10 Interaction of Cyanide with Enzymes Containing Vanadium, Manganese, Non-Heme Iron, and Zinc

Chapters in this book

1. Frontmatter I
2. Historical Development and Perspectives of the Series V
3. Preface to Volume 6: Metal-Carbon Bonds in Enzymes and Cofactors VII
4. Contents XI
5. Contributors to Volume 6 XVII
6. Titles of Volumes 1–44 in the Metal Ions in Biological Systems Series XIX
7. 1 Organometallic Chemistry of B₁₂ Coenzymes 1
8. 2 Cobalamin- and Corrinoid-Dependent Enzymes 53
9. 3 Nickel-Alkyl Bond Formation in the Active Site of Methyl-Coenzyme M Reductase 115
10. 4 Nickel-Carbon Bonds in Acetyl-Coenzyme A Synthases/Carbon Monoxide Dehydrogenases 133
11. 5 Structure and Function of [NiFe]-Hydrogenases 151
12. 6 Carbon Monoxide and Cyanide Ligands in the Active Site of [FeFe]-Hydrogenases 179
13. 7 Carbon Monoxide as Intrinsic Ligand to Iron in the Active Site of [Fe]-Hydrogenase 219
14. 8 The Dual Role of Heme as Cofactor and Substrate in the Biosynthesis of Carbon Monoxide 241
15. 9 Copper-Carbon Bonds in Mechanistic and Structural Probing of Proteins as well as in Situations where Copper is a Catalytic or Receptor Site 295
16. 10 Interaction of Cyanide with Enzymes Containing Vanadium, Manganese, Non-Heme Iron, and Zinc 363
17. 11 The Reaction Mechanism of the Molybdenum Hydroxylase Xanthine Oxidoreductase: Evidence Against the Formation of Intermediates Having Metal-Carbon Bonds 395
18. 12 Computational Studies of Bioorganometallic Enzymes and Cofactors 417
19. Subject Index 461
20. Author Index of Contributors to MIBS and MILS 497