Material properties and their interrelation in chemically modified clear wood of Scots pine
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Hannah Epmeier
Abstract
The mechanical and physical properties of modified wood were assessed experimentally. Timber studs with a cross-section of 45 mm×70 mm were modified on a semi-industrial scale by four different methods: 1) acetylation (AC) with acetic anhydride; 2) modification with methylated melamine formaldehyde resin (MMF); 3) heat treatment in vegetable oil (HT); and 4) furfurylation (FA). Sapwood of Scots pine (Pinus sylvestris) with test specimen dimensions of 10×10×200 mm3 was investigated. A total of 2449 specimens were included in the study. The following properties and their correlations were studied: density, modulus of elasticity (MOEdyn) measured dynamically, equilibrium moisture content (EMC), and swelling behaviour. The properties were measured at humidity levels of 30%, 65%, and 90% RH, while the temperature was kept constant at 23°C. Significant changes in material properties took place. AC increased the density and reduced MOEdyn, EMC and swelling strain. FA increased the density and the swelling coefficient and reduced EMC and swelling strain. HT reduced the EMC, while MMF modification increased it.
References
Bengtsson, C. (2001). Variation of moisture induced movements in Norway spruce. Ann. For. Sci.58:569–581.Search in Google Scholar
Bodig, J., Jayne, B.A. Mechanics of Wood and Wood Composite. Krieger, Malabar, FL, 1992.Search in Google Scholar
European standard (1995) EN 384, Structural timber – determination of characteristic values of mechanical properties and density.Search in Google Scholar
Epmeier, H. (2003) Properties of chemically modified wood. Licentiate of Engineering thesis. Chalmers University of Technology, Göteborg, Sweden.Search in Google Scholar
Epmeier, H., Kliger, R. (2005) Experimental study of material properties of modified Scots pine. Holz Roh Werkst.63:430–436.10.1007/s00107-005-0019-2Search in Google Scholar
Epmeier, H., Westin, M., Rapp, A.O. (2004) Differently modified wood: Comparison of some selected properties. Scand. J. For. Res.19(Suppl. 5):1–7.10.1080/02827580410017825Search in Google Scholar
Evans, P.D., Wallis, A.F.A., Owen, N.L. (2000) Weathering of chemically modified wood surfaces – Natural weathering of Scots pine acetylated to different weight gains. Wood Sci. Technol.34:151–165.10.1007/s002260000039Search in Google Scholar
Holz-Lexikon. DRW-Verlag, Stuttgart, 1993.Search in Google Scholar
Ilic, J. (2001) Relationship among the dynamic and elastic properties of air-dry Eucalyptus delegatensis R. Baker. Holz Roh Werkst.59:169–175.10.1007/s001070100198Search in Google Scholar
Larsson, P., Simonson, R. (1994) A study of strength, hardness and deformation of acetylated Scandinavian softwoods. Holz Roh Werkst.52:83–86.10.1007/BF02615470Search in Google Scholar
Niemz, P., Sonderegger, W. (2003) Untersuchungen zur Korrelation ausgewählter Holzeigenschaften untereinander und mit der Rohdicht unter Verwendung von 103 Holzarten. Schweiz. Z. Forstwesen154:12:489–493.10.3188/szf.2003.0489Search in Google Scholar
Papadopoulos, A.N., Hill, C.A.S. (2003) The sorption of water vapour by anhydride modified softwood. Wood Sci. Technol.37:221–231.10.1007/s00226-003-0192-6Search in Google Scholar
Rapp, A. (1999) Physikalische und biologische Vergütung von Vollholz mit wasserverdünnbaren Harzen [Improvement of physical and biological properties of wood by water-based resins]. Ph.D. thesis. Hamburg University, Hamburg.Search in Google Scholar
Rowell, R.M., Tillman, A.M., Simonson, R. (1986a) A simplified procedure for acetylation of hardwood and softwood flakes for flakeboard production. J. Wood Chem. Technol.6:427–448.10.1080/02773818608085236Search in Google Scholar
Rowell, R.M., Simonson, R., Tillman, A.M. (1986b) A simplified procedure for acetylation of chips for dimensionally stabilized particleboard products. Pap. Puu68:740–744.Search in Google Scholar
Sailer, M., Rapp, A.O., Leithoff, H., Peek, R.-D. (2000) Vergütung von Holz durch Anwendung einer Öl-Hitzbehandlung. Holz Roh Werkst.58:15–22.10.1007/s001070050379Search in Google Scholar
Suchsland, O. (2004) The swelling and shrinkage of wood. A practical technology primer. Forest Product Society, Madison, WI, USA.Search in Google Scholar
Tjeerdsma, B.F., Boonstra, M., Pizzi, A., Tekely, P., Militz, H. (1998) Characterisation of thermally modified wood: molecular reasons for wood performance improvement. Holz Roh Werkst.56:149–153.10.1007/s001070050287Search in Google Scholar
Van Acker, J., Stevens, M. (1998) The impact of resin treatments on the mechanical properties of solid wood. In: Proceedings of COST Action 8, Mechanical Performance of Wood and Wood Products, workshop on mechanical performance on non-standard wood, Florence, Italy.Search in Google Scholar
Wagenführ, R. Holzatlas. Fachbuchverlag, Leipzig, 1996.Search in Google Scholar
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Articles in the same Issue
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Articles in the same Issue
- MWL fraction with a high concentration of lignin-carbohydrate linkages: Isolation and 2D NMR spectroscopic analysis
- Papermaking properties of the ECF-bleached kraft pulps from first-thinning Scots pine (Pinus sylvestris L.)
- Syntheses and properties of liquefied products of ozone treated wood/epoxy resins having high wood contents
- Quality control of thermally modified timber: Interrelationship between heat treatment intensities and CIE L*a*b* color data on homogenized wood samples
- Violet light causes photodegradation of wood beyond the zone affected by ultraviolet radiation
- Dynamic mechanical analysis of dry wood: Linear viscoelastic response region and effects of minor moisture changes
- Material properties and their interrelation in chemically modified clear wood of Scots pine
- Effect of treatments with 1,3-dimethylol-4,5-dihydroxy-ethyleneurea (DMDHEU) on the tensile properties of wood
- Penetration of amino-silicone micro- and macro-emulsions into Scots pine sapwood and the effect on water-related properties
- Search for a relationship between stress wave velocity and internal stresses in eucalypts and radiata pine
- Kiln-drying lumber quality of hybrid poplar clones
- Heat and mass transfer in wood composite panels during hot pressing: Part 3. Predicted variations and interactions of the pressing variables
- Heat and mass transfer in wood composite panels during hot pressing: Part 4. Experimental investigation and model validation
- Dielectric relaxation of water adsorbed on wood and charcoal
- Properties of piezoelectric voltage considering the microscopic structure of wood cell walls
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- External and internal fungal flora of pine sapwood (Pinus sylvestris L.) specimens in above-ground field tests at six different sites in south-west Germany
- Award Presentation on the occasion of the European Workshop on Lignocellulosics and Pulp (EWLP 2006) in Vienna
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