Mechanisms of TMP peroxide bleaching using Mg-based alkalis
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Liliane Savoye
,
Michel Petit-Conil
Abstract
The driving force for pulp and paper industry is to develop new technologies with less impact to the environment. In this context, the successful approach in the present paper was the substitution of sodium hydroxide during peroxide bleaching of thermomechanical pulp (TMP) by magnesium hydroxide or magnesium carbonate. Looking at brightening development, thioacidolysis showed that Mg-based processes eliminated less coniferaldehydes than NaOH-based bleaching. Moreover, 19F NMR analysis showed slightly more residual quinone in lignin isolated from NaOH-based bleached pulp than lignin extracted after Mg-based bleaching. Replacing NaOH by Mg-based compounds affected the strength properties of the paper: tensile index was 10% lower than conventional bleached paper, probably due to Mg2+ adsorption on the acid groups of fibers. However, the brightness reversion of Mg-based bleached paper decreased by about two ISO points during photoageing under sunlight. X-ray photoelectron spectroscopy supported the conclusion that Mg-based bleaching caused less re-deposition of lignin and extractives onto the fiber surface compared to the conventional process resulting in less light-induced yellowing.
©2011 by Walter de Gruyter Berlin Boston
Articles in the same Issue
- Original Papers
- Fundamental understanding of pulp property development under different thermomechanical pulp refining conditions as observed by a new Simons’ staining method and SEM observation of the ultrastructure of fibre surfaces
- Enhancing dewatering of thermo-mechanical pulp (TMP) based papermaking through enzymatic treatment
- Mechanisms of TMP peroxide bleaching using Mg-based alkalis
- Properties of wood chips for thermomechanical pulp (TMP) production as a function of spout angle
- Determination of local material properties of OSB sample by coupling advanced imaging techniques and morphology-based FEM simulation
- Combined bound water and water vapour diffusion of Norway spruce and European beech in and between the principal anatomical directions
- Oxygen plasma-treated enzymatic hydrolysis lignin as a natural binder for manufacturing biocomposites
- Influence of the adhesive formulation on the mechanical properties and bonding performance of polyurethane prepolymers
- Characterizing perpendicular-to-grain compression (C⊥) behavior in wood construction
- Predicting the strength of Populus spp. clones using artificial neural networks and ε-regression support vector machines (ε-rSVM)
- X-ray scattering and microtomography study on the structural changes of never-dried silver birch, European aspen and hybrid aspen during drying
- Equilibrium moisture content (EMC) in Norway spruce during the first and second desorptions
- Fungal degradation of bamboo samples
- qPCR as a tool to study basidiomycete colonization in wooden field stakes
- Meetings
- Meetings
Articles in the same Issue
- Original Papers
- Fundamental understanding of pulp property development under different thermomechanical pulp refining conditions as observed by a new Simons’ staining method and SEM observation of the ultrastructure of fibre surfaces
- Enhancing dewatering of thermo-mechanical pulp (TMP) based papermaking through enzymatic treatment
- Mechanisms of TMP peroxide bleaching using Mg-based alkalis
- Properties of wood chips for thermomechanical pulp (TMP) production as a function of spout angle
- Determination of local material properties of OSB sample by coupling advanced imaging techniques and morphology-based FEM simulation
- Combined bound water and water vapour diffusion of Norway spruce and European beech in and between the principal anatomical directions
- Oxygen plasma-treated enzymatic hydrolysis lignin as a natural binder for manufacturing biocomposites
- Influence of the adhesive formulation on the mechanical properties and bonding performance of polyurethane prepolymers
- Characterizing perpendicular-to-grain compression (C⊥) behavior in wood construction
- Predicting the strength of Populus spp. clones using artificial neural networks and ε-regression support vector machines (ε-rSVM)
- X-ray scattering and microtomography study on the structural changes of never-dried silver birch, European aspen and hybrid aspen during drying
- Equilibrium moisture content (EMC) in Norway spruce during the first and second desorptions
- Fungal degradation of bamboo samples
- qPCR as a tool to study basidiomycete colonization in wooden field stakes
- Meetings
- Meetings
