Abstract
In this study, the mixing efficiency of a passive contraction-expansion helical mixer, which combines several features, such as helical pipes for induction of secondary flows and sudden expansion and contraction array for expansion vortices, was numerically and experimentally studied. We employed the method of Box–Behnken to select the appropriate design points. Then, various configurations were investigated via computational fluid dynamics (CFD) simulations. The extent of mixing was evaluated by monitoring the residence time distribution (RTD) and observing the shape of the RTD curves. A fast competitive-consecutive diazo coupling reaction is carried out to validate the RTD results. The influences of radius of curvature of the helical mixer, ratio of the length of the contraction part to expansion part, pitch of helical mixer, and the Reynolds number (Re) on mixing efficiency, and pressure drop were also investigated. As expected, the radius of curvature of the helical mixer, ratio of the length of the contraction part to expansion part, and the Reynolds number affected significantly the mixing efficiency, while the pitch of helical mixer had little influence on mixing efficiency. Quadratic models for mixing efficiency and pressure drop were then proposed and could be used for designing the optimal contraction-expansion helical mixer for the required pumping power.
Nomenclature
- b [m]
pitch of helical mixer
- C(t) [s−1]
tracer concentration as a function of time
- dc [m]
inner diameter of the contraction part
- de [m]
inner diameter of the expansion part
- E(t) [s−1]
RTD function
- E(θ) [–]
normalized RTD function
- Ep [–]
peak value of the normalized RTD function
- k [mol m−3 s−1]
reaction rate constants,
- Lc [m]
length of the contraction part
- Le [m]
length of the expansion part
- o–R [–]
2-[(4-sulfophenyl)azo]-1-naphthol
- p–R [–]
4-[(4-sulfophenyl]azo]-1-naphthol
- R [m]
radius of curvature
- Re [–]
Reynolds number
- S [–]
2,4-bis[(4-sulfophenyl)azo]-1-naphthol
- t [s]
mixing time
- tm [s]
mean residence time
- ΔP [kg m−1 s−2]
pressure drop along the conduit
- XS
product distribution
- Y
response function
Greek letters
- aj, βj [–]
coefficients of the quadratic model
- θ [–]
dimensionless time
Acknowledgements
The authors are grateful to the financial supports of the National Key Technology R&D Program (2011BAE07B01) and Major Program of the National Natural Science Foundation of China (20836001).
References
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©2014 by De Gruyter
Articles in the same Issue
- Frontmatter
- Research Articles
- Simulation of CO Preferential Oxidation (COPrOx) Monolithic Reactors
- Simulation of a New Chemical-Looping Combustion Process without Sulfur Evolution Based on Ca-Based Oxygen Carrier
- Syngas Production from Reforming of Methane with CO2 and O2 over LaNi1–xCoxO3 Perovskites
- Investigation of the Effect of Outlet Structures on the Jet Flow Characteristics in the Circulating Jet Tank
- Transesterification of Sunflower Oil in Microreactors
- Influence of the Photoreactor Configuration and of Different Light Sources in the Photocatalytic Treatment of Highly Polluted Wastewater
- Stability and Emissions of a Lean Pre-Mixed Combustor with Rich Catalytic/Lean-burn Pilot
- Carica Papaya Seed as a Biosorbent for Removal of Cr (VI) and Ni (II) Ions from Aqueous Solution: Thermodynamics and Kinetic Analysis of Experimental Data
- Chemical Equilibrium Model and Prediction for Coal Hydrogasification
- Use of Experimental Designs to Establish a Kinetic Law for a Gas Phase Photocatalytic Process
- Application of Support Vector Machine Modeling on Phase Distribution in the Riser of an LSCFB Reactor
