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    1,4-Additions of arylboron, -silicon, and -bismuth compounds to α,β-unsaturated carbonyl compounds catalyzed by dicationic palladium(II) complexes
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        Yasunori Yamamoto
        
 , Takashi Nishikata and Norio Miyaura 
                            Published/Copyright:
                            
                                January 1, 2009
                            
                        
                    
                
            
  Published Online: 2009-01-01
 
 
  Published in Print: 2008-01-01
 
© 2013 Walter de Gruyter GmbH, Berlin/Boston
Articles in the same Issue
- Preface
 - 1,4-Additions of arylboron, -silicon, and -bismuth compounds to α,β-unsaturated carbonyl compounds catalyzed by dicationic palladium(II) complexes
 - OMCOS for functional polymers - double-stranded DNA-like polymers
 - Organometallic catalysts in synthetic organic chemistry: From reactions in aqueous media to gold catalysis
 - Reaction of alcohols and silyl ethers in the presence of an indium/silicon-based catalyst system: Deoxygenation and allyl substitution
 - Catalysts through self-assembly for combinatorial homogeneous catalysis
 - Ruthenium catalysts for selective nucleophilic allylic substitution
 - Evaluation of catalytic activity of copper salts and their removal processes in the three-component coupling reactions
 - New methods in asymmetric catalysis based on new hemi-labile bidentate ligands
 - Catalytic enantioselective Reformatsky reactions
 - Metal carbonyl complexes and chirality
 - New preparative methods for allylic boronates and their application in stereoselective catalytic allylborations
 - Nickel-catalyzed coupling reactions of alkenes
 - Carbon-carbon bond-forming reactions using alkyl fluorides
 - Asymmetric synthesis: From transition metals to organocatalysis
 - Enantio- and regioselective CpRu-catalyzed Carroll rearrangement
 - Palladium-catalyzed selective activation of allyl alcohols as allyl cations, allyl anions, and zwitterionic trimethylenemethanes
 - Transition-metal-catalyzed synthesis of organosulfur compounds
 - New synthetic methodologies based on active transition metals
 - Asymmetric Lewis acid-catalyzed 1,3-dipolar cycloadditions
 - Application of rhodium-catalyzed cyclohydrocarbonylation to the syntheses of enantiopure homokainoids
 - Copper-catalyzed asymmetric allylic substitution reactions with organozinc and Grignard reagents
 - Copper-catalyzed substitution of allylic carbonates with diboron: A new approach to allylboronate synthesis
 - Hydrogenation of polar functionalities with Cp*Ru(PN) catalysts
 - Cu(I)-catalyzed asymmetric allylation of ketones and ketimines
 - Golden opportunities in catalysis
 - Asymmetric epoxidation of olefins catalyzed by Ti(salan) complexes using aqueous hydrogen peroxide as the oxidant
 - Rhodium-catalyzed CO gas-free carbonylative cyclization using aldehydes
 - First palladium- and nickel-catalyzed oxidative diamination of alkenes: Cyclic urea, sulfamide, and guanidine building blocks
 - Nickel-catalyzed carbocyanation of alkynes
 - Asymmetric synthesis of planar-chiral ferrocenes by Mo- or Ru-catalyzed enantioselective metathesis
 - Nickel-catalyzed [2+2+2] cycloaddition of two alkynes and an imine
 - Rhodium- and iridium-catalyzed oxidative coupling of benzoic acids with alkynes and alkenes
 - γ-Methylidene-δ-valerolactones as a coupling partner for cycloaddition: Palladium-catalyzed [4+3] cycloaddition with nitrones
 - Toward the total synthesis of ritterazine N
 - Rhenium-catalyzed synthesis of indene derivatives via C-H bond activation
 - New hydrosilylation reaction of arylacetylene accompanied by C-H bond activation catalyzed by a xantsil ruthenium complex
 - Palladium-catalyzed cross-addition of triisopropylsilylacetylene to unactivated alkynes
 - New cyclizations via catalytic ruthenium vinylidenes
 - Cationic palladium-catalyzed hydrosilylative cross-coupling of alkynes with alkenes forming 4-silylated-1-butene frameworks
 - Boryllithium: A novel boron nucleophile and its application in the synthesis of borylmetal complexes
 
