Thermal and Flexural Properties and Water Absorption of Caulis Spatholobi Residue Fiber Reinforced Biodegradable Poly(propylene carbonate) Composites
-
W. Li
, F.-Q. Chen , X.-C. Yin , J.-P. Qu and M. Yan
Abstract
This paper investigated and compared the thermal and flexural properties and water absorption of natural caulis spatholobi residue fibers reinforced PPC/CSRF composites. Polypropylene carbonate (PPC) was reinforced by caulis spatholobi residue fibers (CSRF) which had been pretreated by continuous steam explosion. The effect of fiber content (10 to 60 wt%) on the properties and water absorption of PPC/CSRF biodegradable composites was investigated. The thermal properties of PPC/CSRF composites indicated that the addition of CSRF could improve the thermal stability of the composites. The flexural strength and modulus of the composites were found to be improved as the content of fiber increased. From the SEM micrographs, it was found that a small amount of fibers were pulled out on fractured surfaces of the composites, showing good network structure between the fiber and PPC matrix. The water absorption amount of the composites increased with increasing the fiber content. This paper demonstrates that the incorporation of low-cost and biodegradable caulis spatholobi residue fiber into PPC provides a practical way to produce completely biodegradable and cost-competitive composites with good mechanical properties.
References
AzwaZ. N., YousifB. F., ManaloA. C. and KarunasenaW., “A Review on the Degradability of Polymeric Composites Based on Natural Fibres”, Mater. Des., 47, 424–442 (2013)10.1016/j.matdes.2012.11.025Search in Google Scholar
ChaimR., BaumL. and BrandonD. G., “Mechanical Properties and Microstructure of Whisker-Reinforced Alumina–30 Vol% Glass Matrix Composite”, J. Am. Ceram. Sac., 72, 1636–1642 (1989) 10.1111/j.1151-2916.1989.tb06295.xSearch in Google Scholar
ChangMa. X. P. R., YuJ. and WangN., “Preparation and Properties of Biodegradable Poly(propylene carbonate)/Thermoplastic Dried Starch Composites”, Carbohydr. Polym., 71, 229–234 (2008) 10.1016/j.carbpol.2007.05.033Search in Google Scholar
ChenF. Q., LiuH. Y., ZhaoY. Q., FengY. Y., GuoR. B., WuZ.H., ChenH. Z., TangH. L. and QuJ. P., “Caulis Spatholobi Residue Fiber Reinforced Biodegradable Poly(propylene carbonate) Composites: The Effect of Fiber Content on Mechanical and Morphological Properties”, Polym. Compos., 35, 208–216 (2014) 10.1002/pc.22652Search in Google Scholar
ChenW., PangM., XiaoM., WangS., WenL. and MengY., “Mechanical, Thermal, and Morphological Properties of Glass Fiber-Reinforced Biodegradable Poly(propylene carbonate) Composites”, J. Reinf. Plast. Compos., 29, 1545–1550 (2010) 10.1177/0731684409336370Search in Google Scholar
DeepaB., AbrahamE., CherianB. M., BismarckA., BlakerJ.J., PothanaN. A., LeaobA. L., SouzabS. F. D. and KottaisamyY.M., “Structure, Morphology and Thermal Characteristics of Banana Nano Fibers Obtained by Steam Explosion”, Bioresour. Technol., 102, 1988–1997 (2011)10.1016/j.biortech.2010.09.030Search in Google Scholar PubMed
DhakalH. N., ZhangZ. Y. and RichardsonM. O. W., “Effect of Water Absorption on the Mechanical Properties of Hemp Fibre Reinforced Unsaturated Polyester Composites”, Compos. Sci. Technol., 67, 1674–1683 (2007) 10.1016/j.compscitech.2006.06.019Search in Google Scholar
