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Preparation of electrode for electric double layer capacitor from electrospun lignin fibers

  • Xiangyu You , Keiichi Koda , Tatsuhiko Yamada and Yasumitsu Uraki ORCID logo EMAIL logo
Published/Copyright: February 19, 2015
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Abstract

Lignin-based activated carbon fibers (ACFs) were prepared by electrospinning of hardwood acetic acid lignin (HW-AAL) solution followed by thermostabilization, carbonization, and steam activation. The thermostabilization process was able to be remarkably shortened from 38 h to 3 h with hexamethylenetetramine (hexamine) in binary solvents, AcOH/CCl4 (8/2), when compared with conventional thermostabilization processes. The resultant ACFs possessed higher specific surface area (2185 m2 g-1) than those from commercial activated carbon and electrospun lignin fibers without hexamine. These ACFs also exhibited good electrical capacitance (133.3 F g-1 at a current density of 1 A g-1) as electrodes of electric double layer capacitor (EDLC) are efficient not only due to their large surfaces area but also due to their porous structure with well-developed micropores (diameter: 0.5–1.3 nm). High energy density and power density of this EDLC (42 Wh kg-1 and 91 kW kg-1, respectively) were also achieved.


Corresponding author: Yasumitsu Uraki, Research Faculty of Agriculture, Hokkaido University, Sapporo 060-8589, Japan, Phone: +81 011 706 2817, Fax: +81 011 706 2817, e-mail:

Acknowledgments

This work was supported by a grant from the Ministry of Agriculture, Forestry and Fisheries of Japan, “Development of Technologies for Biofuel Production Systems in Rural Areas (2012–2015)”. We would also like to thank Prof. Aorigele (South China University of Technology, China) for his valuable advice to our work.

References

Babel, K., Jurewicz, K. (2008) KOH activated lignin based nanostructured carbon exhibiting high hydrogen electrosorption. Carbon 46:1948–1956.10.1016/j.carbon.2008.08.005Search in Google Scholar

Bose, S., Kuila, T., Mishra, A.K., Rajasekar, R., Kim, N.H., Lee, J.H. (2012) Carbon-based nanostructured materials and their composites as supercapacitor electrodes. J. Mater. Chem. 22:767–784.10.1039/C1JM14468ESearch in Google Scholar

Bozell, J.J., Petersen, G.R. (2010) Technology development for the production of biobased products from biorefinery carbohydrates-the US Department of Energy’s “Top 10” revisited. Green Chem. 12:539–554.10.1039/b922014cSearch in Google Scholar

Burke, A. (2007) R&D considerations for the performance and application of electrochemical capacitors. Electrochim. Acta 53:1083–1091.10.1016/j.electacta.2007.01.011Search in Google Scholar

Calvo-Flores, F.G., Dobado, J.A. (2010) Lignin as renewable raw material. ChemSusChem 3:1227–35.10.1002/cssc.201000157Search in Google Scholar

Chmiola, J., Yushin, G., Gogotsi, Y., Portet, C., Simon, P., Taberna, P.L. (2006) Anomalous increase in carbon capacitance at pore sizes less than 1 nanometer. Science 313:1760–1763.10.1126/science.1132195Search in Google Scholar

El-Kady, M.F., Strong, V., Dubin, S., Kaner, R.B. (2012) Laser scribing of high-performance and flexible graphene-based electrochemical capacitors. Science 335:1326–1330.10.1126/science.1216744Search in Google Scholar

Feng, Y., Aorigele. (2009) Preparation of lignin-based nanofibers by electrospinning. Paper Sci. Technol. 28:29–32.Search in Google Scholar

Fitzer, E., Müller, D.J. (1975) The influence of oxygen on the chemical reactions during stabilization of pan as carbon fiber precursor. Carbon 13:63–69.10.1016/0008-6223(75)90259-6Search in Google Scholar

Im, J.S., Park, S.-J., Lee, Y.-S. (2007) Preparation and characteristics of electrospun activated carbon materials having meso- and macropores. J. Colloid Interface Sci. 314:32–37.10.1016/j.jcis.2007.05.033Search in Google Scholar

Imaizumi, S., Matsumoto, H., Suzuki, K., Minagawa, M., Kimura, M., Tanioka, A. (2009) Phenolic resin-based carbon thin fibers prepared by electrospinning: additive effects of poly(vinyl butyral) and electrolytes. Polym. J. 41:1124–1128.10.1295/polymj.PJ2009160Search in Google Scholar

Inagaki, M. (2009) Pores in carbon materials-importance of their control. New Carbon Mater. 24:193–232.10.1016/S1872-5805(08)60048-7Search in Google Scholar

Inagaki, M., Konno, H., Tanaike, O. (2010) Carbon materials for electrochemical capacitors. J. Power Sources 195:7880–7903.10.1016/j.jpowsour.2010.06.036Search in Google Scholar

Kadla, J.F., Kubo, S., Venditti, R.A., Gilbert, R.D., Compere, A.L., Griffith, W. (2002) Lignin-based carbon fibers for composite fiber applications. Carbon 40:2913–2920.10.1016/S0008-6223(02)00248-8Search in Google Scholar

Kim, C., Yang, K.S. (2003) Electrochemical properties of carbon nanofiber web as an electrode for supercapacitor prepared by electrospinning. Appl. Phys. Lett. 83:1216–1218.10.1063/1.1599963Search in Google Scholar

Kim, T., Jung, G., Yoo, S., Suh, K.S., Ruoff, R.S. (2013) Activated graphene-based carbons as supercapacitor electrodes with macro- and mesopores. ACS Nano 7:6899–6905.10.1021/nn402077vSearch in Google Scholar

