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Complexation of Organic Dyes by Peptides Built of Lysine and Glutamic Acid Amides

  • Heinz Mehlmann , Daniel Olschewski , Andrey Olschewski and Martin Feigel EMAIL logo
Published/Copyright: June 2, 2014
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Zeitschrift für Naturforschung B
From the journal Zeitschrift für Naturforschung B Volume 57 Issue 3

Abstract

Two amide libraries, Fmoc-[Lys(aci)]4-Gly-resin (1) (aci = 2-naphthylcarbonyl, 1-adamantylcarbonyl and benzyloxycarbonyl) and Fmoc-[δ-Glu(α-amidei)]4-Gly-resin (2) (amidei = morpholineamide, piperidineamide, (N´-phenyl)-piperazineamide), have been synthesized from the corresponding Fmoc-protected amino acid derivatives. Beads of the libraries complex organic dyes (crystal violet and Sudan black) differently according to the sequence of residues in 1 or 2. The results are considered a step towards artificial receptors for small organic molecules build from linear oligoamides.

Keywords : Amino Acids; Complexation; Combinatorial Chemistry
Received: 2001-10-11
Published Online: 2014-6-2
Published in Print: 2002-3-1

© 1946 – 2014: Verlag der Zeitschrift für Naturforschung

Articles in the same Issue

  1. Magnetic Super-Exchange Mechanism and Crystal Structure of a Binuclear μ-Acetato-Bridged Copper(II) Complex of Pentadentate Binucleating Ligand.An Influence of Overlap Interactions to Magnetic Properties
  2. Cationic Ruthenium-Sulfine Complexes: Synthesis and Dynamic Behaviour
  3. Palladium-Cadmium Ordering In Repdcd (Re = La, Ce, Pr, Nd, Sm, Eu, Gd, Tb) And Comparison With Isotypic Indium Compounds
  4. Metallkomplexe mit biologisch wichtigen Liganden, CXLXXX [1]. Kationische Bis(α-Aminosäuremethylester)-N,O-Chelatkomplexe von Palladium(II) [Pd(NH2CHRCO2Me)2]2+(BF4–)2/ Metal Complexes of Biologically Important Ligands, CXLXXX [1]. Cationic Bis(α-Amino Acid Methylester)-N,O-Chelate Complexes of Palladium(II) [(Pd(NH2CHRCO2Me)2]2+(BF4–)2
  5. Synthesis and Structural Characterization of Aminoalkanol Derivatives of 2,3-Dihydro-2,2-dimethyl-7-benzofuranol with an Expected β-Adrenolytic and / or Anxiolytic Activity
  6. Hydroboration and Haloboration of Propyne and 1-Butyne
  7. Excited State Behavior of Uranyl Complexes with Salophen and Oxine as Chromophoric Ligands
  8. 57Fe NMR Spectroscopy of Some Sila-[1]ferrocenophanes and a Phospha-[1]ferrocenophane
  9. peri-Interactions in Naphthalenes, 7 [1]. A Hetera-naphthalene as a Model Compound for 8-Dimethylaminonaphth- 1-yl Silicon and Phosphorus Compounds
  10. Polymeric Double [Cu(NCS)] Chains in the Crystal Structure of [Cu2(Me2Ea)2(SCN)2]∞ (HMe2Ea = 2-Dimethylaminoethanol) (NewP olymorph) and the Dimeric Structure of its DMSO Adduct
  11. Isolation and Structure Elucidation of Two New Xanthones from Gentiana azurium Bunge (Fam. Gentianaceae)
  12. 5-(2-Methylphenyl)-4-pentenoic Acid from a Terrestrial Streptomycete
  13. Optically Active Cyclopentadienyl Ligands from the Chiral Pool, Part 1. The Synthetic Utility of a Camphor-Derived Pentafulvene
  14. Complexation of Organic Dyes by Peptides Built of Lysine and Glutamic Acid Amides
  15. N-Arylsulfonyl-benzimidazolones as Potential Hypoglycemic Agents
  16. Synthesis of AM15C5 Bonded Merrifield Peptide Resin and its Separating Properties
  17. Notizen: Synthesis and Characterization of Nadorite: PbSbO2Cl
https://doi.org/10.1515/znb-2002-0314
Keywords for this article
Amino Acids; Complexation; Combinatorial Chemistry

Articles in the same Issue

  1. Magnetic Super-Exchange Mechanism and Crystal Structure of a Binuclear μ-Acetato-Bridged Copper(II) Complex of Pentadentate Binucleating Ligand.An Influence of Overlap Interactions to Magnetic Properties
  2. Cationic Ruthenium-Sulfine Complexes: Synthesis and Dynamic Behaviour
  3. Palladium-Cadmium Ordering In Repdcd (Re = La, Ce, Pr, Nd, Sm, Eu, Gd, Tb) And Comparison With Isotypic Indium Compounds
  4. Metallkomplexe mit biologisch wichtigen Liganden, CXLXXX [1]. Kationische Bis(α-Aminosäuremethylester)-N,O-Chelatkomplexe von Palladium(II) [Pd(NH2CHRCO2Me)2]2+(BF4–)2/ Metal Complexes of Biologically Important Ligands, CXLXXX [1]. Cationic Bis(α-Amino Acid Methylester)-N,O-Chelate Complexes of Palladium(II) [(Pd(NH2CHRCO2Me)2]2+(BF4–)2
  5. Synthesis and Structural Characterization of Aminoalkanol Derivatives of 2,3-Dihydro-2,2-dimethyl-7-benzofuranol with an Expected β-Adrenolytic and / or Anxiolytic Activity
  6. Hydroboration and Haloboration of Propyne and 1-Butyne
  7. Excited State Behavior of Uranyl Complexes with Salophen and Oxine as Chromophoric Ligands
  8. 57Fe NMR Spectroscopy of Some Sila-[1]ferrocenophanes and a Phospha-[1]ferrocenophane
  9. peri-Interactions in Naphthalenes, 7 [1]. A Hetera-naphthalene as a Model Compound for 8-Dimethylaminonaphth- 1-yl Silicon and Phosphorus Compounds
  10. Polymeric Double [Cu(NCS)] Chains in the Crystal Structure of [Cu2(Me2Ea)2(SCN)2]∞ (HMe2Ea = 2-Dimethylaminoethanol) (NewP olymorph) and the Dimeric Structure of its DMSO Adduct
  11. Isolation and Structure Elucidation of Two New Xanthones from Gentiana azurium Bunge (Fam. Gentianaceae)
  12. 5-(2-Methylphenyl)-4-pentenoic Acid from a Terrestrial Streptomycete
  13. Optically Active Cyclopentadienyl Ligands from the Chiral Pool, Part 1. The Synthetic Utility of a Camphor-Derived Pentafulvene
  14. Complexation of Organic Dyes by Peptides Built of Lysine and Glutamic Acid Amides
  15. N-Arylsulfonyl-benzimidazolones as Potential Hypoglycemic Agents
  16. Synthesis of AM15C5 Bonded Merrifield Peptide Resin and its Separating Properties
  17. Notizen: Synthesis and Characterization of Nadorite: PbSbO2Cl
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