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Headspace single-drop microextraction coupled with gas chromatography electron capture detection of butanone derivative for determination of iodine in milk powder and urine

  • Meihua Hu EMAIL logo , Haiying Chen , Yong Jiang and Huifang Zhu
Published/Copyright: June 4, 2013
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Chemical Papers
From the journal Chemical Papers Volume 67 Issue 10

Abstract

A new detection method using headspace single-drop microextraction (HS-SDME) coupled to gas chromatography (GC) was established to determine the iodine in milk powder and urine. The derivative from the reaction between iodine and butanone in the acidic media was extracted into a micro-drop then determined by GC-ECD. With the optimisation of HS-SDME and derivatisation, the calibration curve showed good linearity within the range of 0.004–0.1 μg mL−1 (0.004–0.1 μg g−1) (R 2 = 0.9991), and the limits of detection for milk powder and urine were 0.0018 μg g−1 and 0.36 μg L−1, respectively. The mean recoveries of milk powder and urine were 90.0–107 % and 89.4–101 % with mean RSD of 1.7–3.4 % and 2.7–3.3 %, respectively. This detection method affords a number of advantages, such as being simple, rapid, and inexpensive, with low organic solvent consumption, and is remarkably free from interference effects, rendering it an efficient method for the determination of iodine in milk powder and urine samples.

Keywords: headspace single-drop microextraction; gas chromatography-electron capture detection; iodine; butanone; milk powder; urine

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Published Online: 2013-6-4
Published in Print: 2013-10-1

© 2013 Institute of Chemistry, Slovak Academy of Sciences

Articles in the same Issue

  1. Headspace single-drop microextraction coupled with gas chromatography electron capture detection of butanone derivative for determination of iodine in milk powder and urine
  2. Production of l-tryptophan by enantioselective hydrolysis of d,l-tryptophanamide using a newly isolated bacterium
  3. Copper hydride-catalyzed reduction of electron-deficient olefins
  4. Efficient photodegradation of resorcinol with Ag2O/ZnO nanorods heterostructure under a compact fluorescent lamp irradiation
  5. Comparison of anthocyanins present in grapes of Vitis vinifera L. varieties and interspecific hybrids grown in the Czech Republic
  6. Synthesis and characterisation of Cu(II), Ni(II), and Zn(II) complexes of furfural derived from aroylhydrazones bearing aliphatic groups and their interactions with DNA
  7. Efficacy of zinc and tourmaline in mitigating corrosion of carbon steel in non-flow mode
  8. Influence of the B-site cation nature on dielectric properties of Ca2XBiO6 (X = Dy, Fe, Al) double perovskite
  9. Stereoselective total synthesis of protected sulfamisterin and its analogues
  10. Investigation of 3,5-dichlorosalicylate-copper(II)-(3-pyridylmethanol or N,N′-diethylnicotinamide) complex systems by EPR spectroscopy
  11. Heavy-metal extraction capability of chalcogenoic aminophosphines derived from 1-amino-4-methylpiperazine
  12. Electrical conductivity of systems based on Na3AlF6-SiO2 melt
https://doi.org/10.2478/s11696-013-0391-z
Keywords for this article
headspace single-drop microextraction; gas chromatography-electron capture detection; iodine; butanone; milk powder; urine

Articles in the same Issue

  1. Headspace single-drop microextraction coupled with gas chromatography electron capture detection of butanone derivative for determination of iodine in milk powder and urine
  2. Production of l-tryptophan by enantioselective hydrolysis of d,l-tryptophanamide using a newly isolated bacterium
  3. Copper hydride-catalyzed reduction of electron-deficient olefins
  4. Efficient photodegradation of resorcinol with Ag2O/ZnO nanorods heterostructure under a compact fluorescent lamp irradiation
  5. Comparison of anthocyanins present in grapes of Vitis vinifera L. varieties and interspecific hybrids grown in the Czech Republic
  6. Synthesis and characterisation of Cu(II), Ni(II), and Zn(II) complexes of furfural derived from aroylhydrazones bearing aliphatic groups and their interactions with DNA
  7. Efficacy of zinc and tourmaline in mitigating corrosion of carbon steel in non-flow mode
  8. Influence of the B-site cation nature on dielectric properties of Ca2XBiO6 (X = Dy, Fe, Al) double perovskite
  9. Stereoselective total synthesis of protected sulfamisterin and its analogues
  10. Investigation of 3,5-dichlorosalicylate-copper(II)-(3-pyridylmethanol or N,N′-diethylnicotinamide) complex systems by EPR spectroscopy
  11. Heavy-metal extraction capability of chalcogenoic aminophosphines derived from 1-amino-4-methylpiperazine
  12. Electrical conductivity of systems based on Na3AlF6-SiO2 melt
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