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Impact of Heat Treatment on the Performance of Polymers as Ferric Ions Stabilization Agents for Aqueous Systems

  • Z. Amjad
Published/Copyright: March 31, 2013
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Tenside Surfactants Detergents
From the journal Tenside Surfactants Detergents Volume 45 Issue 2

Abstract

The impact of heat treatment on the performance of various polymers as ferric ions stabilization agents in an aqueous system at pH 7.00, 23 °C has been investigated. The polymers evaluated include: (a) homo-polymers of acrylic acid, methacrylic acid, maleic acid, 2-acrylamido-2-methylpropane sulfonic acid, sulfonated styrene; (b) co-polymers of acrylic acid: 2-acrylamido-2-methylpropane sulfonic acid and maleic acid: sulfonated styrene, and (c) ter-polymers of acrylic acid: 2-acryalamido-2-methylpropane sulfonic acid: sulfonated styrene, acrylic acid: methacrylic acid: t-butylacrylamide, and acrylic acid: 2-acrylamido-2-methylpropane sulfonic acid: t-butylacrylamide. It has been found that all polymers lose performance to a varying degree when exposed to thermal treatment (150 °C, 200 °C, 240 °C, 20 hr). The performance data collected before and after thermal treatment suggest that sulfonated styrene containing co- and ter-polymers are better ferric ions stabilization agents than the co- and ter-polymers containing 2-acrylamido-2-methylpropane sulfonic acid and t-butylacrylamide. In addition, it has been found that heat treatment exhibits positive influence on the performance of homo-polymer of 2-acrylamido-2-methypropane sulfonic acid. The results have been explained in terms of loss of 2-acrylamido-2-methylpropane sulfonic acid and t-butylacrylamide in the co- and ter-polymers during thermal treatment.

Kurzfassung

Der Auswirkung einer Wärmebehandlung auf die Leistungsfähigkeit verschiedener Polymere als Stabilisierungsmittel für Eisenionen wurde bei pH 7.00, 23 °C in wässrigen System untersucht. Die bewerteten Polymere waren: (a) Homopolymere der Acrylsäure, Methacrylsäure, Maleinsäure, 2-Acrylamido-2-methylpropansulfonsäure, sulfoniertes Styrol; (b) Copolymere von Acrylsäure: 2-Acrylamido-2-methylpropansulfonsäure und Maleinsäure: sulfoniertes Styrol und (c) Terpolymere von Acrylsäure: 2-Acrylamido-2-methylpropansulfonsäure: sulfoniertes Styrol, Acrylsäure: Methacrylsäure: t-Butylacrylamid und Acrylsäure: 2-Acrylamido-2-methylpropansulfonsäure: t-Butylacrylamid. Es wurde gefunden, dass alle Polymere an Leistungsfähigkeit mit unterschiedlichem Ausmaß einbüßen, wenn sie einer thermischen Behandlung (150 °C, 200 °C, 240 °C, 20 h) ausgesetzt werden. Die gesammelten Leistungswerte, vor und nach der thermischen Behandlung, zeigen, dass sulfonierte Styrole mit Co- und Terpolymeren bessere Stabilisierungsmittel für Eisenionen sind als Co- und Terpolymere mit 2-Acrylamido-2-methylpropansulfonsäuren und t-Butylacrylamiden. Außerdem wurde gefunden, dass die Wärmebehandlung einen positiven Einfluss auf die Leistungsfähigkeit von Homopolymeren der 2-Acrylamido-2-methylpropansulfonsäure besitzt. Die Ergebnisse sind erklärbar durch einen Verlust an 2-Acrylamido-2-methylpropansulfonsäure und t-Butylacrylamid bei den Co- und Terpolymeren während der thermischen Behandlung.

Key words:: Ferric ion; stabilization; polymers; thermal stability
Stichwörter:: Eisenionen; Stabilisierung; Polymere; thermische Stabilität
∗ Zahid Amjad, Lubrizol Advanced Materials, Inc., 9911 Brecksville Road, Brecksville, OH 44141

Zahid Amjad, received his M.Sc. in Chemistry from Punjab University, Lahore, Pakistan, and his Ph.D. in Chemistry from Glasgow University, Scotland. He is currently a Senior Fellow in the Lubrizol Advanced Materials, Inc. His areas of research include interactions of polymers with different substrates in aqueous solution, and applications of water soluble and water swellable polymers in personal care, pharmaceutical, and industrial water systems.

References

1.Semiat, R., Sutzkover, I. and Hasson, D.: CORROSION/2000, Paper No 00310, NACE International, Houston, Texas (2000).Search in Google Scholar

2.Amjad, Z.: Tenside Surfactants Detergents44(2007)88.10.3139/113.100329Search in Google Scholar

3.Gallup, D. L.: Geothermics31(2002)415. 10.1016/S0375-6505(02)00004-4Search in Google Scholar

4.Cowan, J. C. and Weintritt, D. J.: Water Formed Scale Deposits, Gulf Publishing Company, Houston, Texas, (1976).Search in Google Scholar

5.Harmandas, N. G., Fernandez, E. N. and Koutsoukos, P. G.: Langmuir14(1998)1250. 10.1021/la970354cSearch in Google Scholar

6.Amjad, Z., Zibrida, J. F. and Zuhl, R. W.: Materials Performance36(1997)32.Search in Google Scholar

7.Amjad, Z., Butala, D. and Pugh, J.: CORROSION/99, Paper No 118, NACE International, Houston, Texas (1999).Search in Google Scholar

