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Distribution of extracts including 4,8-dihydroxy-5-methoxy-2-naphthaldehyde in Diospyros kaki analyzed by gas chromatography-mass spectrometry and time-of-flight secondary ion mass spectrometry

  • Yasuyuki Matsushita EMAIL logo , In-Cheol Jang , Takanori Imai , Ruka Takama , Kaori Saito , Takashi Masumi , Seung-Cheol Lee and Kazuhiko Fukushima
Published/Copyright: March 5, 2012
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Abstract

The distribution of ethyl acetate extracts and 4,8-dihydroxy-5-methoxy-2-naphthaldehyde (compound I), which is a major constituent of the extracts obtained from the blackened heartwood of Diospyros kaki, was analyzed via gas chromatography-mass spectrometry (GC-MS) and time-of-flight secondary ion mass spectrometry (ToF-SIMS). According to GC-MS, the extracts and compound I are high in concentration at the pith and at the edges of the blackened heartwood. ToF-SIMS analysis revealed a peak at a mass-to-charge ratio of (m/z) 218, which is characteristic of the ionic form of compound I. The ToF-SIMS imaging of compound I in the blackened heartwood based on m/z 218 shows that compound I is located in parenchyma cells and their neighboring axial elements.


Corresponding author. Graduate School of Bioagricultural Sciences, Nagoya University, Furo-cho Chikusa-ku Nagoya, Aichi 464-8601, Japan Phone: +81-52-789-4160 Fax: +81-52-789-4163

Received: 2011-10-19
Accepted: 2012-1-23
Published Online: 2012-03-05
Published in Print: 2012-08-01

©2012 by Walter de Gruyter Berlin Boston

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  18. Distribution of extracts including 4,8-dihydroxy-5-methoxy-2-naphthaldehyde in Diospyros kaki analyzed by gas chromatography-mass spectrometry and time-of-flight secondary ion mass spectrometry
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