Home peri-Interactions in Naphthalenes, 7 [1]. A Hetera-naphthalene as a Model Compound for 8-Dimethylaminonaphth- 1-yl Silicon and Phosphorus Compounds
Article
Licensed
Unlicensed Requires Authentication

peri-Interactions in Naphthalenes, 7 [1]. A Hetera-naphthalene as a Model Compound for 8-Dimethylaminonaphth- 1-yl Silicon and Phosphorus Compounds

  • Günter Paulus Schiemenz and Christian Näther EMAIL logo
Published/Copyright: June 2, 2014
Become an author with De Gruyter Brill
Author Information Explore this Subject
Zeitschrift für Naturforschung B
From the journal Zeitschrift für Naturforschung B Volume 57 Issue 3

Abstract

In a 4-isopropyl-1-oxa-3-oxonia-2-borata-naphthalene the isopropyl group exhibits the same conformational phenomena as the Me2N group in 8-dimethylamino-naphth-1-yl-silanes and related phosphorus compounds. Since the details can be fully rationalized on the basis of the steric situation and electronic factors are excluded, the common features cannot serve to infer dative interaction from nitrogen to silicon / phosphorus resulting in hypercoordination of the third period element atoms in the reference compounds.

Keywords : peri-Interactions in Naphthalenes; Phosphorus Compounds
Received: 2001-12-28
Published Online: 2014-6-2
Published in Print: 2002-3-1

© 1946 – 2014: Verlag der Zeitschrift für Naturforschung

Articles in the same Issue

  1. Magnetic Super-Exchange Mechanism and Crystal Structure of a Binuclear μ-Acetato-Bridged Copper(II) Complex of Pentadentate Binucleating Ligand.An Influence of Overlap Interactions to Magnetic Properties
  2. Cationic Ruthenium-Sulfine Complexes: Synthesis and Dynamic Behaviour
  3. Palladium-Cadmium Ordering In Repdcd (Re = La, Ce, Pr, Nd, Sm, Eu, Gd, Tb) And Comparison With Isotypic Indium Compounds
  4. Metallkomplexe mit biologisch wichtigen Liganden, CXLXXX [1]. Kationische Bis(α-Aminosäuremethylester)-N,O-Chelatkomplexe von Palladium(II) [Pd(NH2CHRCO2Me)2]2+(BF4–)2/ Metal Complexes of Biologically Important Ligands, CXLXXX [1]. Cationic Bis(α-Amino Acid Methylester)-N,O-Chelate Complexes of Palladium(II) [(Pd(NH2CHRCO2Me)2]2+(BF4–)2
  5. Synthesis and Structural Characterization of Aminoalkanol Derivatives of 2,3-Dihydro-2,2-dimethyl-7-benzofuranol with an Expected β-Adrenolytic and / or Anxiolytic Activity
  6. Hydroboration and Haloboration of Propyne and 1-Butyne
  7. Excited State Behavior of Uranyl Complexes with Salophen and Oxine as Chromophoric Ligands
  8. 57Fe NMR Spectroscopy of Some Sila-[1]ferrocenophanes and a Phospha-[1]ferrocenophane
  9. peri-Interactions in Naphthalenes, 7 [1]. A Hetera-naphthalene as a Model Compound for 8-Dimethylaminonaphth- 1-yl Silicon and Phosphorus Compounds
  10. Polymeric Double [Cu(NCS)] Chains in the Crystal Structure of [Cu2(Me2Ea)2(SCN)2]∞ (HMe2Ea = 2-Dimethylaminoethanol) (NewP olymorph) and the Dimeric Structure of its DMSO Adduct
  11. Isolation and Structure Elucidation of Two New Xanthones from Gentiana azurium Bunge (Fam. Gentianaceae)
  12. 5-(2-Methylphenyl)-4-pentenoic Acid from a Terrestrial Streptomycete
  13. Optically Active Cyclopentadienyl Ligands from the Chiral Pool, Part 1. The Synthetic Utility of a Camphor-Derived Pentafulvene
  14. Complexation of Organic Dyes by Peptides Built of Lysine and Glutamic Acid Amides
  15. N-Arylsulfonyl-benzimidazolones as Potential Hypoglycemic Agents
  16. Synthesis of AM15C5 Bonded Merrifield Peptide Resin and its Separating Properties
  17. Notizen: Synthesis and Characterization of Nadorite: PbSbO2Cl
https://doi.org/10.1515/znb-2002-0309
Keywords for this article
peri-Interactions in Naphthalenes; Phosphorus Compounds

