Polymeric ionic liquids: a strategy for preparation of novel polymeric materials
-
Manoochehr Farzin
,
Keyvan Nosratzadegan
Abstract
A novel polymeric ionic liquid (PIL), bearing high C-N and N-N content, potentially suitable for new safe energetic materials and catalyst supports was introduced. The PIL was prepared by way of radical co-polymerisation of 1-vinyl-3-p-nitrobenzylimidazolium bromide and 1-vinylimidazole at 80◦C using azobisisobutyronitrile (AIBN) as an initiator. The PIL thus produced was successfully transformed into NO3@PIL and N3@PIL for potential application as safe energetic materials and/or catalyst supports. The polymers were obtained in quantitative yields and were characterised by NMR, FTIR, DSC and TGA data. This study reveals the adequate thermal stability of novel salt-based nitrogen-rich polymeric ionic liquids for application as safe energetic materials and/or supports in heterogeneous catalysis.
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Artikel in diesem Heft
- Selective catalytic oxidation of ammonia into nitrogen and water vapour over transition metals modified Al2O3, TiO2 and ZrO2
- Carbonylation of cyclohexene to 2-cyclohexene-1-one by montmorillonite-supported Co(II) catalysts
- Ni-based olivine-type catalysts and their application in hydrogen production via auto-thermal reforming of acetic acid
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- Reaction kinetics of malachite in ammonium carbamate solution
- Bioleaching of hazardous waste
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- Effect of process parameters on the concentration, current efficiency and energy consumption of electro-generated silver(II)
- A facile, highly efficient and novel method for synthesis of 5-substituted 1H-tetrazoles catalysed by copper(I) chloride
- A new procedure for the synthesis of 2-[(4-dodecyloxyphenyl)sulfonyl]butanoic acid
- Formation of a vanillic Mannich base – theoretical study
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