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A self-cleaning surface based on heat treatment of g-C3N4-coated wood prepared by a rapid and eco-friendly method

  • Yue Dong , Xiaodi Ji , Fenglong Li , Tat Thang Nguyen , Zhanhua Huang and Minghui Guo EMAIL logo
Published/Copyright: December 10, 2018
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Abstract

A self-cleaning surface treatment has been developed, which is prepared by an eco-friendly and effective two-step method. First, graphitic carbon nitride (g-C3N4) was deposited on the wood surface by vacuum impregnation, followed by heat treatment. The morphology, weight change, dimensional stability, crystal and micro structure, and elemental composition of the wood samples were determined by photography, weighting, swelling rate determination, X-ray diffraction (XRD) and scanning electron microscopy and energy dispersive X-ray analysis (SEM-EDXA). Moreover, contact angle measurements and photocatalytic degradation experiments were carried out with Rhodamine B as the target. It was demonstrated that g-C3N4 is successfully deposited on the wood surface, which lowers the heat treatment temperature and renders photocatalytic properties to the coating. The heat treatment at around 210°C strengthened the immobility of g-C3N4 and increased the surface hydrophobicity. Moreover, the better photocatalytic ability of the surface is accompanied with self-cleaning effects.

  1. Author contributions: All the authors have accepted responsibility for the entire content of this submitted manuscript and approved submission.

  2. Research funding: This research was financially supported by the National Key Research and Development Program of China (2017YFD0600204).

  3. Employment or leadership: None declared.

  4. Honorarium: None declared.

References

Andersson, S., Serimaa, R., Paakkari, T., Saranpää, P., Pesonen, E. (2003) Crystallinity of wood and the size of cellulose crystallites in Norway spruce (Picea abies). J. Wood Sci. 49:531–537.10.1007/s10086-003-0518-xSearch in Google Scholar

Chang, F., Xie, Y., Li, C., Chen, J., Luo, J., Hu, X., Shen, J. (2013) A facile modification of g-C3N4 with enhanced photocatalytic activity for degradation of methylene blue. Appl. Surf. Sci. 280:967–974.10.1016/j.apsusc.2013.05.127Search in Google Scholar

Chen, W.H., Hsu, H.C., Lu, K.M., Lee, W.J., Lin, T.C. (2011) Thermal pretreatment of wood (Lauan) block by torrefaction and its influence on the properties of the biomass. Energy 36:3012–3021.10.1016/j.energy.2011.02.045Search in Google Scholar

Chen, Y., Huang, W., He, D., Yue, S., Hong, H. (2014) Construction of heterostructured g-C3N4/Ag/TiO2 microspheres with enhanced photocatalysis performance under visible-light irradiation. ACS Appl. Mater. Inter. 6:14405–14414.10.1021/am503674eSearch in Google Scholar PubMed

Dang, H., Jian, Z., Bassinot, F., Qiao, P., Cheng, X. (2013) Preparation of graphite-like carbon nitride nanoflake film with strong fluorescent and electrochemiluminescent activity. Nanoscale 5:225–230.10.1039/C2NR32248JSearch in Google Scholar

Dong, F., Wang, Z., Li, Y., Ho, W.K., Lee, S.C. (2014) Immobilization of polymeric g-C3N4 on structured ceramic foam for efficient visible light photocatalytic air purification with real indoor illumination. Environ. Sci. Technol. 48:10345–10353.10.1021/es502290fSearch in Google Scholar PubMed

Dong, H., Guo, X.T., Yang, C., Ouyang, Z.Z. (2018) Synthesis of g-C3N4 by different precursors under burning explosion effect and its photocatalytic degradation for tylosin. Appl. Catal. B-Environ. 230:65–76.10.1016/j.apcatb.2018.02.044Search in Google Scholar

Dubey Manoj, K., Pang, S., Walker, J. (2012) Changes in chemistry, color, dimensional stability and fungal resistance of Pinus radiata D. Don wood with oil heat-treatment. Holzforschung 66:49–57.Search in Google Scholar

Evans, P.D., Wallis, A.F.A., Owen, N.L. (2000) Weathering of chemically modified wood surfaces. Wood. Sci. Technol. 34:151–165.10.1007/s002260000039Search in Google Scholar