Articles in the same Issue

  1. Magnetic Super-Exchange Mechanism and Crystal Structure of a Binuclear μ-Acetato-Bridged Copper(II) Complex of Pentadentate Binucleating Ligand.An Influence of Overlap Interactions to Magnetic Properties
  2. Cationic Ruthenium-Sulfine Complexes: Synthesis and Dynamic Behaviour
  3. Palladium-Cadmium Ordering In Repdcd (Re = La, Ce, Pr, Nd, Sm, Eu, Gd, Tb) And Comparison With Isotypic Indium Compounds
  4. Metallkomplexe mit biologisch wichtigen Liganden, CXLXXX [1]. Kationische Bis(α-Aminosäuremethylester)-N,O-Chelatkomplexe von Palladium(II) [Pd(NH2CHRCO2Me)2]2+(BF4–)2/ Metal Complexes of Biologically Important Ligands, CXLXXX [1]. Cationic Bis(α-Amino Acid Methylester)-N,O-Chelate Complexes of Palladium(II) [(Pd(NH2CHRCO2Me)2]2+(BF4–)2
  5. Synthesis and Structural Characterization of Aminoalkanol Derivatives of 2,3-Dihydro-2,2-dimethyl-7-benzofuranol with an Expected β-Adrenolytic and / or Anxiolytic Activity
  6. Hydroboration and Haloboration of Propyne and 1-Butyne
  7. Excited State Behavior of Uranyl Complexes with Salophen and Oxine as Chromophoric Ligands
  8. 57Fe NMR Spectroscopy of Some Sila-[1]ferrocenophanes and a Phospha-[1]ferrocenophane
  9. peri-Interactions in Naphthalenes, 7 [1]. A Hetera-naphthalene as a Model Compound for 8-Dimethylaminonaphth- 1-yl Silicon and Phosphorus Compounds
  10. Polymeric Double [Cu(NCS)] Chains in the Crystal Structure of [Cu2(Me2Ea)2(SCN)2]∞ (HMe2Ea = 2-Dimethylaminoethanol) (NewP olymorph) and the Dimeric Structure of its DMSO Adduct
  11. Isolation and Structure Elucidation of Two New Xanthones from Gentiana azurium Bunge (Fam. Gentianaceae)
  12. 5-(2-Methylphenyl)-4-pentenoic Acid from a Terrestrial Streptomycete
  13. Optically Active Cyclopentadienyl Ligands from the Chiral Pool, Part 1. The Synthetic Utility of a Camphor-Derived Pentafulvene
  14. Complexation of Organic Dyes by Peptides Built of Lysine and Glutamic Acid Amides
  15. N-Arylsulfonyl-benzimidazolones as Potential Hypoglycemic Agents
  16. Synthesis of AM15C5 Bonded Merrifield Peptide Resin and its Separating Properties
  17. Notizen: Synthesis and Characterization of Nadorite: PbSbO2Cl
Sign up now to receive a 20% welcome discount
Institutional Access
How does access work?
Have an idea on how to improve our website?
Please write us.
© 2025 De Gruyter Brill
Downloaded on 18.9.2025 from https://www.degruyterbrill.com/document/doi/10.1515/znb-2002-0309/html
Scroll to top button