Abstract
Poor dimensional stability restricts the commercial utilization of fast-growing wood. In this study, fast-growing poplar (Populus cathayana) was treated by removing hemicellulose with hydrothermal treatment and impregnating alkali lignin via full-cell process, synergistically, for enhanced dimensional stability. After modification, hydroxyl groups were reduced in hemicellulose removed wood (DHC), alkali lignin was observed to fill in the cell lumens of vessels and wood fibers in the impregnated wood (AL) and in the wood modified by hemicellulose removal with alkali lignin impregnation (DHCAL). Compared with untreated wood, the volumetric swelling ratio of DHC and AL decreased by 11 % and 21 % under relative humidity (RH) of 89 %, respectively. The volumetric swelling ratio of DHCAL decreased by over 50 %, indicating a positive synergistic effect. The combination of hemicellulose removal and alkali lignin impregnation treatment improved the dimensional stability of wood significantly by reconstructing wood chemical components with various levels of hygroscopicity. This work could meaningfully contribute to the efficient utilization of fast-growing wood and promote the added value of industrial alkali lignin.
Funding source: National Natural Science Foundation of China
Award Identifier / Grant number: No. 31971583
-
Author contributions: Meng Yang: conceptualization, investigation, methodology, formal analysis, validation, data curation, visualization, writing-original draft, writing-review & editing. Runhua Zhang: investigation, methodology, visualization, supervision, writing-review & editing. Erni Ma: funding acquisition, conceptualization, methodology, resources, project administration, supervision, writing-review & editing. All authors have accepted responsibility for the entire content of this submitted manuscript and approved submission.
-
Research funding: This research was funded by the National Natural Science Foundation of China, grant no. 31971583.
-
Conflict of interest statement: The authors declare that they have no conflicts of interest regarding this article.
References
Altgen, M., Hofmann, T., and Militz, H. (2016). Wood moisture content during the thermal modification process affects the improvement in hygroscopicity of Scots pine sapwood. Wood Sci. Technol. 50: 1181–1195, https://doi.org/10.1007/s00226-016-0845-x.Search in Google Scholar
Andersson, S., Serimaa, R., Väänänen, T., Paakkari, T., Jämsä, S., and Viitaniemi, P. (2005). X-ray scattering studies of thermally modified Scots pine (Pinus sylvestris L.). Holzforschung 59: 422–427, https://doi.org/10.1515/hf.2005.069.Search in Google Scholar
Antczak, A., Szadkowski, J., Szadkowska, D., and Zawadzki, J. (2022). Assessment of the effectiveness of liquid hot water and steam explosion pretreatments of fast-growing poplar (Populus trichocarpa) wood. Wood Sci. Technol. 56: 87–109, https://doi.org/10.1007/s00226-021-01350-1.Search in Google Scholar
Chen, P., Dai, K., Wang, Z., Zhuang, W., Yang, P., Ying, H., and Wu, J. (2021). Separation and recovery of alkali lignin and NaOH based on size exclusion methodology. Sep. Purif. Technol. 257: 117852, https://doi.org/10.1016/j.seppur.2020.117852.Search in Google Scholar
Chien, Y., Yang, T., Hung, K., Li, C., Xu, J., and Wu, J. (2018). Effects of heat treatment on the chem-ical compositions and thermal decomposition kinetics of Japanese cedar and beech wood. Polym. Degrad. Stabil. 158: 220–227, https://doi.org/10.1016/j.polymdegradstab.2018.11.003.Search in Google Scholar
