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Oxygen plasma-treated enzymatic hydrolysis lignin as a natural binder for manufacturing biocomposites

  • Xiaoyan Zhou EMAIL logo , Lijuan Tang , Fei Zheng , Gi Xue , Guanben Du , Weidong Zhang , Chenglong Lv , Qiang Yong , Rong Zhang , Bijun Tang and Xueyuan Liu
Published/Copyright: May 29, 2011
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Holzforschung
From the journal Volume 65 Issue 6

Abstract

This paper describes the investigation of the oxygen plasma treatment of enzymatic hydrolysis lignin (EHL) that was obtained from the lignocellulosic ethanol production pro- cesses. The application of EHL as a natural binder for biocomposite product manufacturing was in focus. To understand the effects of oxygen plasma treatment, the chemical changes on the surface of EHL were evaluated by Fourier transform infrared (FTIR) spectroscopy, X-ray photo-electron spectroscopy (XPS), and electron spin resonance (ESR) spectroscopy. Adding EHL into the cotton-stalk fiberboards has a beneficial effect on physical and mechanical properties. Moreover, adding oxygen plasma-treated EHL produced a 69.2% increase of internal bond strength (IB), a 78.2% increase of modulus of rupture (MOR), and a 49.8% reduction of thickness swelling (TS). The bonding improvement was probably due to the generation of more oxygen-related functional groups and free radicals on the surface of EHL after the oxygen plasma treatment.


Corresponding author. College of Wood Science and Technology, Nanjing Forestry University, No. 159 Longpan Road, Jiangsu, Nanjing 210037, China Phone: +86-854-285-06 Fax: +86-854-275-17

Received: 2010-11-2
Accepted: 2011-4-12
Published Online: 2011-05-29
Published Online: 2011-05-30
Published in Print: 2011-10-01

©2011 by Walter de Gruyter Berlin Boston

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