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4.2 Complexes with Amino Acids

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Modern Syntheses of Cobalt (III) Complexes
This chapter is in the book Modern Syntheses of Cobalt (III) Complexes
© 2022 Walter de Gruyter GmbH, Berlin/Munich/Boston

© 2022 Walter de Gruyter GmbH, Berlin/Munich/Boston

Chapters in this book

  1. Frontmatter I
  2. Preface IX
  3. Table of Contents XI
  4. Abbreviations 1
  5. 1 Some Modern Methods of General Syntheses
  6. 1.1 Significance of Preparative Work 4
  7. 1.2 Complexes with Flexible Quadridentate Ligands 7
  8. 1.3 Complexes with Macrocyclic Quadridentate Ligand 13
  9. 1.4 Complexes Containing α,ω-Alkanediamines 17
  10. 1.5 Mixed Cyano Complexes 19
  11. 1.6 References 24
  12. 2 Versatile Uses of Tricarbonatocobaltate(III) as Starting Material
  13. 2.1 Historical 26
  14. 2.2 Tricarbonatocobaltate(III) Anion 27
  15. 2.3 Systematic Synthesis of Complexes 30
  16. 2.4 General Syntheses of Tris(bidentate) Complexes 33
  17. 2.5 General Syntheses of Amino Acid Complexes 34
  18. 2.6 Binuclear Complexes 37
  19. 2.7 Heteropoly Electrolytes 39
  20. 2.8 Reaction Kinetics Concerning Tricarbonatocobaltate(III) 41
  21. 2.9 References 43
  22. 3 Preparative Application of Chromatography
  23. 3.1 Introduction 46
  24. 3.2 Chromatography on Ion-Exchange Resins 47
  25. 3.3 Chromatography on Ion-Exchange Cellulose or Ion-Exchange Dextran 56
  26. 3.4 Chromatography using Cellulose Powder, Paper, or Alumina 63
  27. 3.5 References 66
  28. 4 Stereoselectivity in Complexes with Less Puckered Chelate Rings
  29. 4.1 Historical Background 69
  30. 4.2 Complexes with Amino Acids 70
  31. 4.3 Optically Active Aspartate Containing Complexes 74
  32. 4.4 Mixed Diamine-Amino Acid Complexes 78
  33. 4.5 Dipeptide Complexes 80
  34. 4.6 Tris-Complexes of 3-Substituted Camphor 82
  35. 4.7 Complexes Containing Optically Active Tartaric Acid 84
  36. 4.8 References 85
  37. 5 Design of Low Symmetry Complexes
  38. 5.1 Introduction 87
  39. 5.2 Complexes Exhibiting Marked Splitting in the Second Absorption Bands 87
  40. 5.3 Complexes with Optical Activity Due to Unidentate Ligands 97
  41. 5.4 Chiral Complexes of the [Co(0)4(N)2]-and [Co(0)2(N)4]+Types 107
  42. 5.5 References 114
https://doi.org/10.1515/9783112620908-024

Chapters in this book

  1. Frontmatter I
  2. Preface IX
  3. Table of Contents XI
  4. Abbreviations 1
  5. 1 Some Modern Methods of General Syntheses
  6. 1.1 Significance of Preparative Work 4
  7. 1.2 Complexes with Flexible Quadridentate Ligands 7
  8. 1.3 Complexes with Macrocyclic Quadridentate Ligand 13
  9. 1.4 Complexes Containing α,ω-Alkanediamines 17
  10. 1.5 Mixed Cyano Complexes 19
  11. 1.6 References 24
  12. 2 Versatile Uses of Tricarbonatocobaltate(III) as Starting Material
  13. 2.1 Historical 26
  14. 2.2 Tricarbonatocobaltate(III) Anion 27
  15. 2.3 Systematic Synthesis of Complexes 30
  16. 2.4 General Syntheses of Tris(bidentate) Complexes 33
  17. 2.5 General Syntheses of Amino Acid Complexes 34
  18. 2.6 Binuclear Complexes 37
  19. 2.7 Heteropoly Electrolytes 39
  20. 2.8 Reaction Kinetics Concerning Tricarbonatocobaltate(III) 41
  21. 2.9 References 43
  22. 3 Preparative Application of Chromatography
  23. 3.1 Introduction 46
  24. 3.2 Chromatography on Ion-Exchange Resins 47
  25. 3.3 Chromatography on Ion-Exchange Cellulose or Ion-Exchange Dextran 56
  26. 3.4 Chromatography using Cellulose Powder, Paper, or Alumina 63
  27. 3.5 References 66
  28. 4 Stereoselectivity in Complexes with Less Puckered Chelate Rings
  29. 4.1 Historical Background 69
  30. 4.2 Complexes with Amino Acids 70
  31. 4.3 Optically Active Aspartate Containing Complexes 74
  32. 4.4 Mixed Diamine-Amino Acid Complexes 78
  33. 4.5 Dipeptide Complexes 80
  34. 4.6 Tris-Complexes of 3-Substituted Camphor 82
  35. 4.7 Complexes Containing Optically Active Tartaric Acid 84
  36. 4.8 References 85
  37. 5 Design of Low Symmetry Complexes
  38. 5.1 Introduction 87
  39. 5.2 Complexes Exhibiting Marked Splitting in the Second Absorption Bands 87
  40. 5.3 Complexes with Optical Activity Due to Unidentate Ligands 97
  41. 5.4 Chiral Complexes of the [Co(0)4(N)2]-and [Co(0)2(N)4]+Types 107
  42. 5.5 References 114
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