EspertA., VilaplanaF. and KarlssonS., “Comparison of Water Absorption in Natural Cellulosic Fibres from Wood and One-Year Crops in Polypropylene Composites and its Influence on their Mechanical Properties”, Composites Part A, 35, 1267–1276 (2004) 10.1016/j.compositesa.2004.04.004Search in Google Scholar
FengY., ShenH., QuJ., LiB., HeH. and HanL., “Preparation and Properties of PBS/Sisal-Fiber Composites”, Polym. Eng. Sci., 51, 474–481 (2011) 10.1002/pen.21852Search in Google Scholar
FrolliniE., BartolucciN., SistiL. and CelliA., “Poly(butylene succinate) Reinforced with Different Lignocellulosic Fibers”, Ind. Crops Prod., 45, 160–169 (2013) 10.1016/j.indcrop.2012.12.013Search in Google Scholar
GeX. C., ZhuQ. and MengY. Z., “Fabrication and Characterization of Biodegradable Poly(propylene carbonate)/Wood Flour Composites”, J. Appl. Polym. Sci., 99, 782–787 (2006) 10.1002/app.22557Search in Google Scholar
Ghasemi-MobarakehL., PrabhakaranM. P., MorshedM., Nasr-EsfahaniM. H. and RamakrishnaS., “Bio-Functionalized PCL Nanofibrous Scaffolds for Nerve Tissue Engineering”, Mater. Sci. Eng., C, 30, 1129–1136 (2010) 10.1016/j.msec.2010.06.004Search in Google Scholar
JohnM. J., ThomasS., “Biofibres and Biocomposites”, Carbohydr. Polym., 71, 343–364 (2008)10.1016/j.carbpol.2007.05.040Search in Google Scholar
KhalilH. P. S. A., TehraniM. A. Y., DavoudpourJ., BhatA. H., JawaidM. and HassanA., “Natural Fiber Reinforced Poly(vinyl chloride) Composites: A Review”, Reinf. Plast. Compos., 32, 330–356 (2013)10.1177/0731684412458553Search in Google Scholar
KimH. J., SeoD. W., “Effect of Water Absorption Fatigue on Mechanical Properties of Sisal Textile-Reinforced Composites”, Int. J. Fatigue, 28, 1307–1314 (2006) 10.1016/j.ijfatigue.2006.02.018Search in Google Scholar
LiX. H., MengY. Z., WangS. J., RajuluVarada A. and TjongS. C., “Completely Biodegradable Composites of Poly(propylene carbonate) and Short, Lignocellulose Fiber Hildegardia Populifolia”, Polym. Sci, Part B: Polym. Phys., 42, 666–675 (2004)10.1002/polb.10761Search in Google Scholar
LiX. H., TjongS. C., MengY. Z. and ZhuQ., “Fabrication and Properties of Poly(propylene Carbonate)/Calcium Carbonate Composites”, Polym. Sci., Part B: Polym. Phys., 41, 1806–1813 (2003)10.1002/polb.10546Search in Google Scholar
MaX. F., ChangP. R., YuJ. G. and WangN., “Preparation and Properties of Biodegradable Poly(propylene carbonate)/Thermoplastic Dried Starch Composites”, Carbohydr. Polym, 71, 229–234 (2008)10.1016/j.carbpol.2007.05.033Search in Google Scholar
MaX., YuJ. and WangN., “Compatibility Characterization of Poly(lactic acid)/Poly(propylene carbonate) Blends”, J. Polym. Sci., Part B: Polym. Phys., 44, 94–101 (2006) 10.1002/polb.20669Search in Google Scholar
MochizukiM., HiramiM., “Structural Effects on the Biodegradation of Aliphatic Polyesters”, Polym. Adv. Tech., 8, 203–209 (1997)10.1002/(SICI)1099-1581(199704)8:4<203::AID-PAT627>3.0.CO;2-3Search in Google Scholar
PangM. Z., QiaoJ. J., JiaoJ., WangS. J., XiaoM. and MengY. Z., “Miscibility and Properties of Completely Biodegradable Blends of Poly(propylene carbonate) and Poly(butylene succinate)”, J. Appl. Polym. Sci., 107, 2854–2860 (2008) 10.1002/app.27252Search in Google Scholar
PangM. Z., QiaoJ. J., JiaoJ., WangS. J., XiaoM. and MengY. Z., “Miscibility and Properties of Completely Biodegradable Blends of Poly(propylene carbonate) and Poly(butylene succinate)”, Polym. Adv. Tech., 8, 203–209 (1997)10.1002/app.27252Search in Google Scholar
