun Propellant.” Journal of Energetic Materials 28 (4): 285–98, https://doi.org/10.1080/07370651003785695.Suche in Google Scholar
Yoh, J. J. 2006. “High-end Modeling and Simulation of Cookoff of HMX-Based Energetic Materials.” Lecture Notes In Computer Science-2006: 484–90, https://doi.org/10.1007/11751649_53.Suche in Google Scholar
Zinn, J., and C. L. Mader. 1960. “Thermal Initiation of Explosives.” Journal of Applied Physics 31 (2): 323–8, https://doi.org/10.1063/1.1735565.Suche in Google Scholar
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Artikel in diesem Heft
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- Micro-emulsion synthesis of La1 − xCrxFeO3 nanoparticles: effect of Cr doping on ferroelectric, dielectric and photocatalytic properties
- Experimental and theoretical evaluation of zinc recovery from zinc oxide ore: process optimization and simulation using Aspen Plus software
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- Synthesis, characterization and photocatalytic activity evaluation of WO3, TiO2 and WO3/TiO2 supported on zeolite faujasite
- Usage of textile dyes BB41 and BR46 for microscopic examination of filamentous bacteria in activated sludge reactor: a new staining method
- Titania-termite hill composite as a heterogeneous catalyst: preparation, characterization, and performance in transesterification of waste frying oil
- Short Communications
- Easy removal of nitrate and phosphate anions from water by low cost chitosan and activated charcoal
- Synthesis of Ag decorated Zn-Co/TiO2 nanocomposites
- Determination of catastrophic sets of a tubular chemical reactor by two-parameter continuation method