Dong, Y., Yan, Y., Wang, K., Li, J., Zhang, S., Xia, C., Shi, S.Q., and Cai, L. (2016). Improvement of water resistance, dimensional stability, and mechanical properties of poplar wood by rosin impregnation. Eur. J. Wood Wood Prod. 74: 177–184, https://doi.org/10.1007/s00107-015-0998-6.Search in Google Scholar
Gao, C., Zhang, Y., and Wang, C. (2015). Effect of high-temperature hydrothermal treatment on properties of particleboard. Packag. Eng. (Chinese) 36: 36–39. ISSN1001-3563.Search in Google Scholar
García-Iruela, A., Esteban, L.G., García Fernández, F., de Palacios, P., Rodriguez-Navarro, A.B., Martín-Sampedro, R., and Eugenio, M.E. (2019). Effect of vacuum/pressure cycles on cell wall composition and structure of poplar wood. Cellulose 26: 8543–8556, https://doi.org/10.1007/s10570-019-02692-7.Search in Google Scholar
Grönquist, P., Frey, M., Keplinger, T., and Burgert, I. (2019). Mesoporosity of delignified wood investigated by water vapor sorption. ACS Omega 4: 12425–12431, https://doi.org/10.1021/acsomega.9b00862.Search in Google Scholar PubMed PubMed Central
Guo, X., Fu, Y., Zhang, F., Li, X., and Liu, N. (2021). Change of structural features and relocalization of chemical components in the autohydrolyzed poplar wood chips enhance the accessibility of remaining components. Ind. Crop. Prod. 167: 113508, https://doi.org/10.1016/j.indcrop.2021.113508.Search in Google Scholar
He, M., Xu, D., Li, C., Ma, Y., Dai, X., Pan, X., Fan, J., He, Z., Gui, S., Dong, X., et al.. (2020). Cell wall bulking by maleic anhydride for wood durability improvement. Forests 11: 367, https://doi.org/10.3390/f11040367.Search in Google Scholar
Hill, C.A.S., Altgen, M., and Rautkari, L. (2021). Thermal modification of wood—a review: chemical changes and hygroscopicity. J. Mater. Sci. 56: 6581–6614.10.1007/s10853-020-05722-zSearch in Google Scholar
Hosseinaei, O., Wang, S., Enayati, A.A., and Rials, T.G. (2012). Effects of hemicellulose extraction on properties of wood flour and wood-plastic composites. Compos. Part A-Appl. S. 43: 686–694, https://doi.org/10.1016/j.compositesa.2012.01.007.Search in Google Scholar
Hou, S., Wang, J., Yin, F., Qi, C., and Mu, J. (2022). Moisture sorption isotherms and hysteresis of cellulose, hemicelluloses and lignin isolated from birch wood and their effects on wood hygroscopicity. Wood Sci. Technol. 56: 1087–1102.10.1007/s00226-022-01393-ySearch in Google Scholar
Huang, Y., Ma, E., and Zhao, G. (2015). Thermal and structure analysis on reaction mechanisms during the preparation of activated carbon fibers by KOH activation from liquefied wood-based fibers. Ind. Crop. Prod. 69: 447–455, https://doi.org/10.1016/j.indcrop.2015.03.002.Search in Google Scholar
Inalbon, M.C., Solier, Y.N., and Zanuttini, M.Á. (2017). Hydrothermal treatment of Eucalyptus wood: effects on Ion permeability and material removing. Ind. Crop. Prod. 104: 195–200, https://doi.org/10.1016/j.indcrop.2017.04.042.Search in Google Scholar
Jiang, X., Hou, Q., Liu, W., Zhang, H., and Qin, Q. (2016). Hemicelluloses removal in autohydrolysis pretreatment enhances the subsequent alkali impregnation effectiveness of poplar sapwood. Bioresour. Technol. 222: 361–366, https://doi.org/10.1016/j.biortech.2016.10.017.Search in Google Scholar PubMed
Kulasinski, K., Salmén, L., Derome, D., and Carmeliet, J. (2016). Moisture adsorption of glucomannan and xylan hemicelluloses. Cellulose 23: 1629–1637, https://doi.org/10.1007/s10570-016-0944-8.Search in Google Scholar