Keywords for this article
                        
                            arylboron compounds;
                        
                            asymmetric 1,4-addition;
                        
                            dicationic Pd catalyst;
                        
                            enantioselection mechanism;
                        
                            transmetallation
                        
                    Articles in the same Issue
- Preface
 - 1,4-Additions of arylboron, -silicon, and -bismuth compounds to α,β-unsaturated carbonyl compounds catalyzed by dicationic palladium(II) complexes
 - OMCOS for functional polymers - double-stranded DNA-like polymers
 - Organometallic catalysts in synthetic organic chemistry: From reactions in aqueous media to gold catalysis
 - Reaction of alcohols and silyl ethers in the presence of an indium/silicon-based catalyst system: Deoxygenation and allyl substitution
 - Catalysts through self-assembly for combinatorial homogeneous catalysis
 - Ruthenium catalysts for selective nucleophilic allylic substitution
 - Evaluation of catalytic activity of copper salts and their removal processes in the three-component coupling reactions
 - New methods in asymmetric catalysis based on new hemi-labile bidentate ligands
 - Catalytic enantioselective Reformatsky reactions
 - Metal carbonyl complexes and chirality
 - New preparative methods for allylic boronates and their application in stereoselective catalytic allylborations
 - Nickel-catalyzed coupling reactions of alkenes
 - Carbon-carbon bond-forming reactions using alkyl fluorides
 - Asymmetric synthesis: From transition metals to organocatalysis
 - Enantio- and regioselective CpRu-catalyzed Carroll rearrangement
 - Palladium-catalyzed selective activation of allyl alcohols as allyl cations, allyl anions, and zwitterionic trimethylenemethanes
 - Transition-metal-catalyzed synthesis of organosulfur compounds
 - New synthetic methodologies based on active transition metals
 - Asymmetric Lewis acid-catalyzed 1,3-dipolar cycloadditions
 - Application of rhodium-catalyzed cyclohydrocarbonylation to the syntheses of enantiopure homokainoids
 - Copper-catalyzed asymmetric allylic substitution reactions with organozinc and Grignard reagents
 - Copper-catalyzed substitution of allylic carbonates with diboron: A new approach to allylboronate synthesis
 - Hydrogenation of polar functionalities with Cp*Ru(PN) catalysts
 - Cu(I)-catalyzed asymmetric allylation of ketones and ketimines
 - Golden opportunities in catalysis
 - Asymmetric epoxidation of olefins catalyzed by Ti(salan) complexes using aqueous hydrogen peroxide as the oxidant
 - Rhodium-catalyzed CO gas-free carbonylative cyclization using aldehydes
 - First palladium- and nickel-catalyzed oxidative diamination of alkenes: Cyclic urea, sulfamide, and guanidine building blocks
 - Nickel-catalyzed carbocyanation of alkynes
 - Asymmetric synthesis of planar-chiral ferrocenes by Mo- or Ru-catalyzed enantioselective metathesis
 - Nickel-catalyzed [2+2+2] cycloaddition of two alkynes and an imine
 - Rhodium- and iridium-catalyzed oxidative coupling of benzoic acids with alkynes and alkenes
 - γ-Methylidene-δ-valerolactones as a coupling partner for cycloaddition: Palladium-catalyzed [4+3] cycloaddition with nitrones
 - Toward the total synthesis of ritterazine N
 - Rhenium-catalyzed synthesis of indene derivatives via C-H bond activation
 - New hydrosilylation reaction of arylacetylene accompanied by C-H bond activation catalyzed by a xantsil ruthenium complex
 - Palladium-catalyzed cross-addition of triisopropylsilylacetylene to unactivated alkynes
 - New cyclizations via catalytic ruthenium vinylidenes
 - Cationic palladium-catalyzed hydrosilylative cross-coupling of alkynes with alkenes forming 4-silylated-1-butene frameworks
 - Boryllithium: A novel boron nucleophile and its application in the synthesis of borylmetal complexes