Fu, Y., Yu, H., Sun, Q., Li, G., Liu, Y. (2012) Testing of the superhydrophobicity of a zinc oxide nanorod array coating on wood surface prepared by hydrothermal treatment. Holzforschung 66:739–744.10.1515/hf-2011-0261Search in Google Scholar

Gao, L., Gan, W., Xiao, S., Zhan, X., Li, J. (2016) A robust superhydrophobic antibacterial Ag–TiO2 composite film immobilized on wood substrate for photodegradation of phenol under visible-light illumination. Ceram. Int. 42:2170–2179.10.1016/j.ceramint.2015.10.002Search in Google Scholar

Hakkou, M., Pétrissans, M., Gérardin, P., Zoulalian, A. (2006) Investigations of the reasons for fungal durability of heat-treated beech wood. Polym. Degrad. Stab. 91:393–397.10.1016/j.polymdegradstab.2005.04.042Search in Google Scholar

Han, Q., Wang, B., Gao, J., Cheng, Z., Zhao, Y., Zhang, Z., Qu, L. (2016) Atomically thin mesoporous nanomesh of graphitic-C3N4 for high-efficiency photocatalytic hydrogen evolution. ACS Nano 10:2745–2751.10.1021/acsnano.5b07831Search in Google Scholar

Hayoz, P., Peter, W., Rogez, D. (2003) A new innovative stabilization method for the protection of natural wood. Prog. Org. Coat. 48:297–309.10.1016/S0300-9440(03)00102-4Search in Google Scholar

Huang, X., Kocaefe, D., Kocaefe, Y., Boluk, Y., Krause, C. (2013) Structural analysis of heat-treated birch (Betula papyrifera) surface during artificial weathering. Appl. Surf. Sci. 264: 117–127.10.1016/j.apsusc.2012.09.137Search in Google Scholar

Hui, B., Li, G., Li, J., Via, B.K. (2016) Hydrothermal deposition and photoresponsive properties of WO3 thin films on wood surfaces using ethanol as an assistant agent. J. Taiwan Inst. Chem. E. 64:336–342.10.1016/j.jtice.2016.04.031Search in Google Scholar

Hui, B., Li, J. (2016) Low-temperature synthesis of hierarchical flower-like hexagonal molybdenum trioxide films on wood surfaces and their light-driven molecular responses. J. Mater. Sci. 51:10926–10934.10.1007/s10853-016-0304-ySearch in Google Scholar

Hui, B., Wu, D., Huang, Q., Cai, L., Li, G., Li, J., Zhao, G. (2015) Photoresponsive and wetting performances of sheet-like nanostructures of tungsten trioxide thin films grown on wood surfaces. Rsc Adv. 5:73566–73574.10.1039/C5RA10479CSearch in Google Scholar

Inari, G.N., Petrissans, M., Gerardin, P. (2007) Chemical reactivity of heat-treated wood. Wood. Sci. Technol. 41:157–168.10.1007/s00226-006-0092-7Search in Google Scholar

Ishikura, Y., Nakano, T. (2005) Adsorption properties and structural features of alkali treated wood. J. Jpn. Wood Res. Soc. 51:364–371.10.2488/jwrs.51.364Search in Google Scholar

Ji, X., Guo, M. (2017) Facile surface hydrophobization of medium-density fiberboard (MDF) by silver deposition. Holzforschung 71:337–340.10.1515/hf-2016-0106Search in Google Scholar

Jia, S., Liu, M., Wu, Y., Luo, S., Yan, Q., Chen, H. (2016) Facile and scalable preparation of highly wear-resistance superhydrophobic surface on wood substrates using silica nanoparticles modified by VTES. Appl. Surf. Sci. 386:115–124.10.1016/j.apsusc.2016.06.004Search in Google Scholar

Kong, L., Tu, K., Guan, H., Wang, X. (2017) Growth of high-density ZnO nanorods on wood with enhanced photostability, flame retardancy and water repellency. Appl. Surf. Sci. 407: 479–484.10.1016/j.apsusc.2017.02.252Search in Google Scholar

Liu, Y. (2016) Formation and properties of polyelectrolytes/TiO2 composite coating on wood surfaces through layer-by-layer assembly method. Holzforschung 70:361–367.10.1515/hf-2015-0047Search in Google Scholar

