Startseite Adsorption/desorption, Kinetics and Equilibrium Studies for the Uptake of Cu(II) and Zn(II) onto Banana Peel
Artikel
Lizenziert
Nicht lizenziert Erfordert eine Authentifizierung

Adsorption/desorption, Kinetics and Equilibrium Studies for the Uptake of Cu(II) and Zn(II) onto Banana Peel

  • Sanjay Bhagat , Vidyadhar V. Gedam und Pranav Pathak EMAIL logo
Veröffentlicht/Copyright: 18. März 2020
Veröffentlichen auch Sie bei De Gruyter Brill

Abstract

The paper addresses an exploration of the removal efficiency of banana peel ftrip(BP) towards copper and zinc ions from water and to optimize the factors involved in this adsorption process. In this sense, process optimization, kinetics, and equilibrium studies were performed in a batch process. The kinetics shows that the equilibrium reached in 60 minutes and the adsorption is favored above pH 5. The BP was firstly characterized by proximate analysis, FTIR, BET surface area, and SEM. The highest adsorption capacity for Langmuir isotherm for Cu(II) and Zn(II) onto BP was observed to be 61.728 mg/g and 55.56 mg/g respectively. Finally, the regeneration of BP was also studied up to 5 cycles. Thus, BP showed excellent adsorption characteristics during the uptake of Cu(II) and Zn(II) from wastewater effluent and can be used as low-cost agricultural waste biomass as an adsorbent.

References

Acharya, J., U. Kumar, and P. M. Rafi. 2018. “Removal of Heavy Metal Ions from Wastewater by Chemically Modified Agricultural Waste Material as Potential Adsorbent-A Review.” International Journal of Current Engineering and Technology 8 (3): 526–30.10.14741/ijcet/v.8.3.6Suche in Google Scholar

Albarellia, J. Q., R. B. Rabeloa, D. T. Santosb, M. M. Beppua, and M. A. A. Meireles. 2011. “Effects of Supercritical Carbon Dioxide on Waste Banana Peels for Heavy Metal Removal.” The Journal of Supercritical Fluids 58 (3): 343–51.10.1016/j.supflu.2011.07.014Suche in Google Scholar

Amel, K., M. Hassan, and S. Ouacil. 2011. “An Experimental Parametric and Kinetics Study of Cu(II) Retention by Orange Peels as Adsorbent.” Chemical Engineering Transaction 25: 447–52.Suche in Google Scholar

Caetano, L., G. Ferreira, P. M. Padilha, M. J. Saeki, L. F. Zara, M. A. U. Martines, and G. R. Castro. 2011. “Banana Peel Applied to the Solid Phase Extraction of Copper and Lead from River Water: Preconcentration of Metal Ions with a Fruit Waste.” Industrial & Engineering Chemistry Research 50 (6): 3446–51.10.1021/ie101499eSuche in Google Scholar

Carolyn, P., C. Elsa, U. Johana, and M. M. Jesús. 2011. “Eco-friendly Technologies Based on Banana Peel Use for the Decolourization of the Dyeing Process Wastewater.” Waste and Biomass Valorization 2 (1): 77–86.10.1007/s12649-010-9052-4Suche in Google Scholar

Castro, R. S. D., L. Caetano, G. Ferreira, P. M. Padilha, M. J. Saeki, L. F. Zara, M. A. U. Martines, and G. R. Castro. 2011. “Banana Peel Applied to the Solid Phase Extraction of Copper and Lead from River Water: Preconcentration of Metal Ions with a Fruit Waste.” Industrial & Engineering Chemistry Research 50 (6): 3446–51.10.1021/ie101499eSuche in Google Scholar

Cong, P., C. Li-Yuan, S. Yu-Xia, M. Xiao-Bo, and T. Chong-Jian. 2018. “Thermodynamics, Kinetics and Mechanism Analysis of Cu(II) Adsorption by In-situ Synthesized Struvite Crystal.” Journal of Central South University 25: 1033−1042.10.1007/s11771-018-3803-ySuche in Google Scholar

El-Ashtoukhy, E.-S. Z., N. K. Amina, and O. Abdelwahab. 2008. “Removal of Lead (II) and Copper (II) from Aqueous Solution Using Pomegranate Peel as a New Adsorbent.” Desalination 223 (1–3): 162–73.10.1016/j.desal.2007.01.206Suche in Google Scholar

