A Generalized Kinetic Model for Hydrometallurgical Processes
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Fathi Habashi
In electrochemical leaching processes the solid must be an electric conductor, e.g., a metal, or a semiconductor, e.g., certain metal sulfides or oxides. Reaction takes place by the transfer of electrons at the solid surface and involves oxidation–reduction processes that take place simultaneously at two different locations not far from each other. At one location, electrons are picked up by a depolarizer, D, in solution, e.g., O2, H+, etc. (the cathodic zone) and at another location metal ions are released in solution (the anodic zone) where they react with reagent C. A single kinetic law derived theoretically is obeyed: Rate = k1k2A[D][C] / (k1[D] + k2[C]) where k1 and k2 are constants, and A is the total surface area of the dissolving solid.
©2011 Walter de Gruyter GmbH & Co. KG, Berlin/Boston
Articles in the same Issue
- Review
- A Generalized Kinetic Model for Hydrometallurgical Processes
- Advanced Modeling of Reactive Separation Units with Structured Packings
- Applications of Computational Fluid Dynamics (CFD) Tools for Gravity Concentrators in Coal Preparation
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- CFD Diagnosis of the Cyclotol Manufacturing Plant: Product Quality and Process Operation
- Performance Analysis of Three Controllers for the Polymerisation of Styrene in a Batch Reactor
- Enhanced Explicit Scheme to Solve Transient Heat Conduction Problem
- Analysis and Simulation of Cross-Flow Reactor for Ethylene Epoxidation
- Learning to Control pH Processes at Multiple Time Scales: Performance Assessment in a Laboratory Plant
- Estimating Output Variance in Closed Loop Systems
- CFD Simulations for Continuous Flow of Bubbles through Gas-Liquid Columns: Application of VOF Method
- Inference of Chemical Reaction Networks Using Hybrid S-system Models
- Optimization of the Variable Reflux Ratio in a Batch Distillation Column through a Heuristic Method
- Spatial and Temporal Resolution in Data-Driven Process Modeling of an Integrated Newsprint Mill
Articles in the same Issue
- Review
- A Generalized Kinetic Model for Hydrometallurgical Processes
- Advanced Modeling of Reactive Separation Units with Structured Packings
- Applications of Computational Fluid Dynamics (CFD) Tools for Gravity Concentrators in Coal Preparation
- Article
- CFD Diagnosis of the Cyclotol Manufacturing Plant: Product Quality and Process Operation
- Performance Analysis of Three Controllers for the Polymerisation of Styrene in a Batch Reactor
- Enhanced Explicit Scheme to Solve Transient Heat Conduction Problem
- Analysis and Simulation of Cross-Flow Reactor for Ethylene Epoxidation
- Learning to Control pH Processes at Multiple Time Scales: Performance Assessment in a Laboratory Plant
- Estimating Output Variance in Closed Loop Systems
- CFD Simulations for Continuous Flow of Bubbles through Gas-Liquid Columns: Application of VOF Method
- Inference of Chemical Reaction Networks Using Hybrid S-system Models
- Optimization of the Variable Reflux Ratio in a Batch Distillation Column through a Heuristic Method
- Spatial and Temporal Resolution in Data-Driven Process Modeling of an Integrated Newsprint Mill
