The sorption of monovalent cations onto wood flour and holocelluloses of Norway spruce: molecular interactions during LiCl impregnation
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Reddysuresh Kolavali
Abstract
Active functional groups and interactions involved in the sorption of Li+ ions from an aqueous LiCl solution onto the Norway spruce sapwood (sW) flour have been investigated. To this purpose, sW was delignified by peracetic acid (PAA) treatments and the resulting holocelluloses (HC6 h, HC24 h, HC51 h, HC72 h, where the lower case data indicate the PAA treatment time) with various lignin contents were immersed in aqueous solution of LiCl and the sorption effects were studied by flame atomic emission spectroscopy (FAES), attenuated total reflectance-Fourier transform infrared spectroscopy (ATR-FTIR), and X-ray photoelectron spectroscopy (XPS). The Brunauer- Emmett-Teller (BET) specific surface area increased from 1.5±0.0 m2g−1 to 2.4±0.1 m2g−1 for HC6 h, and from 1.6±0.03 m2g−1 to 2.7±0.6 m2g−1 for HC72 h upon LiCl treatment. It was found that Li+/Cl− retention occurs predominantly via O-containing functionalities and the carbohydrate-rich samples sorbed more Li+. Upon LiCl treatment, the mobility and accessibility of the wood matrix was enhanced, possibly by interference of the introduced ions with the existing intermolecular bonds.
Acknowledgments
We are grateful to Chalmers Energy Initiative for their financial support. Our thanks go to Ms. Anne Wendel, senior research engineer, Applied Chemistry, Chalmers University of Technology, for her technical assistance with the XPS characterization measurements.
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©2017 Walter de Gruyter GmbH, Berlin/Boston
Artikel in diesem Heft
- Frontmatter
- Preparation of highly mesoporous wood-derived activated carbon fiber and the mechanism of its porosity development
- The sorption of monovalent cations onto wood flour and holocelluloses of Norway spruce: molecular interactions during LiCl impregnation
- Dynamic hardness of wood – measurements with an automated portable hardness tester
- Static and dynamic tensile shear test of glued lap wooden joint with four different types of adhesives
- Nondestructive bending tests on Douglas-fir utility poles as a potential tool for pole sorting and for prediction of their behavior in service
- Verification of the elastic material characteristics of Norway spruce and European beech in the field of shear behaviour by means of digital image correlation (DIC) for finite element analysis (FEA)
- Characterizing spatial distribution of the adsorbed water in wood cell wall of Ginkgo biloba L. by μ-FTIR and confocal Raman spectroscopy
- A comprehensive mathematical model of heat and moisture transfer for wood convective drying
- Phylogenetic analysis of wood-inhabiting molds and assessment of soft-rot wood deterioration. Part 5. Genus Aureobasidium
- Creating extended antimicrobial property in paper by means of Ag and nanohybrids of montmorillonite (MMT)
Artikel in diesem Heft
- Frontmatter
- Preparation of highly mesoporous wood-derived activated carbon fiber and the mechanism of its porosity development
- The sorption of monovalent cations onto wood flour and holocelluloses of Norway spruce: molecular interactions during LiCl impregnation
- Dynamic hardness of wood – measurements with an automated portable hardness tester
- Static and dynamic tensile shear test of glued lap wooden joint with four different types of adhesives
- Nondestructive bending tests on Douglas-fir utility poles as a potential tool for pole sorting and for prediction of their behavior in service
- Verification of the elastic material characteristics of Norway spruce and European beech in the field of shear behaviour by means of digital image correlation (DIC) for finite element analysis (FEA)
- Characterizing spatial distribution of the adsorbed water in wood cell wall of Ginkgo biloba L. by μ-FTIR and confocal Raman spectroscopy
- A comprehensive mathematical model of heat and moisture transfer for wood convective drying
- Phylogenetic analysis of wood-inhabiting molds and assessment of soft-rot wood deterioration. Part 5. Genus Aureobasidium
- Creating extended antimicrobial property in paper by means of Ag and nanohybrids of montmorillonite (MMT)