Kymäläinen, M., Ben Mlouka, S., Belt, T., Merk, V., Liljeström, V., Hänninen, T., Uimonen, T., Kostiainen, M., and Rautkari, L. (2018). Chemical, water vapour sorption and ultrastructural analysis of Scots pine wood thermally modified in high-pressure reactor under saturated steam. J. Mater. Sci. 53: 3027–3037, https://doi.org/10.1007/s10853-017-1714-1.Search in Google Scholar
Kyyrö, S., Altgen, M., Seppäläinen, H., Belt, T., and Rautkari, L. (2021). Effect of drying on the hydroxyl accessibility and sorption properties of pressurized hot water extracted wood. Wood Sci. Technol. 55: 1203–1220, https://doi.org/10.1007/s00226-021-01307-4.Search in Google Scholar
Kyyrö, S., Altgen, M., Belt, T., Seppäläinen, H., Brischke, C., Heinze, P., Militz, H., and Rautkari, L. (2022). Effect of pressurized hot water extraction and esterification on the moisture properties and decay resistance of Scots pine (Pinus sylvestris L.) sapwood. Holzforschung 76: 916–928, https://doi.org/10.1515/hf-2022-0100.Search in Google Scholar
Labbe, N., Rials, T.G., Kelley, S.S., Cheng, Z., Kim, J.Y., and Li, Y. (2005). FT-IR imaging and pyrolysis-molecular beam mass spectrometry: new tools to investigate wood tissues. Wood Sci. Technol. 39: 61–76, https://doi.org/10.1007/s00226-004-0274-0.Search in Google Scholar
Li, M., Chen, C., and Sun, R. (2014). Effect of pretreatment severity on the enzymatic hydrolysis of bamboo in hydrothermal deconstruction. Cellulose 21: 4105–4117, https://doi.org/10.1007/s10570-014-0451-8.Search in Google Scholar
Lindh, E.L., Bergenstråhle-Wohlert, M., Terenzi, C., Salmén, L., and Furó, I. (2016). Non-exchanging hydroxyl groups on the surface of cellulose fibrils: the role of interaction with water. Carbohydr. Res. 434: 136–142, https://doi.org/10.1016/j.carres.2016.09.006.Search in Google Scholar PubMed
Ling, Z., Ji, Z., Ding, D., Cao, J., and Xu, F. (2016). Microstructural and topochemical characterization of thermally modified poplar (Populus cathayaha) cell wall. Bioresources 11: 786–799, https://doi.org/10.15376/biores.11.1.786-799.Search in Google Scholar
Liu, M., Yi, Q., Li, J., Ma, E., and Liu, R. (2019). Synergistic effect of montmorillonite/lignin on improvement of water resistance and dimensional stability of Populus cathayana. Ind. Crop. Prod. 141: 111747, https://doi.org/10.1016/j.indcrop.2019.111747.Search in Google Scholar
Ma, J., Ji, Z., Chen, J., Zhou, X., Kim, Y.S., and Xu, F. (2015). The mechanism of xylans removal during hydrothermal pretreatment of poplar fibers investigated by immunogold labeling. Planta 242: 327–337, https://doi.org/10.1007/s00425-015-2313-5.Search in Google Scholar PubMed
Ma, X., Zheng, X., Yang, H., Wu, H., Cao, S., Chen, L., and Huang, L. (2016). A perspective on lignin effects on hemicelluloses dissolution for bamboo pretreatment. Ind. Crop. Prod. 94: 117–121, https://doi.org/10.1016/j.indcrop.2016.08.025.Search in Google Scholar
Metsä-Kortelainen, S., Antikainen, T., and Viitaniemi, P. (2006). The water absorption of sapwood and heartwood of Scots pine and Norway spruce heat-treated at 170°C, 190°C, 210°Cand 230°C. Holz. Roh. Werkst. 64: 192–197, https://doi.org/10.1007/s00107-005-0063-y.Search in Google Scholar
Ou, R., Xie, Y., Wolcott, M.P., Sui, S., and Wang, Q. (2014). Morphology, mechanical properties, and dimensional stability of wood particle/high density polyethylene composites: effect of removal of wood cell wall composition. Mater. Des. 58: 339–345, https://doi.org/10.1016/j.matdes.2014.02.018.Search in Google Scholar