- Characteristics of the Bending Moment Acting on an Overhung Shaft in a Stirred Vessel
- Conversion of Glycerol into Value-Added Products Over Cu–Ni Catalyst Supported on γ-Al2O3 and Activated Carbon
- Analysis of Equilibrium Shifting by Inter-Stage Reactant Feeding in a Series of Isothermal Reactors
- Single and Multi-Channel Reactor for Oxidative Coupling of Methane
- Effect of Peak Temperature Limitations on the Design of Processes with Cooled Tubular Reactors
- Genetic Optimization of Energy Consumption of Pellet Shaft Furnace Combustor Based on Support Vector Machine (SVM)
- Effect of CuO on the Thermal Stability of Polyaniline Nanofibers
- Kinetics and Mechanism of Formaldehyde-Free Phenol-Glucose Novolac Resin Cured with an Epoxy
- Micromixing Characteristics in an Aerated Stirred Tank with Half Elliptical Blade Disk Turbine
- Application of Response Surface Methodology and Central Composite Rotatable Design for Modeling and Optimization of Catalyst Compositions in Ethanol Synthesis via CO Hydrogenation
- Accurate Measurement of the Photon Flux Received Inside Two Continuous Flow Microphotoreactors by Actinometry
- A Non-linear Inverse Problem in Estimating the Reaction Rate Function for an Annular-Bed Reactor
- Passive Microextractor with Internal Fluid Recirculation for Two Immiscible Liquids
- Oxidative Desulfurization of Dibenzothiophene by Zirconia-Based Catalysts
- Studies on Performance Analysis and Computer Aided Design of Inverse Fluidized Bed Bioreactors with Nanosupport Particles
- Modeling the Industrial Propylene–Ethylene Copolymerization FBR at Emergency Accidents
- Modelling of the Membrane Permeability Effect on the H2 Production Using CFD Method
- SBA-15 Supported Bimetallic Catalysts for Enhancement Isomers Production During n-Heptane Decomposition
- Effects of Microwave and Ultrasonic-Assisted Aging on the Synthesis of H-ZSM-5 Nanozeolite and Its Catalytic Performance in Methanol Dehydration
- Oxydehydrogenation of Ethylbenzene to Styrene: Membrane Reactor Analysis and Design
- Methanol Electrooxidation Study on Mesoporous Silica Supported Pt–Co Direct Methanol Fuel Cell Anode
- An Experimental Study of the Synthesis of Ultrafine Titania Powder in Plasmachemical Flow-Type Reactor
- Tesla Valves in Micromixers
- Kinetic Modelling of Photoconversion of Phenol by a Photo-Fenton Reagent and UV
- Overall Effectiveness Factor for Slab Geometry in a Three-Phase Reaction System
- Effect of Surface Chemistry and Structure of Sludge Particles on Their Co-slurrying Ability with Petroleum Coke
- CFD-DEM Modeling of CO2 Capture using Alkali Metal-Based Sorbents in a Bubbling Fluidized Bed
- Reaction Kinetics of Catalytic Esterification of Nonanoic Acid with Ethanol over Amberlyst 15
- Numerical and Experimental Investigation of the Effect of Geometrical Parameters on the Performance of a Contraction-Expansion Helical Mixer
- Comparative Study of Removal of Cadmium (II) and Chromium (III) Ions from Aqueous Solution Using Low-Cost Biosorbent
- Ethylation of Ethylbenzene with Ethanol over Mordenite-Based Catalysts: Effects of Acidity, Desilication and Kinetics Analysis
- A Two-Phase CFD Modeling Approach to Investigate the Flow Characteristics in Radial Flow Moving-Bed Reactors
- Esterification of Free Fatty Acids in Crude Palm Oil Using Sulfated Cobalt–Tin Mixed Oxide Catalysts
- Numerical Simulation of Chemical Stripping Process in Resid Fluid Catalytic Cracking Stripper
- Experiment on Simultaneous Absorption of NO and SO2 from Sintering Flue Gas by Oxidizing Agents of KMnO4/NaClO
- Analysis of the Simultaneous Gas–Liquid CO2 Absorption and Liquid–Gas NH3 Desorption in a Hydrometallurgical Waelz Oxides Purification Process
