Startseite Naturwissenschaften By-product Eucalyptus leaves valorization in the basic dye adsorption: kinetic equilibrium and thermodynamic study
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By-product Eucalyptus leaves valorization in the basic dye adsorption: kinetic equilibrium and thermodynamic study

  • Naouel Babakhouya , Souad Benammar , Adh’ya-Eddine Hamitouche , Amel Boudjemaa ORCID logo EMAIL logo , Mohamed-Zine Messaoud-Boureghda und Khaldoun Bachari
Veröffentlicht/Copyright: 29. April 2024
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Chemical Product and Process Modeling
Aus der Zeitschrift Chemical Product and Process Modeling Band 19 Heft 2

Abstract

Algerian Eucalyptus Leaves (AEL), a natural biodegradable adsorbent abundantly available, was used for the removal of methylene blue (MB) dye. The AEL properties for the removal of MB were investigated under different conditions by varying the AEL amount, MB concentration, pH of the solution and the reaction temperature. Scanning electron microscopy (SEM) and infrared spectroscopy (FTIR) techniques have been used to characterize AEL biosorbent. Experimental results showed that the adsorption of MB dye at the concentration of 50 mg L−1 reached to 91 % at pH 10 with a stirring speed of 200 rpm and after 180 min of reaction time. The experimental data were analyzed using the linear forms of different kinetic models (pseudo-first order kinetic model, pseudo-second order kinetic model, and intra-particle diffusion models). The results demonstrated that the adsorption kinetics of MB was consistent with the pseudo-second order model with R 2 value of 0.9969. The isotherm models Langmuir, Freundlich, Dubinin, Elovich, Brunaut Emmet Teller and Temkin models were also investigated to describe the adsorption equilibrium. The results show that the AEL adsorption is in accordance with Temkin isotherm. The thermodynamic study revealed that the adsorption is spontaneous and exothermic. Therefore, as a cheap green adsorbent with high MB adsorption performance, AEL is expected to become one of the best candidate materials for future industrial wastewater treatment.

Keywords: Eucalyptus leaves; valorisation; adsorption; dye removal; isotherm models; thermodynamic
Corresponding author: Amel Boudjemaa, Centre de Recherche Scientifique et Technique en Analyses Physico-Chimiques, BP 384, Siège ex-Pasna Zone Industrielle, Bou-Ismail CP, Tipaza 42004, Algeria, E-mail:

Funding source: General Directorate for Scientific Research and Technological Development DGRSDT (Algeria)

  1. Research ethics: Not applicable.

  2. Author contributions: Naouel Babakhouya: Conceptualization, Methodology, Writing – original draft. Souad Benammar: Visualization, Investigation, Methodology, – review & editing. Adh’ya-Eddine Hamitouche: Visualization, Investigation, Methodology, – review & editing. Kkaldoun Bachari: Review & Editing. Messaoud-Boureghda Mohamed-Zine: Review & Editing. Amel Boudjemaa: Conceptualization, Writing – review & editing. All the authors commented on previous versions of the manuscript, read and improved the final manuscript.

  3. Competing interests: The authors declare no competing interests.

  4. Research funding: This work is supported by the General Directorate for Scientific Research and Technological Development DGRSDT (Algeria).

  5. Data availability: All data generated or analyzed during this study are included in the published article.

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Received: 2023-03-14
Accepted: 2024-03-01
Published Online: 2024-04-29

© 2024 Walter de Gruyter GmbH, Berlin/Boston

Artikel in diesem Heft

  1. Frontmatter
  2. Editorial
  3. CPPM special issue in honor of Professor Faïçal Larachi
  4. Research Articles
  5. Predicting buoyant jet characteristics: a machine learning approach
  6. Insights into the bubble formation dynamics in converging shape microchannels using CLSVOF method
  7. Comparison of different CFD approaches for the simulation of developing free surface two-phase flow in straight and bent pipes
  8. A new approach to model the fluid dynamics in sandwich packings
  9. Effect of novel mixed impeller on local bubble size and flow regime transition in pilot scale gas-liquid stirred tank reactor
  10. Quantitative structure-electrochemistry relationship modeling of a series of anticancer agents using MLR and ANN approaches
  11. Extractive desulfurization of crude petroleum oil and liquid fuels using trihexyl tetradecyl phosphonium bis(2-ethylhexyl) phosphate ionic liquid
  12. CFD-aided contraction-expansion static mixer design for oil-in-water emulsification
  13. Liquid-liquid flow pattern and mass transfer in a rotating millimeter channel reactor
  14. By-product Eucalyptus leaves valorization in the basic dye adsorption: kinetic equilibrium and thermodynamic study
https://doi.org/10.1515/cppm-2023-0023
Schlagwörter für diesen Artikel
Eucalyptus leaves; valorisation; adsorption; dye removal; isotherm models; thermodynamic

Artikel in diesem Heft

  1. Frontmatter
  2. Editorial
  3. CPPM special issue in honor of Professor Faïçal Larachi
  4. Research Articles
  5. Predicting buoyant jet characteristics: a machine learning approach
  6. Insights into the bubble formation dynamics in converging shape microchannels using CLSVOF method
  7. Comparison of different CFD approaches for the simulation of developing free surface two-phase flow in straight and bent pipes
  8. A new approach to model the fluid dynamics in sandwich packings
  9. Effect of novel mixed impeller on local bubble size and flow regime transition in pilot scale gas-liquid stirred tank reactor
  10. Quantitative structure-electrochemistry relationship modeling of a series of anticancer agents using MLR and ANN approaches
  11. Extractive desulfurization of crude petroleum oil and liquid fuels using trihexyl tetradecyl phosphonium bis(2-ethylhexyl) phosphate ionic liquid
  12. CFD-aided contraction-expansion static mixer design for oil-in-water emulsification
  13. Liquid-liquid flow pattern and mass transfer in a rotating millimeter channel reactor
  14. By-product Eucalyptus leaves valorization in the basic dye adsorption: kinetic equilibrium and thermodynamic study
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