Priadi, T., Suharjo, A.A.C., and Karlinasari, L. (2019). Dimensional stability and colour change of heat-treated young teak wood. Int. Wood Prod. J. 10: 119–125, https://doi.org/10.1080/20426445.2019.1679430.Search in Google Scholar
Rautkari, L., Hill, C.A.S., Curling, S., Jalaludin, Z., and Ormondroyd, G. (2013). What is the role of the accessibility of wood hydroxyl groups in controlling moisture content? J. Mater. Sci. 48: 6352–6356, https://doi.org/10.1007/s10853-013-7434-2.Search in Google Scholar
Srinivas, K. and Pandey, K.K. (2012). Effect of heat treatment on color changes, dimensional stability, and mechanical properties of wood. J. Wood Chem. Technol. 32: 304–316, https://doi.org/10.1080/02773813.2012.674170.Search in Google Scholar
Standard China (1934). Method for determination the water absorption of wood (GB/T 1934.1-2009). Standards Press of China, Beijing.Search in Google Scholar
Stokke, D.D., Wu, Q., and Han, G. (2013). Introduction to wood and natural fiber composites. John Wiley & Sons, Inc, UK.10.1002/9780470711804Search in Google Scholar
Thybring, E.E., Piqueras, S., Tarmian, A., and Burgert, I. (2020). Water accessibility to hydroxyls confined in solid wood cell walls. Cellulose 27: 5617–5627.10.1007/s10570-020-03182-xSearch in Google Scholar
Wang, X., Zhang, Y., Yu, Z., and Qi, C. (2017). Properties of fast-growing poplar wood simultaneously treated with dye and flame retardant. Eur. J. Wood Wood Prod. 75: 325–333.10.1007/s00107-016-1142-ySearch in Google Scholar
Wang, Y., Zhang, R., Yang, M., Peng, Y., and Cao, J. (2022). Improvement on dimensional stability and mold resistance of wood modified by tannin acid and tung oil. Holzforschung 76: 929–940, https://doi.org/10.1515/hf-2022-0062.Search in Google Scholar
Xu, F., Xu, L., Zheng, C., Wang, Y., and Zhang, H. (2022). Effect of lignin removal on the hygroscopicity of PMMA/Wood composites. Polymers 14: 3356, https://doi.org/10.3390/polym14163356.Search in Google Scholar PubMed PubMed Central
Xu, J., Zhang, Y., Shen, Y., Li, C., Wang, Y., Ma, Z., and Sun, W. (2019). New perspective on wood thermal modification: Relevance between the evolution of chemical structure and physical-mechanical properties, and online analysis of release of VOCs. Polymers 11: 1145–1163, https://doi.org/10.3390/polym11071145.Search in Google Scholar PubMed PubMed Central
Yang, L. and Liu, H. (2020). Effect of a combination of moderate-temperature heat treatment and subsequent wax impregnation on wood hygroscopicity, dimensional stability, and mechanical properties. Forests 11: 920–928, https://doi.org/10.3390/f11090920.Search in Google Scholar
Yang, T. (2020). Moisture sorption and deformation response mechanisms of furfurylated poplar wood to cyclically changing relative humidity. Ph.D. thesis. Beijing, Beijing Forestry University.Search in Google Scholar
Yang, T., Ma, E., and Cao, J. (2018a). Effects of lignin in wood on moisture sorption and hygroexpansion tested under dynamic condition. Holzforschung 72: 943–950, https://doi.org/10.1515/hf-2017-0198.Search in Google Scholar
Yang, T., Zhou, H., Ma, E., and Wang, J. (2018b). Effects of removal of different chemical components on moisture sorption property of Populus euramericana Cv. under dynamic hygrothermal conditions. Results Phys. 10: 61–68, https://doi.org/10.1016/j.rinp.2018.05.024.Search in Google Scholar
Yang, T., Ma, E., and Cao, J. (2019). Synergistic effects of partial hemicellulose removal and furfurylation on improving the dimensional stability of poplar wood tested under dynamic condition. Ind. Crop. Prod. 139: 111550, https://doi.org/10.1016/j.indcrop.2019.111550.Search in Google Scholar
