Encapsulation of anion-cation organo-montmorillonite in terpolymer microsphere: structure, morphology, and properties
-
Yuan Lin
,
Chengcheng Yu
Abstract
Exfoliated organo-montmorillonite (O-Mt) layers were successfully encapsulated in a terpolymer microsphere (PAAA) of acrylamide (AM)/acrylic acid (AA)/2-acrylamido-2-methylpropanesulfonic acid (AMPS) via in situ inverse suspension polymerization, with the aid of the organic modification by cetyltrimethylammonium bromide (CTAB) and sodium lauryl sulfonate (SLS). The chemical structure and properties of the Mt were characterized by Fourier transform infrared (FTIR), X-ray diffraction (XRD) and thermogravimetric analysis (TGA), which showed that SLS molecules successfully intercalated Mt interlayers and enhanced the thermostability of Mt. The microsphere morphologies of the polymer and its nanocomposites were detected by scanning electron microscopy (SEM). The results of X-ray diffraction (XRD) and transmission electron microscopy (TEM) confirmed that the exfoliated O-Mt dispersed in the polymer matrix. The introduction of well-dispersed O-Mt layers significantly enhanced the comprehensive performance of these microspheres, including thermostability and plugging properties. The Tmax of PAAA/1.5 wt.% O-Mt nanocomposite is increased by 46°C compared to the pure terpolymer. The plugging rate of PAAA/2.0 wt.% O-Mt reached up to 85.8%. Therefore, these selected nanocomposite microspheres can provide an effective plugging in the high-permeability layers.
Funding source: National Natural Science Foundation of China
Award Identifier / Grant number: 51974339
Award Identifier / Grant number: 51674270
Funding statement: This work was financially supported by the National Natural Science Foundation of China (grant nos. 51974339; 51674270, Funder Id: http://dx.doi.org/10.13039/501100001809), National Major Project (grant no. 2017ZX05009-003), Major Project of the National Natural Science Foundation of China (no. 51490650), and the Foundation for Innovative Research Groups of the National Natural Science Foundation of China (grant nos. 51821092; 51521063)
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©2020 Walter de Gruyter GmbH, Berlin/Boston
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- Frontmatter
- Material properties
- Interface properties of carbon fiber reinforced cyanate/epoxy resin composites at cryogenic temperature
- A new method to calculate the surface haze
- Structure and properties of particles/rubber composites applied on functionally graded lapping and polishing plate
- Adhesive properties of bio-based epoxy resin reinforced by cellulose nanocrystal additives
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- Encapsulation of anion-cation organo-montmorillonite in terpolymer microsphere: structure, morphology, and properties
- Preparation and characterization of chitosan grafted poly(lactic acid) films for biomedical composites
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Articles in the same Issue
- Frontmatter
- Material properties
- Interface properties of carbon fiber reinforced cyanate/epoxy resin composites at cryogenic temperature
- A new method to calculate the surface haze
- Structure and properties of particles/rubber composites applied on functionally graded lapping and polishing plate
- Adhesive properties of bio-based epoxy resin reinforced by cellulose nanocrystal additives
- Preparation and assembly
- Encapsulation of anion-cation organo-montmorillonite in terpolymer microsphere: structure, morphology, and properties
- Preparation and characterization of chitosan grafted poly(lactic acid) films for biomedical composites
- Preparation and characterization of polyvinylpyrrolidone/cobalt ferrite functionalized chitosan graphene oxide (CoFe2O4@CS@GO-PVP) nanocomposite
- Clay/(PEG-CMC) biocomposites as a novel delivery system for ibuprofen
- Engineering and processing
- Multi-objective optimization of injection-molded plastic parts using entropy weight, random forest, and genetic algorithm methods