- Investigation on Fluidized Bed Bioreactor Treating Ice Cream Wastewater Using Response Surface Methodology and Artificial Neural Network
- Rapid Determination of the Residence Time Distribution (RTD) Function in an Oscillatory Baffled Reactor (OBR) Using a Design of Experiments (DoE) Approach
- α-Amylase Aspergillus oryzae Immobilized on Modified Expanded Perlite
- Diffusion and Equilibrium Adsorption Coefficients of Aromatic Hydrocarbon Species in Capillary Columns
- Design and Optimization of the Preparation of Calcium Carbonate from Calcium Sulfate and Ammonium Bicarbonate
- Short Communications
- Effect of Different Silicate Supports on the Catalytic Performance of MoVTeO Mixed Oxides in Partial Oxidation of Isobutane
- Liquid Flow and Mixing in Bottom Regions of Baffled and Unbaffled Vessels Agitated by Turbine-Type Impeller
- Review
- Progress in Reactors for High-Temperature Fischer–Tropsch Process: Determination Place of Intensifier Reactor Perspective
- Errata
- Erratum to Two-Dimensional Modeling of an Externally Irradiated Slurry Photoreactor
- Erratum to Photocatalytic Purification of Wastewater Polluted by Odorant Sulfur Compounds Using Titanium Oxide in a Continuous Photoreactor
Articles in the same Issue
- Frontmatter
- Research Articles
- Simulation of CO Preferential Oxidation (COPrOx) Monolithic Reactors
- Simulation of a New Chemical-Looping Combustion Process without Sulfur Evolution Based on Ca-Based Oxygen Carrier
- Syngas Production from Reforming of Methane with CO2 and O2 over LaNi1–xCoxO3 Perovskites
- Investigation of the Effect of Outlet Structures on the Jet Flow Characteristics in the Circulating Jet Tank
- Transesterification of Sunflower Oil in Microreactors
- Influence of the Photoreactor Configuration and of Different Light Sources in the Photocatalytic Treatment of Highly Polluted Wastewater
- Stability and Emissions of a Lean Pre-Mixed Combustor with Rich Catalytic/Lean-burn Pilot
- Carica Papaya Seed as a Biosorbent for Removal of Cr (VI) and Ni (II) Ions from Aqueous Solution: Thermodynamics and Kinetic Analysis of Experimental Data
- Chemical Equilibrium Model and Prediction for Coal Hydrogasification
- Use of Experimental Designs to Establish a Kinetic Law for a Gas Phase Photocatalytic Process
- Application of Support Vector Machine Modeling on Phase Distribution in the Riser of an LSCFB Reactor
- Characteristics of the Bending Moment Acting on an Overhung Shaft in a Stirred Vessel
- Conversion of Glycerol into Value-Added Products Over Cu–Ni Catalyst Supported on γ-Al2O3 and Activated Carbon
- Analysis of Equilibrium Shifting by Inter-Stage Reactant Feeding in a Series of Isothermal Reactors
- Single and Multi-Channel Reactor for Oxidative Coupling of Methane
- Effect of Peak Temperature Limitations on the Design of Processes with Cooled Tubular Reactors
- Genetic Optimization of Energy Consumption of Pellet Shaft Furnace Combustor Based on Support Vector Machine (SVM)
- Effect of CuO on the Thermal Stability of Polyaniline Nanofibers
- Kinetics and Mechanism of Formaldehyde-Free Phenol-Glucose Novolac Resin Cured with an Epoxy
- Micromixing Characteristics in an Aerated Stirred Tank with Half Elliptical Blade Disk Turbine
- Application of Response Surface Methodology and Central Composite Rotatable Design for Modeling and Optimization of Catalyst Compositions in Ethanol Synthesis via CO Hydrogenation
- Accurate Measurement of the Photon Flux Received Inside Two Continuous Flow Microphotoreactors by Actinometry
- A Non-linear Inverse Problem in Estimating the Reaction Rate Function for an Annular-Bed Reactor
