Pulping-tailored fiber properties from a novel Brazilian Eucalyptus hybrid
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Marcelo Coelho dos Santos Muguet
, Fernando José Borges Gomes
Abstract
The chemical composition and morphology of pulp fibers have a significant impact on the properties of fiber products. Pulp samples from a novel unique Eucalyptus triple hybrid [Eucalyptus grandis × (Eucalyptus urophylla × Eucalyptus globulus)] were obtained by various pulping processes – kraft, soda-anthraquinone (NaOH-AQ), and thermomechanical pulping (TMP). The chemical composition of the fiber surfaces was evaluated by X-ray photoelectron spectroscopy (XPS). The surface lignin content of NaOH-AQ pulp fibers was lower than that of the kraft counterpart. However, kraft pulp handsheets showed better physical and mechanical properties. XPS data strongly suggests that together with the pulp bulk chemical composition the xylan is more abundant on the surface of kraft fibers, which is reflected on their better mechanical properties. Moreover, the relatively low surface lignin content in TMP pulp compared to wood suggests that defibration takes place in the secondary wall, where lignin is less concentrated.
The authors would like to acknowledge the financial support from the Academy of Finland (Effect of fibre wall chemistry on energy demand in wood defibration, DEFIBRE), the Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq, Brazil), and the Multidisciplinary Institute of Digitalization and Energy (MIDE) at the Aalto University. The authors would also like to acknowledge José Maurício Lino, for the wood and pulps chemical characterization, Heikki Tulokas for the help during TMP experiments, Mirja Reinikainen for the Raman measurements, Matti Sarantola for the handsheets extractions, Lasse Tolonen and Anne Michud for the help during the GPC experiments, and Dr. Joseph Campbell for performing the XPS experiments.
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- Frontmatter
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- Meetings
- Meetings
Articles in the same Issue
- Frontmatter
- Original articles
- Enhancement of paper dry strength by carboxymethylated β-d-glucan from oat as additive
- Effect of fiber modification with 3-isopropenyl-dimethylbenzyl isocyanate (TMI) on the mechanical properties and water absorption of hemp-unsaturated polyester (UPE) composites
- Pulping-tailored fiber properties from a novel Brazilian Eucalyptus hybrid
- Mechanical performance of cellulose nanofibril film-wood flake laminate
- Variation of mechanical properties of single bamboo fibers (Dendrocalamus latiflorus Munro) with respect to age and location in culms
- Determination of the mechanical properties of radiata pine timber by means of longitudinal and transverse vibration methods
- A theoretical and experimental study of the circular sawing process
- Mathematical modeling of drying of Masson pine lumber and its asymmetrical moisture content profile
- Combined treatment of green pitch pine wood by heat and superheated steam and the effects on physical properties of the products
- Effect of mild torrefaction on pulverization of Norway spruce (Picea abies) by oscillatory ball milling: particle morphology and cellulose crystallinity
- Improved weathering performance and wettability of wood protected by CeO2 coating deposited onto the surface
- Impregnation of laser incised wood of Douglas fir and Japanese cedar by dipping (passive impregnation) in solutions of copper azole (CuAz-B) and a fire retardant (PPC)
- Short Notes
- Effect of initial moisture content on the anti-swelling efficiency of thermally modified Scots pine sapwood treated in a high-pressure reactor under saturated steam
- Comparison of antitermite properties of 2-thioxocoumarins against Coptotermes formosanus Shiraki
- Meetings
- Meetings