Calcined Ni—Al layered double hydroxide as a catalyst for total oxidation of volatile organic compounds: Effect of precursor crystallinity
-
Z. Mikulová
,
P. Čuba
Abstract
The effect of hydrothermal treatment on properties (crystallinity, porous structure, reducibility, acidity, basicity, and catalytic activity and selectivity in toluene and ethanol total oxidation) of Ni—Al layered double hydroxide precursors and related mixed oxides was examined. The hydrothermal treatment increased considerably both the content of crystalline phase and LDH crystallite size. On the other hand, only a slight effect of the precursor hydrothermal treatment on crystallinity of the related Ni—Al mixed oxides obtained by calcination at 450°C was observed. The reducibility of NiO particles appeared to be hindered considerably compared to the reducibility of pure NiO. Catalytic activity of the Ni—Al mixed oxides prepared from the precursors hydrothermally treated for a short time (4 h) was the highest. The highest amount of acetaldehyde formed during the total oxidation of ethanol, i.e. the worst selectivity was found for the calcined Ni—Al LDH without hydrothermal treatment.
[1] Papaefthimiou, P., Ioannides, T., and Verykios, E. X., Appl. Catal., B 13, 175 (1997). http://dx.doi.org/10.1016/S0926-3373(96)00103-810.1016/S0926-3373(96)00103-8Search in Google Scholar
[2] Larson, P. O., Berggren, H., and Andersson, A., Catal. Today 35, 137 (1997). http://dx.doi.org/10.1016/S0920-5861(96)00140-X10.1016/S0920-5861(96)00140-XSearch in Google Scholar
[3] Lintz, H. G. and Wittstock, K., Catal. Today 29, 457 (1996). http://dx.doi.org/10.1016/0920-5861(95)00320-710.1016/0920-5861(95)00320-7Search in Google Scholar
[4] Cavani, F., Trifiro, F., and Vaccari, A., Catal. Today 11, 173 (1991). http://dx.doi.org/10.1016/0920-5861(91)80068-K10.1016/0920-5861(91)80068-KSearch in Google Scholar
[5] Vaccari, A., Catal. Today 41, 53 (1998). http://dx.doi.org/10.1016/S0920-5861(98)00038-810.1016/S0920-5861(98)00038-8Search in Google Scholar
[6] Basile, F., and Vaccari, A., in Layered Double Hydroxides: Present and Future (Rives, V., Editor), p. 285. Nova Science Publishers, New York, 2001. Search in Google Scholar
[7] Kovanda, F., Jirátová, K., and Kalousková, R., in Advances in Chemistry Research, Vol. 1 (Gerard, F. L., Editor), p. 89. Nova Science Publishers, New York, 2006. Search in Google Scholar
[8] Jirátová, K., Čuba, P., Kovanda, F., Hilaire, L., and Pitchon, V., Catal. Today 76, 43 (2002). http://dx.doi.org/10.1016/S0920-5861(02)00203-110.1016/S0920-5861(02)00203-1Search in Google Scholar
[9] Bahranowski, K., Bielanska, E., Janik, R., Machej, T., and Serwicka, E. M., Clay Miner. 34, 67 (1999). http://dx.doi.org/10.1180/claymin.1999.034.1.0810.1180/claymin.1999.034.1.08Search in Google Scholar
[10] Forano, C., in Clay Surfaces: Fundamentals and Applications (Wypych, F. and Satyanarayana, K. G., Editors), p. 425. Elsevier, Amsterdam, 2004. Search in Google Scholar
[11] Roy, D. M., Roy, R., and Osborn, E. F., Am. J. Sci. 251, 337 (1953). http://dx.doi.org/10.2475/ajs.251.5.33710.2475/ajs.251.5.337Search in Google Scholar
[12] Miyata, S., Clays Clay Miner. 28, 50 (1980). http://dx.doi.org/10.1346/CCMN.1980.028010710.1346/CCMN.1980.0280107Search in Google Scholar
[13] Kovanda, F., Koloušek, D., Cílová, Z., and Hulínský, V., Appl. Clay Sci. 28, 101 (2005). http://dx.doi.org/10.1016/j.clay.2004.01.00910.1016/j.clay.2004.01.009Search in Google Scholar
[14] Kruissink, E. C., van Reijen, L. L., and Ross, J. R. H., J. Chem. Soc., Faraday Trans. 177, 649 (1981). Search in Google Scholar