8.Fivizzani, K. P., Dubin, L., Fair, B. E. and Hoots, J. F.: CORROSION/89, Paper No 433, NACE International, Houston, Texas (1989).Search in Google Scholar

9.Zini, P. (Ed): Polymeric Additives for High Performance detergents, Technomic Publishing Company, Inc., Lancaster, Pennsylvania(1995).Search in Google Scholar

10.Moriarty, B. E., Rasimas, J. P., Young, P. R. and Hoots, J. E.: CORROSION/2001, Paper No 01450, NACE International, Houston, Texas (2001).Search in Google Scholar

11.Nagarajan, M. K.: JAOCS62(1985)949. 10.1007/BF02541766Search in Google Scholar

12.Denman, W. L. and Salutsky, M. L.: in Proceedings of the 28th International Water Conference, Pittsburgh, Pennsylvania, (1967).Search in Google Scholar

13.Masler, W. F.: in Proceedings of the 43rd International Water Conference, Pittsburgh, Pennsylvania, (1982).Search in Google Scholar

14.Amjad, Z. and Zuhl, R. W.: in Proceedings of the Association of Water Technologies 2005 Annual Convention, Palm Springs, California, (2005).Search in Google Scholar

15.Perez, L. and Freese, D.: CORROSION/97, Paper No 174, NACE International, Houston, Texas (1997).Search in Google Scholar

16.Klepetsanis, P. G., Kladi, A., Koutsoukos, P. G. and Amjad, Z.: Progr. Colloid Poly Sci.115(2000)1006.Search in Google Scholar

17.Amjad, Z.: Tenside Surfactants Detergents36(1999)50.Search in Google Scholar

18.Amjad, Z.: Phos. Res. Bull.20(2006)165. 10.3363/prb.20.165Search in Google Scholar

19.Amjad, Z.: Tenside Surfactants Detergents43(2006)242.10.3139/113.100312Search in Google Scholar

20.Smyk, E. E., Hoots, J., Fivizzani, K. F. and Fulks, K.: CORROSION/88, Paper No 88014, NACE International, Hosuton, Texas (1988).Search in Google Scholar

21.Oner, M., Dogan, O. and Oner, G.: J. Crystal Growth186(1998)427. 10.1016/S0022-0248(97)00518-6Search in Google Scholar

22.Garcia-Raso, F. G., Palou, A., Costa-Bauza, A. and MarchJ.G.: Colloids Surfaces54(1991)313. 10.1016/0166-6622(91)80069-ZSearch in Google Scholar

23.Amjad, Z.: Langmuir7(1991)2405. 10.1021/la00058a072Search in Google Scholar

24.Amjad, Z.: Water Treatment9(1994)47.10.6012/jwei.1994.47Search in Google Scholar

25.Amjad, Z.: Can J. Chem.66(1988)1529. 10.1139/v88-247Search in Google Scholar

26.Binbuga, N., Hasty, J. K., Gwaltney, S. R., Henry, W. P. and Schultz, T. P.: Inorganica Chimica Acta360(2007)2339. 10.1016/j.ica.2006.11.018Search in Google Scholar

27.Amjad, Z., unpublished results (2007).Search in Google Scholar

28.Amjad, Z.: Can J. Chem.66(1987)1529. 10.1139/v88-247Search in Google Scholar

29.Amjad, Z. and Zuhl, R. W.: CORROSION/2007, Paper No 07056, NACE International, Houston, Texas (2007).Search in Google Scholar

Received: 2007-10-17
Published Online: 2013-03-31
Published in Print: 2008-03-01

© 2008, Carl Hanser Publisher, Munich

Articles in the same Issue

  1. Contents/Inhalt
  2. Contents
  3. Abstracts
  4. Abstracts
  5. Application
  6. Impact of Heat Treatment on the Performance of Polymers as Ferric Ions Stabilization Agents for Aqueous Systems
  7. Novel Surfactants
  8. Preparation and Performance Properties of a Series of Novel Anionic Gemini Surfactants
  9. Biologically Active Tin Compounds Based on Aziridine and Azepane Derivatives
  10. Obituary
  11. Obituary
  12. Synthesis
  13. Synthesis and Properties Evaluation of Nonionic-Anionic Surfactants Suitable for Enhanced Oil Recovery Using Sea Water
  14. Synthesis and Characterisation of Antifungal Agents Containing Copper(II) Soaps and Derived from Mustard and Soyabean Oil
https://doi.org/10.3139/113.100362
Keywords for this article
Ferric ion; stabilization; polymers; thermal stability

Articles in the same Issue

  1. Contents/Inhalt
  2. Contents
  3. Abstracts
  4. Abstracts
  5. Application
  6. Impact of Heat Treatment on the Performance of Polymers as Ferric Ions Stabilization Agents for Aqueous Systems
  7. Novel Surfactants
  8. Preparation and Performance Properties of a Series of Novel Anionic Gemini Surfactants
  9. Biologically Active Tin Compounds Based on Aziridine and Azepane Derivatives
  10. Obituary
  11. Obituary
  12. Synthesis
  13. Synthesis and Properties Evaluation of Nonionic-Anionic Surfactants Suitable for Enhanced Oil Recovery Using Sea Water
  14. Synthesis and Characterisation of Antifungal Agents Containing Copper(II) Soaps and Derived from Mustard and Soyabean Oil
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