Lu, Y., Xiao, S., Gao, R., Li, J., Sun, Q. (2014) Improved weathering performance and wettability of wood protected by CeO2 coating deposited onto the surface. Holzforschung 68:345–351.10.1515/hf-2013-0119Search in Google Scholar

Mahr, M.S., Hübert, T., Stephan, I., Bücker, M., Militz, H. (2013) Reducing copper leaching from treated wood by sol-gel derived TiO2 and SiO2 depositions. Holzforschung 67:429–435.10.1515/hf-2012-0105Search in Google Scholar

Manoudis, P.N., Karapanagiotis, I., Tsakalof, A., Zuburtikudis, I., Panayiotou, C. (2008) Superhydrophobic composite films produced on various substrates. Langmuir 24:11225–11232.10.1021/la801817eSearch in Google Scholar PubMed

Navickas, P., Albrektas, D. (2013). Effect of heat treatment on sorption properties and dimensional stability of wood. Mater. Sci. 19:291–294.10.5755/j01.ms.19.3.5239Search in Google Scholar

Nguyen, T.T., Ji, X., Nguyen, T.H.V., Guo, M. (2017) Wettability modification of heat-treated wood (HTW) via cold atmospheric-pressure nitrogen plasma jet (APPJ). Holzforschung 72:37–43.10.1515/hf-2017-0004Search in Google Scholar

Pétrissans, M., Gérardin, P., Bakali, I.E., Serraj, M. (2003) Wettability of heat-treated wood. Holzforschung 57:301–307.10.1515/HF.2003.045Search in Google Scholar

Qu, M., Pelkonen, P., Tahvanainen, L., Arevalo, J., Gritten, D. (2012) Experts’ assessment of the development of wood framed houses in China. J. Clean. Prod. 31:100–105.10.1016/j.jclepro.2012.03.002Search in Google Scholar

Song, W., Wei, W., Ren, C., Zhang, S. (2017) Effect of heat treatment or alkali treatment of veneers on the mechanical properties of eucalyptus veneer/polyethylene film plywood composites. Bioresources 12:8683–8703.10.15376/biores.12.4.8683-8703Search in Google Scholar

Sun, B.L., Wang, Z., Liu, J.L. (2017) Changes of chemical properties and the water vapour sorption of Eucalyptus pellita wood thermally modified in vacuum. J. Wood Sci. 63:133–139.10.1007/s10086-016-1601-4Search in Google Scholar

Sun, Q.F., Yu, H.P., Liu, Y.X., Jian, L., Yun, L., Hunt, J.F. (2010) Improvement of water resistance and dimensional stability of wood through titanium dioxide coating. Holzforschung 64:757–761.10.1515/hf.2010.114Search in Google Scholar

Wang, Z., Sun, B.L., Liu, J.L. (2017) Investigation of volatile products released during vacuum heat treatment of larch wood. Wood Res. 62:773–782.Search in Google Scholar

Wolkenhauer, A., Avramidis, G., Militz, H., Viöl, W. (2008) Plasma treatment of heat treated beech wood – investigation on surface free energy. Holzforschung 62:472–474.10.1515/HF.2008.074Search in Google Scholar

Yan, S.C., Li, Z.S., Zou, Z.G. (2009) Photodegradation performance of g-C3N4 fabricated by directly heating melamine. Langmuir 25:10397–10401.10.1021/la900923zSearch in Google Scholar PubMed

Yang, P., Ou, H., Fang, Y., Wang, X. (2017) A facile steam reforming strategy to delaminate layered carbon nitride semiconductors for photoredox catalysis. Angew. Chem. 56:3992–3996.10.1002/anie.201700286Search in Google Scholar PubMed

Zhang, S., Hang, N., Zhang, Z., Yue, H., Yang, W. (2017) Preparation of g-C3N4/graphene composite for detecting NO2 at room temperature. Nanomaterials 7:12.10.3390/nano7010012Search in Google Scholar PubMed PubMed Central

Zhang, Y., Thomas, A., Antonietti, M., Wang, X. (2009) Activation of carbon nitride solids by protonation: morphology changes, enhanced ionic conductivity, and photoconduction experiments. J. Am. Chem. Soc. 131:50–51.10.1021/ja808329fSearch in Google Scholar PubMed

Received: 2018-05-23
Accepted: 2018-11-07
Published Online: 2018-12-10
Published in Print: 2019-04-24

©2019 Walter de Gruyter GmbH, Berlin/Boston

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