[15] Schneider, P., Appl. Catal., A 129, 157 (1995). http://dx.doi.org/10.1016/0926-860X(95)00110-710.1016/0926-860X(95)00110-7Search in Google Scholar
[16] Obalová, L., Jirátová, K., and Kovanda, F., J. Mol. Catal., A 248, 210 (2006). http://dx.doi.org/10.1016/j.molcata.2005.12.03710.1016/j.molcata.2005.12.037Search in Google Scholar
[17] Clause, O., Gazzano, M., Trifiro, F., Vaccari, A., and Zatorski, L., Appl. Catal. 73, 217 (1991). http://dx.doi.org/10.1016/0166-9834(91)85138-L10.1016/0166-9834(91)85138-LSearch in Google Scholar
[18] Puxley, P. C., Kitchener, I. J., Komodromos, C., and Parkyns, N. D., in Studies in Surface Science, Vol. 16, Preparation of Catalysts III (Poncelet, G., Grange, P., and Jacobs, P., Editors), p. 227. Elsevier, Amsterdam, 1983. Search in Google Scholar
© 2007 Institute of Chemistry, Slovak Academy of Sciences
Articles in the same Issue
- Spectrophotometric determination of microamounts of quercetin based on its complexation with copper(II)
- Oxygen evolution on Ti/Co3O4-coated electrodes in alkaline solution
- The zeta potential of kaolin suspensions measured by electrophoresis and electroacoustics
- Fluidization behavior of oil-contaminated sand
- Software sensors for monitoring of a solid waste composting process
- Calcined Ni—Al layered double hydroxide as a catalyst for total oxidation of volatile organic compounds: Effect of precursor crystallinity
- Thermodynamic possibilities and constraints of pure hydrogen production by a chromium, nickel, and manganese-based chemical looping process at lower temperatures
- Death kinetics of Escherichia coli in goat milk and Bacillus licheniformis in cloudberry jam treated by ohmic heating
- Topochemical models for anti-HIV activity of 1-alkoxy-5-alkyl-6-(arylthio)uracils
- Acidity, lipophilicity, solubility, absorption, and polar surface area of some ACE inhibitors
- Silver as anode in cryolite—alumina-based melts
- Multicomponent facile synthesis of novel dihydroazolopyrimidinyl carbamides
- Z. Platková, M. Polakovič, V. Štefuca, M. Vandáková, and M. Antošová: Selection of Carrier for Immobilization of Fructosyltransferase from Aureobasidium pullulans
Articles in the same Issue
- Spectrophotometric determination of microamounts of quercetin based on its complexation with copper(II)
- Oxygen evolution on Ti/Co3O4-coated electrodes in alkaline solution
- The zeta potential of kaolin suspensions measured by electrophoresis and electroacoustics
- Fluidization behavior of oil-contaminated sand
- Software sensors for monitoring of a solid waste composting process
- Calcined Ni—Al layered double hydroxide as a catalyst for total oxidation of volatile organic compounds: Effect of precursor crystallinity
- Thermodynamic possibilities and constraints of pure hydrogen production by a chromium, nickel, and manganese-based chemical looping process at lower temperatures
- Death kinetics of Escherichia coli in goat milk and Bacillus licheniformis in cloudberry jam treated by ohmic heating
- Topochemical models for anti-HIV activity of 1-alkoxy-5-alkyl-6-(arylthio)uracils
- Acidity, lipophilicity, solubility, absorption, and polar surface area of some ACE inhibitors
- Silver as anode in cryolite—alumina-based melts
- Multicomponent facile synthesis of novel dihydroazolopyrimidinyl carbamides
- Z. Platková, M. Polakovič, V. Štefuca, M. Vandáková, and M. Antošová: Selection of Carrier for Immobilization of Fructosyltransferase from Aureobasidium pullulans