Kubo, S., Kadla, J.F. (2005) Lignin-based carbon fibers: effect of synthetic polymer blending on fiber properties. J. Polym. Environ. 13:97–105.10.1007/s10924-005-2941-0Search in Google Scholar

Kubo, S., Uraki, Y., Sano, Y. (1998) Preparation of carbon fibers from softwood lignin by atmospheric acetic acid pulping. Carbon 36:1119–1124.10.1016/S0008-6223(98)00086-4Search in Google Scholar

Lai, C., Zhou, Z., Zhang, L., Wang, X., Zhou, Q., Zhao, Y., Wang, Y., Wu, X.-F., Zhu, Z., Fong, H. (2014) Free-standing and mechanically flexible mats consisting of electrospun carbon nanofibers made from a natural product of alkali lignin as binder-free electrodes for high-performance supercapacitors. J. Power Sources 247:134–141.10.1016/j.jpowsour.2013.08.082Search in Google Scholar

Liu, C.L., Dong, W.S., Cao, G.P., Song, J.R., Liu, L., Yang, Y.S. (2007) Influence of KOH followed by oxidation pretreatment on the electrochemical performance of phenolic based activated carbon fibers. J. Electroanal. Chem. 611:225–231.10.1016/j.jelechem.2007.09.003Search in Google Scholar

Liu, C.L., Dong, W.S., Cao, G.P., Song, J.R., Liu, L., Yang, Y.S. (2008) Capacitance limits of activated carbon fiber electrodes in aqueous electrolyte. J. Electrochem. Soc. 155:F1–F7.10.1149/1.2799683Search in Google Scholar

Liu, S., Song, Y., Ma, C., Shi, J.-L., Guo, Q.-G., Liu, L. (2012) The electrochemical performance of porous carbon nanofibers produced by electrospinning. Carbon 50:3963.10.1016/j.carbon.2012.04.018Search in Google Scholar

Lu, H., Dai, W., Zheng, M., Li, N., Ji, G., Cao, J. (2012) Electrochemical capacitive behaviors of ordered mesoporous carbons with controllable pore sizes. J. Power Sources 209:243–250.10.1016/j.jpowsour.2012.02.041Search in Google Scholar

Martin, C., Ronda, J.C., Cadiz, V. (2006) Development of novel flame-retardant thermosets based on boron-modified phenol-formaldehyde resins. J. Polym. Sci. Part a-Polym. Chem. 44:3503–3512.10.1002/pola.21458Search in Google Scholar

Neimark, A.V., Lin, Y., Ravikovitch, P.I., Thommes, M. (2009) Quenched solid density functional theory and pore size analysis of micro-mesoporous carbons. Carbon 47:1617–1628.10.1016/j.carbon.2009.01.050Search in Google Scholar

Qu, D., Shi, H. (1998) Studies of activated carbons used in double-layer capacitors. J. Power Sources 74:99–107.10.1016/S0378-7753(98)00038-XSearch in Google Scholar

Rosas, J.M., Bedia, J., Rodriguez-Mirasol, J., Cordero, T. (2009) HEMP-derived activated carbon fibers by chemical activation with phosphoric acid. Fuel 88:19–26.10.1016/j.fuel.2008.08.004Search in Google Scholar

Ruiz-Rosas, R., Valero-Romero, M.J., Salinas-Torres, D., Rodriguez-Mirasol, J., Cordero, T., Morallon, E., Cazorla-Amoros, D. (2014) Electrochemical performance of hierarchical porous carbon materials obtained from the infiltration of lignin into zeolite templates. ChemSusChem 7:1458–1467.10.1002/cssc.201301408Search in Google Scholar PubMed

Simon, P., Gogotsi, Y. (2008) Materials for electrochemical capacitors. Nat. Mater. 7:845–854.10.1038/nmat2297Search in Google Scholar

Suhas, Carrott, P.J.M., Ribeiro Carrott, M.M.L. (2007) Lignin – from natural adsorbent to activated carbon: a review. Bioresour. Technol. 98:2301–2312.10.1016/j.biortech.2006.08.008Search in Google Scholar PubMed

Uraki, Y., Kubo, S., Nigo, N., Sano, Y., Sasaya, T. (1995) Preparation of carbon fibers from Organosolv lignin obtained by aqueous acetic acid pulping. Holzforschung 49:343–350.10.1515/hfsg.1995.49.4.343Search in Google Scholar

Uraki, Y., Nakatani, A., Kubo, S., Sano, Y. (2001) Preparation of activated carbon fibers with large specific surface area from softwood acetic acid lignin. J. Wood Sci. 47:465–469.10.1007/BF00767899Search in Google Scholar

Wang, G., Zhang, L., Zhang, J. (2012) A review of electrode materials for electrochemical supercapacitors. Chem. Soc. Rev. 41:797–828.10.1039/C1CS15060JSearch in Google Scholar

Xu, B., Wu, F., Chen, S., Zhang, C.Z., Cao, G.P., Yang, Y.S. (2007) Activated carbon fiber cloths as electrodes for high performance electric double layer capacitors. Electrochim. Acta 52:4595–4598.10.1016/j.electacta.2007.01.006Search in Google Scholar

Zhang, L.L., Zhao, X.S. (2009) Carbon-based materials as supercapacitor electrodes. Chem. Soc. Rev. 38:2520–2531.10.1039/b813846jSearch in Google Scholar

Received: 2014-9-26
Accepted: 2015-1-16
Published Online: 2015-2-19
Published in Print: 2015-11-1

©2015 by De Gruyter

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