Fakhre, N. A., and B. M. Ibrahim. 2018. “The Use of New Chemically Modified Cellulose for Heavy Metal Ion Adsorption.” Journal of Hazardous Materials 343: 324–31.10.1016/j.jhazmat.2017.08.043Suche in Google Scholar PubMed

Feng, N., X. Guo, and S. Liang. 2009. “Adsorption Study of Copper (II) by Chemically Modified Orange Peel.” Journal of Hazardous Materials 164 (2–3): 1286–92.10.1016/j.jhazmat.2008.09.096Suche in Google Scholar PubMed

Foo, K. Y., and B. H. Hameed. 2010. “Insights into the Modeling of Adsorption Isotherm Systems.” Chemical Engineering Journal 156: 2–10.10.1016/j.cej.2009.09.013Suche in Google Scholar

Gao, X., L. Wu, Q. Xu, W. Tian, Z. Li, and N. Kobayashi. 2018. “Adsorption Kinetics and Mechanisms of Copper Ions on Activated Carbons Derived from Pinewood Sawdust by Fast H3PO4 Activation.” Environmental Science and Pollution Research 25: 7907–15.10.1007/s11356-017-1079-7Suche in Google Scholar PubMed

Gedam, V. V., P. Raut, A. Chahande, and P. Pathak. 2019. “Kinetic, Thermodynamics and Equilibrium Studies on the Removal of Congo Red Dye Using Activated Teak Leaf Powder.” Journal of Applied Water Science 9 (3): 55.10.1007/s13201-019-0933-9Suche in Google Scholar

Habib, A., N. Islam, A. Islam, and A. M. S. Alam. 2007. “Removal of Copper from Aqueous Solution Using Orange Peel, Sawdust and Bagasse.” Pakistan Journal of Analytical and Environmental Chemistry 8 (1): 21–25.Suche in Google Scholar

Hang, Y., Y. Si, Q. Zhou, H. Yin, A. Wang, and A. Cao. 2019. “Morphology-controlled Synthesis of Calcium Titanate Particles and Adsorption Kinetics, Isotherms, and Thermodynamics of Cd(II), Pb(II), and Cu(II) Cations.” Journal of Hazardous Materials 380: 120789.10.1016/j.jhazmat.2019.120789Suche in Google Scholar PubMed

Hang, Y., H. Yin, A. Wang, L. Shen, Y. Feng, and R. Liu. 2014. “Preparation of Titanate Whiskers Starting from Metatitanic Acid and Their Adsorption Performances for Cu(II), Pb(II), and Cr(III) Ions.” Water, Air, and Soil Pollution 225: 1–14.10.1007/s11270-014-2095-6Suche in Google Scholar

Huang, K., S. Jiao, and H. Zhu (2013). “Removal of Cadmium from Aqueous Solution by Garlic Peel.” International conference on Materials for Renewable Energy and Environment (ICMREE), 2013. Chengdu, IEEE. 2: 604–07.Suche in Google Scholar

Inagaki, C. S., T. d. O. Caretta, R. V. d. S. Alfaya, and A. A. d. S. Alfaya. 2013. “Mexerica Mandarin (Citrus Nobilis) Peel as a New Biosorbent to Remove Cu(II), Cd(II), and Pb(II) from Industrial Effluent.” Desalination and Water Treatment 51: 5537–46.10.1080/19443994.2012.759156Suche in Google Scholar

IS:1350. (July 2006) Indian Standard “Methods of test for coal and coke PART I : proximate analysis (Second Revision) IS : 1350”.Suche in Google Scholar

Khormaei, M., B. Nasernejad, M. Edrisi, and T. Eslamzadeh. 2007. “Copper Biosorption from Aqueous Solutions by Sour Orange Residue.” Journal of Hazardous Materials 149 (2): 269–74.10.1016/j.jhazmat.2007.03.074Suche in Google Scholar PubMed

Kong, Z., X. Li, J. Tian, J. Yang, and S. Sun. 2014. “Comparative Study on the Adsorption Capacity of Raw and Modified Litchi Pericarp for Removing Cu(II) from Solutions.” Journal of Environmental Management 134: 109–16.10.1016/j.jenvman.2014.01.007Suche in Google Scholar PubMed

Lasheen, M. R., N. S. Ammar, and H. S. Ibrahim. 2012. “Adsorption/desorption of Cd(II), Cu(II) and Pb(II) Using Chemically Modified Orange Peel: Equilibrium and Kinetic Studies.” Solid State Sciences 14 (2): 202–10.10.1016/j.solidstatesciences.2011.11.029Suche in Google Scholar

