Lack-of-fit reduction in non-equilibrium thermodynamics applied to the Kac–Zwanzig model
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Kateřina Mladá
Abstract
Even when microscopic particle dynamics is purely mechanistic and thus reversible, the behavior of macroscopic systems composed of those particles is irreversible. In other words, effectively irreversible behavior emerges out of purely reversible dynamics when we do not observe all degrees of freedom of the detailed dynamics. But how can we find the irreversible macroscopic evolution equations when we only know the reversible microscopic equations? Using the so-called lack-of-fit reduction, which gives the reduced evolution as a sum of Hamiltonian and gradient dynamics, we reduce the purely Hamiltonian Kac–Zwanzig model to a set of irreversible evolution equations with no fitting parameters.
Funding source: Czech Science Foundation
Award Identifier / Grant number: 23-05736S
Acknowledgments
MP is a member of the Nečas center for Mathematical Modelling. We are grateful to Bruce Turkington for discussions on the lack-of-fit reduction. Moreover, we are grateful to Miroslav Grmela and Václav Klika for many discussions on non-equilibrium thermodynamics.
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Research ethics: Not applicable.
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Author contributions: KM made most of the calculations, MŠ wrote the original version of the simulation code, and MP wrote most of the text.
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Competing interests: No competing interests.
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Research funding: KM, MŠ, and MP were supported by Czech Science Foundation, project 23-05736S.
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Data availability: Not applicable.
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Articles in the same Issue
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- Thermodynamic costs of temperature stabilization in logically irreversible computation
- Hydrodynamic, electronic and optic analogies with heat transport in extended thermodynamics
- Variations on the models of Carnot irreversible thermomechanical engine
- Revisit nonequilibrium thermodynamics based on thermomass theory and its applications in nanosystems
- On the dynamic thermal conductivity and diffusivity observed in heat pulse experiments
- On the influence of the fourth order orientation tensor on the dynamics of the second order one
- Lack-of-fit reduction in non-equilibrium thermodynamics applied to the Kac–Zwanzig model
- Optimized quantum drift diffusion model for a resonant tunneling diode
- The wall effect in a plane counterflow channel
- Buoyancy driven convection with a Cattaneo flux model
- Thermodynamics of micro- and nano-scale flow and heat transfer: a mini-review
- Poroacoustic front propagation under the linearized Eringen–Cattaneo–Christov–Straughan model
Articles in the same Issue
- Frontmatter
- Editorial
- Thermodynamic costs of temperature stabilization in logically irreversible computation
- Hydrodynamic, electronic and optic analogies with heat transport in extended thermodynamics
- Variations on the models of Carnot irreversible thermomechanical engine
- Revisit nonequilibrium thermodynamics based on thermomass theory and its applications in nanosystems
- On the dynamic thermal conductivity and diffusivity observed in heat pulse experiments
- On the influence of the fourth order orientation tensor on the dynamics of the second order one
- Lack-of-fit reduction in non-equilibrium thermodynamics applied to the Kac–Zwanzig model
- Optimized quantum drift diffusion model for a resonant tunneling diode
- The wall effect in a plane counterflow channel
- Buoyancy driven convection with a Cattaneo flux model
- Thermodynamics of micro- and nano-scale flow and heat transfer: a mini-review
- Poroacoustic front propagation under the linearized Eringen–Cattaneo–Christov–Straughan model
