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Celleriite, □(Mn22+Al)Al6(Si6O18)(BO3)3(OH)3(OH), , a new mineral species of the tourmaline supergroup

  • Ferdinando Bosi , Federico Pezzotta , Alessandra Altieri , Giovanni B. Andreozzi , Paolo Ballirano ORCID logo , Gioacchino Tempesta , Jan Cempírek ORCID logo , Radek Škoda , Jan Filip , Renata Čopjaková , Milan Novák , Anthony R. Kampf ORCID logo , Emily D. Scribner , Lee A. Groat and R. James Evans
Published/Copyright: December 28, 2021
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American Mineralogist
From the journal American Mineralogist Volume 107 Issue 1

Abstract

Celleriite, □ (Mn22+Al)Al6(Si6O18)(BO3)3(OH)3(OH), is a new mineral of the tourmaline supergroup. It was discovered in the Rosina pegmatite, San Piero in Campo, Elba Island, Italy (holotype specimen), and in the Pikárec pegmatite, western Moravia, Czech Republic (co-type specimen). Celleriite in hand specimen is violet to gray-blue (holotype) and dark brownish-green (co-type) with a vitreous luster, conchoidal fracture, and white streak. Celleriite has a Mohs hardness of ~7 and a calculated density of 3.13 and 3.14 g/cm3 for holotype and its co-type, respectively. In plane-polarized light in thin section, celleriite is pleochroic (O = pale violet and E = light gray-blue in holotype; O = pale green and E = colorless in co-type) and uniaxial negative. Celleriite has trigonal symmetry: space group R3m, Z = 3, a = 15.9518(4) and 15.9332(3) Å, c = 7.1579(2) and 7.13086(15) Å, V = 1577.38(9) and 1567.76(6) Å3 for holotype and co-type, respectively (data from single-crystal X‑ray diffraction). The crystal structure of the holotype specimen was refined to R1 = 2.89% using 1696 unique reflections collected with MoKα X‑ray intensity data. Structural, chemical, and spectroscopic analyses resulted in the formulas:      x(□0.58Na0.42)∑1.00Y(Mn1.392+Fe0.162+Mg0.01Al1.14Fe0.013.0Li0.28 T0.01)Σ3.00ZAl6[  T(Si5.99Al0.01)Σ6.00O18 ](BO3)3(OH)3w[ (OH)0.65 F0.03O0.32 ]Σ1.00 (for holotype) and       X(□0.51Na0.49)Σ1.00Y(Mn0.902+Fe0502+Al1.36Fe0043+Li0.17Zn0.04)Σ3.00ZAl6[ T(Si5.75 B0.25)Σ6.00O18 ](BO3)3(OH)3w[ (OH)0.35 F0.17O0.48 ]∑1.00(for co-type)

Celleriite is a hydroxy species belonging to the X-site vacant group of the tourmaline supergroup. The new mineral was approved by the Commission on New Minerals, Nomenclature and Classification of the International Mineralogical Association, proposal no. 2019-089.

In the Rosina pegmatite, celleriite formed an overgrowth at the analogous pole of elbaite–fluorelbaite–rossmanite crystals during the latest stage of evolution of pegmatite cavities after an event of a pocket rupture. In the Pikárec pegmatite, celleriite occurs as an intermediate growth sector of elbaite, princivalleite, and fluor-elbaite.

Keywords: Celleriite; tourmaline; crystal-structure refinement; electron microprobe; Mössbauer spectroscopy; laser-induced breakdown spectroscopy; laser-ablation inductively coupled plasma mass-spectroscopy; Raman spectroscopy; Lithium; Beryllium; and Boron : Quintessentially Crustal

|| Special collection papers can be found online at http://www.minsocam.org/MSA/AmMin/special-collections.html

Funding statement: Funding by Sapienza University of Rome (Prog. Università 2018 to F. Bosi) and Deep Carbon Observatory (2016 to G.B. Andreozzi) are gratefully acknowledged. J.C., R.Š., R.Č., and M.N. acknowledge support from the project GAČR 17-17276S. The research was supported by an NSERC Discovery Grant to L.A.G. (funding reference 06434). Support from the John Jago Trelawney Endowment to the Mineral Sciences Department of the Natural History Museum of Los Angeles County to A.R.K. is acknowledged. Part of the data presented in this paper were obtained at CEITEC, Core Facility X‑ray Diffraction, and Bio-SAXS supported by MEYS CR (LM2018127).

Acknowledgments

Chemical analyses were completed with the kind assistance of M. Serracino, to whom the authors express their gratitude. The associate editor, E.S. Grew, the Technical Editor, and the reviewers, P. Bačík and D.J. Henry, are thanked for their constructive comments.

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Received: 2020-09-21
Accepted: 2021-01-02
Published Online: 2021-12-28
Published in Print: 2022-01-27

© 2022 Mineralogical Society of America

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https://doi.org/10.2138/am-2021-7818
Keywords for this article
Celleriite; tourmaline; crystal-structure refinement; electron microprobe; Mössbauer spectroscopy; laser-induced breakdown spectroscopy; laser-ablation inductively coupled plasma mass-spectroscopy; Raman spectroscopy; Lithium; Beryllium; and Boron : Quintessentially Crustal

Articles in the same Issue

  1. MSA Presidential Address
  2. MSA at 100 and why optical mineralogy still matters: The optical properties of talc
  3. Boron isotope compositions establish the origin of marble from metamorphic complexes: Québec, New York, and Sri Lanka
  4. Celleriite, □(Mn22+Al)Al6(Si6O18)(BO3)3(OH)3(OH), , a new mineral species of the tourmaline supergroup
  5. Jingsuiite, TiB2, a new mineral from the Cr-11 podiform chromitite orebody, Luobusa ophiolite, Tibet, China: Implications for recycling of boron
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  8. Thermoelastic properties of zircon: Implications for geothermobarometry
  9. A Rayleigh model of cesium fractionation in granite-pegmatite systems
  10. The atomic arrangement and electronic interactions in vonsenite at 295, 100, and 90 K
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  12. High-pressure experimental study of tetragonal CaSiO3-perovskite to 200 GPa
  13. Mesoproterozoic seafloor authigenic glauconite-berthierine: Indicator of enhanced reverse weathering on early Earth
  14. Chemical variability in vyacheslavite, U(PO4)(OH): Crystal-chemical implications for hydrous and hydroxylated U4+, Ca, and REE phosphates
  15. Bennesherite, Ba2Fe2+Si2O7: A new melilite group mineral from the Hatrurim Basin, Negev Desert, Israel
  16. Single-crystal elasticity of phase Egg AlSiO3OH and δ-AlOOH by Brillouin spectroscopy
  17. Letter
  18. On the formation of Martian blueberries
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