Li, X., D. Zhang, F. Sheng, and H. Qing. 2018. “Adsorption Characteristics of Copper (II), Zinc (II) and Mercury (II) by Four Kinds of Immobilized Fungi Residues.” Ecotoxicology and Environmental Safety 147: 357–66.10.1016/j.ecoenv.2017.08.058Suche in Google Scholar PubMed

Liang, S., X. Guo, N. Feng, and Q. Tian. 2009. “Adsorption of Cu2+ and Cd2+ from Aqueous Solution by Mercapto-acetic Acid Modified Orange Peel.” Colloids and Surfaces B: Biointerfaces 73 (1): 10–14.10.1016/j.colsurfb.2009.04.021Suche in Google Scholar PubMed

Liang, S., X. Guo, and Q. Tian. 2011. “Adsorption of Pb2+ and Zn2+ from Aqueous Solutions by Sulfured Orange Peel.” Desalination 275 (1–3): 212–16.10.1016/j.desal.2011.03.001Suche in Google Scholar

Liang, S., X. Guo, and Q. Tian. 2013. “Adsorption of Pb2+, Cu2+ and Ni2+ from Aqueous Solutions by Novel Garlic Peel Adsorbent.” Desalination and Water Treatment 51: 7166–71.10.1080/19443994.2013.769919Suche in Google Scholar

Liu, C., H. H. Ngo, W. Guo, and K.-L. Tung. 2012. “Optimal Conditions for Preparation of Banana Peels, Sugarcane Bagasse and Watermelon Rind in Removing Copper from Water.” Bioresource Technology 119: 349–154.10.1016/j.biortech.2012.06.004Suche in Google Scholar

Liu, X., Z.-Q. Chen, B. Han, C.-L. Su, Q. Han, and W.-Z. Chen. 2018. “Biosorption of Copper Ions from Aqueous Solution Using Rape Straw Powders: Optimization, Equilibrium and Kinetic Studies.” Ecotoxicology and Environmental Safety 150: 251–59.10.1016/j.ecoenv.2017.12.042Suche in Google Scholar

Mahdi, Z., Q. J. Yu, and A. E. Hanandeh. 2018. “Investigation of the Kinetics and Mechanisms of Nickel and Copper Ions Adsorption from Aqueous Solutions by Date Seed Derived Biochar.” Journal of Environmental Chemical Engineering 6 (1): 1171–81.10.1016/j.jece.2018.01.021Suche in Google Scholar

Mallampati, R., and S. Valiyaveettil. 2013. “Apple Peels - A Versatile Biomass for Water Purification?” ACS Applied Materials & Interfaces 5 (10): 4443–49.10.1021/am400901eSuche in Google Scholar

Marín, A. B. P., J. F. Ortuno, M. I. Aguilar, V. F. Meseguer, J. Sáez, and M. Lloréns. 2010. “Use of Chemical Modification to Determine the Binding of Cd(II), Zn(II) and Cr(III) Ions by Orange Waste.” Biochemical Engineering Journal 53 (1): 2–6.10.1016/j.bej.2008.12.010Suche in Google Scholar

Mishra, V., C. Balomajumder, and V. K. Agarwal. 2010. “Biosorption of Zn (II) onto the Surface of Non-living Biomasses: A Comparative Study of Adsorbent Particle Size and Removal Capacity of Three Different Biomasses.” Water, Air, & Soil Pollution 211 (1–4): 489–500.10.1007/s11270-009-0317-0Suche in Google Scholar

Ning-chuan, F., and G. Xue-yi. 2012. “Characterization of Adsorptive Capacity and Mechanisms on Adsorption of Copper, Lead and Zinc by Modified Orange Peel.” Transactions of Nonferrous Metals Society of China 22: 1224–31.10.1016/S1003-6326(11)61309-5Suche in Google Scholar

Ning-Chuan, F., G. Xue-Yi, and L. Sha. 2010. “Enhanced Cu(II) Adsorption by Orange Peel Modified with Sodium Hydroxide.” Transactions of Nonferrous Metals Society of China 22: s146–s152.10.1016/S1003-6326(10)60030-1Suche in Google Scholar

Njokua, V. O., and B. H. Hameed. 2011. “Preparation and Characterization of Activated Carbon from Corncob by Chemical Activation with H3PO4 for 2,4-dichlorophenoxyacetic Acid Adsorption.” Chemical Engineering Journal 173: 391–99.10.1016/j.cej.2011.07.075Suche in Google Scholar