- Passive Microextractor with Internal Fluid Recirculation for Two Immiscible Liquids
- Oxidative Desulfurization of Dibenzothiophene by Zirconia-Based Catalysts
- Studies on Performance Analysis and Computer Aided Design of Inverse Fluidized Bed Bioreactors with Nanosupport Particles
- Modeling the Industrial Propylene–Ethylene Copolymerization FBR at Emergency Accidents
- Modelling of the Membrane Permeability Effect on the H2 Production Using CFD Method
- SBA-15 Supported Bimetallic Catalysts for Enhancement Isomers Production During n-Heptane Decomposition
- Effects of Microwave and Ultrasonic-Assisted Aging on the Synthesis of H-ZSM-5 Nanozeolite and Its Catalytic Performance in Methanol Dehydration
- Oxydehydrogenation of Ethylbenzene to Styrene: Membrane Reactor Analysis and Design
- Methanol Electrooxidation Study on Mesoporous Silica Supported Pt–Co Direct Methanol Fuel Cell Anode
- An Experimental Study of the Synthesis of Ultrafine Titania Powder in Plasmachemical Flow-Type Reactor
- Tesla Valves in Micromixers
- Kinetic Modelling of Photoconversion of Phenol by a Photo-Fenton Reagent and UV
- Overall Effectiveness Factor for Slab Geometry in a Three-Phase Reaction System
- Effect of Surface Chemistry and Structure of Sludge Particles on Their Co-slurrying Ability with Petroleum Coke
- CFD-DEM Modeling of CO2 Capture using Alkali Metal-Based Sorbents in a Bubbling Fluidized Bed
- Reaction Kinetics of Catalytic Esterification of Nonanoic Acid with Ethanol over Amberlyst 15
- Numerical and Experimental Investigation of the Effect of Geometrical Parameters on the Performance of a Contraction-Expansion Helical Mixer
- Comparative Study of Removal of Cadmium (II) and Chromium (III) Ions from Aqueous Solution Using Low-Cost Biosorbent
- Ethylation of Ethylbenzene with Ethanol over Mordenite-Based Catalysts: Effects of Acidity, Desilication and Kinetics Analysis
- A Two-Phase CFD Modeling Approach to Investigate the Flow Characteristics in Radial Flow Moving-Bed Reactors
- Esterification of Free Fatty Acids in Crude Palm Oil Using Sulfated Cobalt–Tin Mixed Oxide Catalysts
- Numerical Simulation of Chemical Stripping Process in Resid Fluid Catalytic Cracking Stripper
- Experiment on Simultaneous Absorption of NO and SO2 from Sintering Flue Gas by Oxidizing Agents of KMnO4/NaClO
- Analysis of the Simultaneous Gas–Liquid CO2 Absorption and Liquid–Gas NH3 Desorption in a Hydrometallurgical Waelz Oxides Purification Process
- Investigation on Fluidized Bed Bioreactor Treating Ice Cream Wastewater Using Response Surface Methodology and Artificial Neural Network
- Rapid Determination of the Residence Time Distribution (RTD) Function in an Oscillatory Baffled Reactor (OBR) Using a Design of Experiments (DoE) Approach
- α-Amylase Aspergillus oryzae Immobilized on Modified Expanded Perlite
- Diffusion and Equilibrium Adsorption Coefficients of Aromatic Hydrocarbon Species in Capillary Columns
- Design and Optimization of the Preparation of Calcium Carbonate from Calcium Sulfate and Ammonium Bicarbonate
- Short Communications
- Effect of Different Silicate Supports on the Catalytic Performance of MoVTeO Mixed Oxides in Partial Oxidation of Isobutane
- Liquid Flow and Mixing in Bottom Regions of Baffled and Unbaffled Vessels Agitated by Turbine-Type Impeller
- Review
- Progress in Reactors for High-Temperature Fischer–Tropsch Process: Determination Place of Intensifier Reactor Perspective
- Errata
- Erratum to Two-Dimensional Modeling of an Externally Irradiated Slurry Photoreactor
- Erratum to Photocatalytic Purification of Wastewater Polluted by Odorant Sulfur Compounds Using Titanium Oxide in a Continuous Photoreactor