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Rare Earth Metal Fluorides in Water and Aqueous Systems

Published/Copyright: July 17, 2014
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Chemistry International
From the journal Chemistry International Volume 36 Issue 4

T. Mioduski, C. Gumiński, and D. ZengJ. Phys. Chem. Ref. Data 43, 013105 (2014)IUPAC-NIST Solubility Data Series, Volume 100

Fluorides of rare earth metals (REM) possess several applications in science and technology (production of REMs, their alloys and compounds, dyes for glass, ceramic, and toners, solid electrolytes for batteries, catalyzers of organic reactions and polymerizations, materials for optics, laser, and fluorescence, materials for hydrogen storage and ion-sensitive electrodes). This report attempts to collect and systematize the experimental results which are, unfortunately, very scattered.

This volume will be published in three parts:

1. Part 1: Scandium group (Sc, Y, La); this paper

2. Part 2: Light lanthanides (Ce–Eu)

3. Part 3: Heavy lanthanides (Gd–Lu)

The work in this first part presents an assessment of solubility data for rare earth metal fluorides (generally of trivalent metals and of CeF4) in water and in aqueous ternary systems. Compilations of all available experimental data are introduced for each rare earth metal fluoride with a corresponding critical evaluation. Every such evaluation contains a collection of all solubility results in water, a selection of suggested solubility data, and a brief discussion of the multicomponent systems. Because the ternary systems were seldom studied more than once, no critical evaluations of such data were possible. Only simple fluorides (no complexes or binary salts) are treated as the input substances in this report. The literature has been covered through the end of 2013.

http://dx.doi.org/10.1063/1.4866773

To access recent volumes in the Solubility Data Series, visit http://jpcrd.aip.org/ and search IUPAC-NIST Solubility Data Series.

Online erschienen: 2014-7-17
Erschienen im Druck: 2014-7-1

©2014 by Walter de Gruyter GmbH & Co.

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https://doi.org/10.1515/ci.2014.36.4.20b

Articles in the same Issue

  1. Masthead - Full issue pdf
  2. From the Editor
  3. Contents
  4. Officer’s Column
  5. Quo vadis—“Whither thou goest?”
  6. Features
  7. Collaborative Research Funding
  8. An Experience in the Digital Age
  9. Youth Views on Sustainability
  10. IUPAC Wire
  11. Increasing IUPAC’s Footprint in Latin America
  12. Jan-Willem Toering Appointed Director of the Royal Netherlands Chemical Society
  13. Future Earth Launches New Website
  14. The 2014 Thieme-IUPAC Prize Goes to Martin Burke
  15. The Project Place
  16. Recommended Methods for the Structural Identification of Biologically Active Compounds in Food and Flavor Chemistry
  17. Terminology for Separation of Macromolecules
  18. Methods for the SI Value Assignment of the Purity of Organic Compounds for use as Primary Reference Materials and Calibrators
  19. Glossary on Renewable Chemistry
  20. Successful Drug Discoveries
  21. Metrological Traceability of Measurement Results in Chemistry: basic concepts required for intercontinental communication of results
  22. Great Lakes Regional Workshop
  23. Making an imPACt
  24. Alcohols + Hydrocarbons + Water
  25. ICTAC nomenclature of thermal analysis (IUPAC Recommendations 2014)
  26. A database of water transitions from experiment and theory (IUPAC Technical Report)
  27. Definition of the transfer coefficient in electrochemistry (IUPAC Recommendations 2014)
  28. Assessment of international reference materials for isotope-ratio analysis (IUPAC Technical Report)
  29. Rare Earth Metal Fluorides in Water and Aqueous Systems
  30. Bookworm
  31. New Edition of the “IUPAC Blue Book”Nomenclature of Organic Chemistry—IUPAC Recommendations and Preferred Names 2013
  32. Laboratory Statistics, Handbook of Formulas and Terms
  33. Future Energy: Improved, Sustainable and Clean Options for our Planet, 2nd Edition
  34. Polymers and Materials
  35. Polymer-Solvent Complexes and Intercalates POLYSOLVAT–9
  36. Marie Curie’s Family: the Spirit and the Letter
  37. NOTeS
  38. Symbols of the Elements, Part III (concluded)*
  39. On the Naming and Symbols for Elements 115 and 112
  40. Stamps International
  41. The Heart and Soul of Turmeric
  42. Conference Call
  43. Scoping the Future of Education in Chemistry
  44. Frontiers of Polymers and Advanced Materials
  45. Chemistry Conference for Young Scientists
  46. Where 2B & Y
  47. High Resolution Spectroscopy
  48. Green Chemistry
  49. Macro and Supramolecular Architectures and Materials
  50. Analytical Chemistry
  51. Mark Your Calendar
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