Pathak, P. D., and S. A. Mandavgane. 2015a. “Preparation and Characterization of Raw and Carbon from Banana Peel by Microwave Activation: Application in Citric Acid Adsorption.” Journal of Environmental Chemical Engineering 3: 2435–47.10.1016/j.jece.2015.08.023Suche in Google Scholar

Pathak, P. D., and S. A. Mandavgane. 2015b. “Preparation and Characterization of Raw and Carbon from Banana Peel by Microwave Activation: Application in Citric Acid Adsorption.” Journal of Environmental Chemical Engineering 3 (4A): 2435–47.10.1016/j.jece.2015.08.023Suche in Google Scholar

Pathak, P. D., S. A. Mandavgane, and B. D. Kulkarni. 2015. “Fruit Peel Waste as a Novel Low-cost Bio Adsorbent.” Reviews in Chemical Engineering 31 (4): 361–81.10.1515/revce-2014-0041Suche in Google Scholar

Pathak, P. D., S. A. Mandavgane, and B. D. Kulkarni. 2016a. “Utilization of Banana Peel for the Removal of Benzoic and Salicylic Acid from Aqueous Solutions and Its Potential Reuse.” Desalination and Water Treatment 57 (27): 1–13.10.1080/19443994.2015.1051589Suche in Google Scholar

Pathak, P. D., S. A. Mandavgane, and B. D. Kulkarni. 2016b. “Valorization of Banana Peel: A Biorefinery Approach.” Reviews in Chemical Engineering 32 (6).10.1515/revce-2015-0063Suche in Google Scholar

Pathak, P. D., S. A. Mandavgane, and B. D. Kulkarni. 2017. “Fruit Peel Waste: Chacterization and Its Potential Uses.” Current Science 113 (3): 444–54.10.18520/cs/v113/i03/444-454Suche in Google Scholar

Pavan, Flavio A., Ilauro S. Lima, Eder C. Lima, Claudio Airoldi, and Y. Gushikem. 2006. “Use of Ponkan Mandarin Peels as Biosorbent for Toxic Metals Uptake from Aqueous Solutions.” Journal of Hazardous Materials 137 (1): 527–33.10.1016/j.jhazmat.2006.02.025Suche in Google Scholar PubMed

Serencam, H., D. Ozdes, C. Duran, and H. B. Senturk. 2014. “Assessment of Kinetics, Thermodynamics, and Equilibrium Parameters of Cu(II) Adsorption onto Rosa Canina Seeds.” Desalination and Water Treatment 52 (16–18): 3226–36.10.1080/19443994.2013.797377Suche in Google Scholar

Si, Y., J. Huo, H. Yin, and A. Wang. 2018. “Adsorption Kinetics, Isotherms, and Thermodynamics of Cr(III), Pb(II), and Cu(II) on Porous Hydroxyapatite Nanoparticles.” Journal of Nanoscience and Nanotechnology 18: 3484–91.10.1166/jnn.2018.14631Suche in Google Scholar PubMed

Thirumavalavan, M., Y.-L. Lai, and J.-F. Lee. 2011. “Fourier Transform Infrared Spectroscopic Analysis of Fruit Peels before and after the Adsorption of Heavy Metal Ions from Aqueous Solution.” Journal of Chemical & Engineering Data 56 (5): 2249–55.10.1021/je101262wSuche in Google Scholar

Xavier, A. L. P., O. F. H. Adarme, L. M. Furtado, G. M. D. Ferreira, L. H. M. da Silva, L. F. Gil, and L. V. A. Gurgel. 2018. “Modeling Adsorption of copper(II), cobalt(II) and nickel(II) Metal Ions from Aqueous Solution onto a New Carboxylated Sugarcane Bagasse. Part II: Optimization of Monocomponent Fixed-bed Column Adsorption.” Journal of Colloid and Interface Science 516: 431–45.10.1016/j.jcis.2018.01.068Suche in Google Scholar PubMed

Received: 2019-05-26
Revised: 2020-01-07
Accepted: 2020-02-02
Published Online: 2020-03-18

© 2020 Walter de Gruyter GmbH, Berlin/Boston

Heruntergeladen am 30.9.2025 von https://www.degruyterbrill.com/document/doi/10.1515/ijcre-2019-0109/html
Button zum nach oben scrollen