Yang, T., Ma, E., and Cao, J. (2020). Dynamic moisture sorption and dimensional stability of furfurylated wood with low lignin content. Holzforschung 74: 68–76, https://doi.org/10.1515/hf-2019-0033.Search in Google Scholar
Yuan, J., Chen, Q., Fang, C., Zhang, S., Liu, X., and Fei, B. (2021). Effect of chemical composition of bamboo fibers on water sorption. Cellulose 28: 7273–7282, https://doi.org/10.1007/s10570-021-03988-3.Search in Google Scholar
Zhou, H. (2018). Study on multi-scale improvement of dimensional stability of fast-growing poplar wood by alkali lignin. Master’s thesis. Beijing, Beijing Forestry University.Search in Google Scholar
Zhou, H., Xu, R., and Ma, E. (2016). Effects of removal of chemical components on moisture adsorption by wood. Bioresources 11: 3110–3122, https://doi.org/10.15376/biores.11.2.3110-3122.Search in Google Scholar
Zhou, H., Li, J., and Ma, E. (2018). Multiscale modification of Populus cathayana by alkali lignin combined with heat treatment. Polymers 10: 1240, https://doi.org/10.3390/polym10111240.Search in Google Scholar PubMed PubMed Central
Supplementary Material
This article contains supplementary material (https://doi.org/10.1515/hf-2022-0147).
© 2023 Walter de Gruyter GmbH, Berlin/Boston
Articles in the same Issue
- Frontmatter
- Wood Physics/Mechanical Properties
- Effects of seismic strain rates on the perpendicular-to-grain compression behaviour of Dahurian larch, Mongolian pine and Chinese poplar: tests and stress-strain model
- The effect of the growth ring orientation on spring-back and set-recovery in surface-densified wood
- Synergistic improvement to dimensional stability of Populus cathay ana via hemicellulose removal/alkali lignin impregnation
- Adding gaseous ammonia with heat treatment to improve the mechanical properties of spruce wood
- Wood as a hydrothermally stimulated shape-memory material: mechanisms of shape-memory effect and molecular assembly structure networks
- Wood Chemistry
- Structural comparison of different isolated eucalyptus lignins and analysis of their interaction mechanism with bovine serum albumin solution under QCM-D
- Role of α-Fe2O3 nano-particles in protecting wood from ultraviolet light degradation
- Wood Science – Non-Tree Plants
- Radial distribution of vascular bundle morphology in Chinese bamboos: machine learning methodology for rapid sampling and classification
Articles in the same Issue
- Frontmatter
- Wood Physics/Mechanical Properties
- Effects of seismic strain rates on the perpendicular-to-grain compression behaviour of Dahurian larch, Mongolian pine and Chinese poplar: tests and stress-strain model
- The effect of the growth ring orientation on spring-back and set-recovery in surface-densified wood
- Synergistic improvement to dimensional stability of Populus cathay ana via hemicellulose removal/alkali lignin impregnation
- Adding gaseous ammonia with heat treatment to improve the mechanical properties of spruce wood
- Wood as a hydrothermally stimulated shape-memory material: mechanisms of shape-memory effect and molecular assembly structure networks
- Wood Chemistry
- Structural comparison of different isolated eucalyptus lignins and analysis of their interaction mechanism with bovine serum albumin solution under QCM-D
- Role of α-Fe2O3 nano-particles in protecting wood from ultraviolet light degradation
- Wood Science – Non-Tree Plants
- Radial distribution of vascular bundle morphology in Chinese bamboos: machine learning methodology for rapid sampling and classification