PotschkeP., WallheinkeK., FritscheH. and StuzH. J., “Morphology and Properties of Blends with Different Thermoplastic Polyurethanes and Polyolefines”, J. Appl. Polym. Sci., 64, 749–762 (1997) 10.1002/(SICI)1097-4628(19970425)64-4<749::AID-APP14>3.0.CO;2-PSearch in Google Scholar
ScottC. E., MacoskoC. W., “Morphology Development during the Initial Stages of Polymer-Polymer Blending”, Polymer36, 461–470 (1995) 10.1016/0032-3861(95)91554-KSearch in Google Scholar
ShiX. D., GanZ. H. “Preparation and Characterization of Poly(propylene carbonate)Montmorillonite Nanocomposites by Solution Intercalation”, Eur. Polym. J., 43, 4852–4858 (2007) 10.1016/j.eurpolymj.2007.09.024Search in Google Scholar
SinghaA. S., ThakurV. K., “Effect of Fibre Loading on Urea-Formaldehyde Matrix Based Green Composites”, Iranian Polymer Journal, 17, 861–873 (2008)Search in Google Scholar
SinghaA. S., ThakurV. K., “Mechanical, Morphological, and Thermal Characterization of Compression-Molded Polymer Biocomposites”, Int. J. Polym. Anal. Charact., 15, 87–97 (2010) 10.1080/10236660903474506Search in Google Scholar
TanB., QuJ. P., LiuL. M., FengY. H., HuS. X. and YinX. C., “Non-Isothermal Crystallization Kinetics and Dynamic Mechanical Thermal Properties of Poly(butylene Ssccinate) Composites Reinforced with Cotton Stalk Bast Fibers”, Thermochim. Acta, 525, 141–149 (2011)10.1016/j.tca.2011.08.003Search in Google Scholar
ThakurV. K., SinghaA. S., “Physicochemical and Mechanical Behavior of Cellulosic Pine Needle-Based Biocomposites”, Int. J. Polym. Anal. Charact., 16, 390–398 (2011) 10.1080/1023666X.2011.596303Search in Google Scholar
ThakurV. K., ThakurM. K. and GuptaR. K., “Development of Functionalized Cellulosic Biopolymers by Graftcopolymerization”, Int. J. Biol. Macromol., 62, 44–51 (2013) 10.1016/j.ijbiomac.2013.08.026Search in Google Scholar
ThakurV. K., ThakurM. K., “Processing and Characterization of Natural Cellulose Fibers/Thermoset Polymer Composites”, Carbohydr. Polym., 109, 102–117 (2014) 10.1016/j.carbpol.2014.03.039Search in Google Scholar
ThakurV. K., ThakurM. K., “Recent Trends in Hydrogels Based on Psyllium Polysaccharide: A Review”, J. Cleaner Prod., 82, 1–15 (2014) 10.1016/j.jclepro.2014.06.066Search in Google Scholar
ThakurV. K., ThakurM. K., RaghavanP. and KesslerM. R., “Progress in Green Polymer Composites from Lignin for Multifunctional Applications: A Review”, ACS Sustainable Chem. Eng., 2, 1072–1092 (2014) 10.1021/sc500087zSearch in Google Scholar
TorresF. G., CubillasM. L., “Study of the Interfacial Properties of Natural Fibre Reinforced Polyethylene”, Polym. Test., 24, 694–698 (2005)10.1016/j.polymertesting.2005.05.004Search in Google Scholar
UtrackiL. A., ShiZ. H., “Development of Polymer Blend Morphology during Compounding in a Twin-Screw Extruder. Part I: Droplet Dispersion and Coalescence-A Review”, Polym. Eng. Sci., 32, 1824–1833 (1992) 10.1002/pen.760322405Search in Google Scholar
WuT. M., WuC. Y., “Biodegradable Poly(lactic acid)/Chitosan-Modified Montmorillonite Nanocomposites: Preparation and Characterization”, Polym. Degrad. Stab., 91, 2198–2204 (2006) 10.1016/j.polymdegradstab.2006.01.004Search in Google Scholar
