Startseite Assembly of electric double-layer capacitors with hardwood kraft lignin-based electrodes and separator together with ionic liquid electrolyte
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Assembly of electric double-layer capacitors with hardwood kraft lignin-based electrodes and separator together with ionic liquid electrolyte

  • Nutthira Pakkang , Shiori Suzuki , Kengo Shigetomi ORCID logo und Yasumitsu Uraki EMAIL logo
Veröffentlicht/Copyright: 15. Dezember 2022
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Holzforschung
Aus der Zeitschrift Holzforschung Band 77 Heft 2

Abstract

This study aimed to assemble a high-performance electric double-layer capacitor (EDLC) using a hardwood kraft lignin (HKL)-based separator and HKL-based electrodes, which were fabricated from a nonwoven mat of electrospun HKL fibers. The separator was prepared by the thermostabilization of the mat derived from a mixed dope of HKL, hexamethylenetetramine, and polyethylene glycol (1.66/0.50/0.09, w/w) for electrospinning. Although a mat-type HKL-based electrode containing conductive carbon black (CB) has been reported to be suitable for a commercial cellulosic separator, this electrode was found to be unsuitable for the HKL-based separator because of its rough surface and poor contact with the separator interface. Hence, a powder-type electrode with a smooth surface was fabricated by grinding the mat, followed by casting with a carboxymethyl cellulose aqueous solution, and its EDLC possessed high energy (49 Wh kg−1) and power densities (151 kW kg−1). Moreover, to provide a simple process for electrode fabrication, another mat-type electrode was fabricated by adding CB to the mixed dope, followed by electrospinning, carbonization, and steam activation. The resultant EDLC exhibited excellent electrochemical performance with energy (58 Wh kg−1) and power densities (55 kW kg−1).

Keywords: electric double layer capacitor; electrode; kraft lignin; separator; supercapacitor
Corresponding author: Yasumitsu Uraki, Research Faculty of Agriculture, Hokkaido University, Sapporo 060-8589, Japan, E-mail:

Funding source: Japan Society for the Promotion of Science

Award Identifier / Grant number: JP19J22306

Funding source: Hokkaido University

Award Identifier / Grant number: Unassigned

Acknowledgments

The authors would like to thank the Machinery Lab. at the Hokkaido University Institute for Catalysis for preparing a container for the thermostabilization of the electrospun mats.

  1. Author contributions: All the authors have accepted responsibility for the entire content of this submitted manuscript and approved submission.

  2. Research funding: This study was supported by a Grant-in-Aid for the Japan Society for the Promotion of Science (JSPS) KAKENHI [grant number: JP19J22306].

  3. Conflict of interest statement: The authors declare no conflicts of interest regarding this article.

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Supplementary Material

The online version of this article offers supplementary material (https://doi.org/10.1515/hf-2022-0143).

Received: 2022-09-14
Revised: 2022-11-16
Accepted: 2022-11-29
Published Online: 2022-12-15
Published in Print: 2023-02-23

© 2022 Walter de Gruyter GmbH, Berlin/Boston

Artikel in diesem Heft

  1. Frontmatter
  2. Original Articles
  3. Accelerated weathering performance of plantation-grown juvenile poplar and Chinese fir woods
  4. The effect of frequency and temperature on dielectric properties of wood with high moisture content
  5. Evaluation of the spatial variation in moisture content inside wood pieces during drying by NIR spectroscopy
  6. Effects of boron compounds impregnation on the physical and vibro-mechanical properties of spruce (Picea sp.)
  7. Assembly of electric double-layer capacitors with hardwood kraft lignin-based electrodes and separator together with ionic liquid electrolyte
https://doi.org/10.1515/hf-2022-0143
Schlagwörter für diesen Artikel
electric double layer capacitor; electrode; kraft lignin; separator; supercapacitor

Artikel in diesem Heft

  1. Frontmatter
  2. Original Articles
  3. Accelerated weathering performance of plantation-grown juvenile poplar and Chinese fir woods
  4. The effect of frequency and temperature on dielectric properties of wood with high moisture content
  5. Evaluation of the spatial variation in moisture content inside wood pieces during drying by NIR spectroscopy
  6. Effects of boron compounds impregnation on the physical and vibro-mechanical properties of spruce (Picea sp.)
  7. Assembly of electric double-layer capacitors with hardwood kraft lignin-based electrodes and separator together with ionic liquid electrolyte
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