Artikel
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New cyclizations via catalytic ruthenium vinylidenes
-
Jesús A. Varela
Veröffentlicht/Copyright:
1. Januar 2009
Published Online: 2009-01-01
Published in Print: 2008-01-01
© 2013 Walter de Gruyter GmbH, Berlin/Boston
Artikel in diesem Heft
- Preface
- 1,4-Additions of arylboron, -silicon, and -bismuth compounds to α,β-unsaturated carbonyl compounds catalyzed by dicationic palladium(II) complexes
- OMCOS for functional polymers - double-stranded DNA-like polymers
- Organometallic catalysts in synthetic organic chemistry: From reactions in aqueous media to gold catalysis
- Reaction of alcohols and silyl ethers in the presence of an indium/silicon-based catalyst system: Deoxygenation and allyl substitution
- Catalysts through self-assembly for combinatorial homogeneous catalysis
- Ruthenium catalysts for selective nucleophilic allylic substitution
- Evaluation of catalytic activity of copper salts and their removal processes in the three-component coupling reactions
- New methods in asymmetric catalysis based on new hemi-labile bidentate ligands
- Catalytic enantioselective Reformatsky reactions
- Metal carbonyl complexes and chirality
- New preparative methods for allylic boronates and their application in stereoselective catalytic allylborations
- Nickel-catalyzed coupling reactions of alkenes
- Carbon-carbon bond-forming reactions using alkyl fluorides
- Asymmetric synthesis: From transition metals to organocatalysis
- Enantio- and regioselective CpRu-catalyzed Carroll rearrangement
- Palladium-catalyzed selective activation of allyl alcohols as allyl cations, allyl anions, and zwitterionic trimethylenemethanes
- Transition-metal-catalyzed synthesis of organosulfur compounds
- New synthetic methodologies based on active transition metals
- Asymmetric Lewis acid-catalyzed 1,3-dipolar cycloadditions
- Application of rhodium-catalyzed cyclohydrocarbonylation to the syntheses of enantiopure homokainoids
- Copper-catalyzed asymmetric allylic substitution reactions with organozinc and Grignard reagents
- Copper-catalyzed substitution of allylic carbonates with diboron: A new approach to allylboronate synthesis
- Hydrogenation of polar functionalities with Cp*Ru(PN) catalysts
- Cu(I)-catalyzed asymmetric allylation of ketones and ketimines
- Golden opportunities in catalysis
- Asymmetric epoxidation of olefins catalyzed by Ti(salan) complexes using aqueous hydrogen peroxide as the oxidant
- Rhodium-catalyzed CO gas-free carbonylative cyclization using aldehydes
- First palladium- and nickel-catalyzed oxidative diamination of alkenes: Cyclic urea, sulfamide, and guanidine building blocks
- Nickel-catalyzed carbocyanation of alkynes
- Asymmetric synthesis of planar-chiral ferrocenes by Mo- or Ru-catalyzed enantioselective metathesis
- Nickel-catalyzed [2+2+2] cycloaddition of two alkynes and an imine
- Rhodium- and iridium-catalyzed oxidative coupling of benzoic acids with alkynes and alkenes
- γ-Methylidene-δ-valerolactones as a coupling partner for cycloaddition: Palladium-catalyzed [4+3] cycloaddition with nitrones
- Toward the total synthesis of ritterazine N
- Rhenium-catalyzed synthesis of indene derivatives via C-H bond activation
- New hydrosilylation reaction of arylacetylene accompanied by C-H bond activation catalyzed by a xantsil ruthenium complex
- Palladium-catalyzed cross-addition of triisopropylsilylacetylene to unactivated alkynes
- New cyclizations via catalytic ruthenium vinylidenes
- Cationic palladium-catalyzed hydrosilylative cross-coupling of alkynes with alkenes forming 4-silylated-1-butene frameworks
- Boryllithium: A novel boron nucleophile and its application in the synthesis of borylmetal complexes
Schlagwörter für diesen Artikel
carbocycles;
cyclizations;
metal-vinylidenes;
nucleophilic additions;
pericyclic reactions
Artikel in diesem Heft
- Preface
- 1,4-Additions of arylboron, -silicon, and -bismuth compounds to α,β-unsaturated carbonyl compounds catalyzed by dicationic palladium(II) complexes
- OMCOS for functional polymers - double-stranded DNA-like polymers
- Organometallic catalysts in synthetic organic chemistry: From reactions in aqueous media to gold catalysis
- Reaction of alcohols and silyl ethers in the presence of an indium/silicon-based catalyst system: Deoxygenation and allyl substitution
- Catalysts through self-assembly for combinatorial homogeneous catalysis
- Ruthenium catalysts for selective nucleophilic allylic substitution
- Evaluation of catalytic activity of copper salts and their removal processes in the three-component coupling reactions
- New methods in asymmetric catalysis based on new hemi-labile bidentate ligands
- Catalytic enantioselective Reformatsky reactions
- Metal carbonyl complexes and chirality
- New preparative methods for allylic boronates and their application in stereoselective catalytic allylborations
- Nickel-catalyzed coupling reactions of alkenes
- Carbon-carbon bond-forming reactions using alkyl fluorides
- Asymmetric synthesis: From transition metals to organocatalysis
- Enantio- and regioselective CpRu-catalyzed Carroll rearrangement
- Palladium-catalyzed selective activation of allyl alcohols as allyl cations, allyl anions, and zwitterionic trimethylenemethanes
- Transition-metal-catalyzed synthesis of organosulfur compounds
- New synthetic methodologies based on active transition metals
- Asymmetric Lewis acid-catalyzed 1,3-dipolar cycloadditions
- Application of rhodium-catalyzed cyclohydrocarbonylation to the syntheses of enantiopure homokainoids
- Copper-catalyzed asymmetric allylic substitution reactions with organozinc and Grignard reagents
- Copper-catalyzed substitution of allylic carbonates with diboron: A new approach to allylboronate synthesis
- Hydrogenation of polar functionalities with Cp*Ru(PN) catalysts
- Cu(I)-catalyzed asymmetric allylation of ketones and ketimines
- Golden opportunities in catalysis
- Asymmetric epoxidation of olefins catalyzed by Ti(salan) complexes using aqueous hydrogen peroxide as the oxidant
- Rhodium-catalyzed CO gas-free carbonylative cyclization using aldehydes
- First palladium- and nickel-catalyzed oxidative diamination of alkenes: Cyclic urea, sulfamide, and guanidine building blocks
- Nickel-catalyzed carbocyanation of alkynes
- Asymmetric synthesis of planar-chiral ferrocenes by Mo- or Ru-catalyzed enantioselective metathesis
- Nickel-catalyzed [2+2+2] cycloaddition of two alkynes and an imine
- Rhodium- and iridium-catalyzed oxidative coupling of benzoic acids with alkynes and alkenes
- γ-Methylidene-δ-valerolactones as a coupling partner for cycloaddition: Palladium-catalyzed [4+3] cycloaddition with nitrones
- Toward the total synthesis of ritterazine N
- Rhenium-catalyzed synthesis of indene derivatives via C-H bond activation
- New hydrosilylation reaction of arylacetylene accompanied by C-H bond activation catalyzed by a xantsil ruthenium complex
- Palladium-catalyzed cross-addition of triisopropylsilylacetylene to unactivated alkynes
- New cyclizations via catalytic ruthenium vinylidenes
- Cationic palladium-catalyzed hydrosilylative cross-coupling of alkynes with alkenes forming 4-silylated-1-butene frameworks
- Boryllithium: A novel boron nucleophile and its application in the synthesis of borylmetal complexes