ZhangB. T., ZhengX. X., LiH. F. and LinJ. M., “Application of Carbon-Based Nanomaterials in Sample Preparation: A Review”, Analytica Chimica Acta, 784, 1–17 (2013)10.1016/j.aca.2013.03.054Search in Google Scholar PubMed
© 2015, Carl Hanser Verlag, Munich
Articles in the same Issue
- Contents
- Contents
- Regular Contributed Articles
- Anti-Aging Performance of Cardanol Grafted onto Polypropylene by Reactive Extrusion
- Co-Extrusion Layer Multiplication of Rheologically Mismatched Polymers: A Novel Processing Route
- Synthesis and Characterization of Acrylated Epoxidized Flaxseed Oil for Biopolymeric Applications
- Processing of Soju Industrial Bioresidue to Extract Microcrystalline Cellulose and Characterization
- Competition between α and β Crystallization in Isotactic Polypropylene: Effect of Nucleating Agents Composition
- Thermal and Flexural Properties and Water Absorption of Caulis Spatholobi Residue Fiber Reinforced Biodegradable Poly(propylene carbonate) Composites
- The Mechanical Properties of Plasticized PVC Processed in an Extruder with a Modified Feed Zone
- Prediction and Validation of Short Fiber Orientation in a Complex Injection Molded Part with Chunky Geometry
- Microthermoforming Integrated in the Injection Molding Process for Fabrication of Film-Based Microstructured Parts
- Modification Induced in Light Diffusing Polycarbonate due to Proton Irradiation
- Surface Quenching Induced Microstructure Transformations in Extrusion Foaming of Porous Sheets
- Repercussion of Cenosphere Filler Size on Mechanical and Dry Sliding Wear Peculiarity of Glass Fiber-Reinforced Polyester Composites Using Taguchi Analysis and Neural Network
- Rapid Communications
- PPy Doped with DBSA and Combined with PSS to Improve Processability and Control the Morphology
- PPS News
- PPS News
- Seikei Kakou Abstracts
- Seikei Kakou Abstracts
Articles in the same Issue
- Contents
- Contents
- Regular Contributed Articles
- Anti-Aging Performance of Cardanol Grafted onto Polypropylene by Reactive Extrusion
- Co-Extrusion Layer Multiplication of Rheologically Mismatched Polymers: A Novel Processing Route
- Synthesis and Characterization of Acrylated Epoxidized Flaxseed Oil for Biopolymeric Applications
- Processing of Soju Industrial Bioresidue to Extract Microcrystalline Cellulose and Characterization
- Competition between α and β Crystallization in Isotactic Polypropylene: Effect of Nucleating Agents Composition
- Thermal and Flexural Properties and Water Absorption of Caulis Spatholobi Residue Fiber Reinforced Biodegradable Poly(propylene carbonate) Composites
- The Mechanical Properties of Plasticized PVC Processed in an Extruder with a Modified Feed Zone
- Prediction and Validation of Short Fiber Orientation in a Complex Injection Molded Part with Chunky Geometry
- Microthermoforming Integrated in the Injection Molding Process for Fabrication of Film-Based Microstructured Parts
- Modification Induced in Light Diffusing Polycarbonate due to Proton Irradiation
- Surface Quenching Induced Microstructure Transformations in Extrusion Foaming of Porous Sheets
- Repercussion of Cenosphere Filler Size on Mechanical and Dry Sliding Wear Peculiarity of Glass Fiber-Reinforced Polyester Composites Using Taguchi Analysis and Neural Network
- Rapid Communications
- PPy Doped with DBSA and Combined with PSS to Improve Processability and Control the Morphology
- PPS News
- PPS News
- Seikei Kakou Abstracts
- Seikei Kakou Abstracts