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Hydrophobisation and densification of wood by different chemical treatments

  • Sylvie Bach , Mohamed Naceur Belgacem and Alessandro Gandini
Published/Copyright: July 5, 2005
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Holzforschung
From the journal Volume 59 Issue 4

Abstract

Samples of Pinus sylvestris were treated with different reagents bearing isocyanate, carboxylic anhydride or oxirane functions to induce reaction with the OH groups of the various components of wood. Conditions were optimised to achieve maximum grafting. When the reagents also carried a polymerisable function, a monomer (styrene or methyl methacrylate) was incorporated into the wood morphology after the derivatisation reaction. Subsequent radical polymerisation produced chemical incorporation of some of the resulting macromolecules. The properties of the doubly modified samples were assessed using a wide variety of tests. Both the hydrophobic character and the density increased considerably, suggesting improved lifetime and extended domains of application.

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Corresponding author. Instituto de Química de São Carlos, Universidade de São Paulo, Av. Trabalhador São Carlense, 400, 13566-590 São Carlos, SP, Brazil Fax: +55-16-3373-9952

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Published Online: 2005-07-05
Published in Print: 2005-07-01

© Walter de Gruyter Berlin New York

Articles in the same Issue

  1. Chemical changes in silver birch (Betula pendula Roth) wood caused by hydrogen peroxide bleaching and monitored by color measurement (CIELab) and UV-Vis, FTIR and UVRR spectroscopy
  2. Hydrophobisation and densification of wood by different chemical treatments
  3. Functionalisation of wood by reaction with 3-isocyanatopropyltriethoxysilane: Grafting and hydrolysis of the triethoxysilane end groups
  4. Isolation and fractionation of lignosulfonates by amine extraction and ultrafiltration: A comparative study
  5. Bioactive phenolic substances in industrially important tree species. Part 4: Identification of two new 7-hydroxy divanillyl butyrolactol lignans in some spruce, fir, and pine species
  6. Characterization of physiological functions of sapwood IV: Formation and accumulation of lignans in sapwood of Cryptomeria japonica (L.f.) D. Don after felling
  7. X-ray scattering studies of thermally modified Scots pine (Pinus sylvestris L.)
  8. Differences in acoustic velocity by resonance and transit-time methods in an anisotropic laminated wood medium
  9. Parallel-plate rheology of latex films bonded to wood
  10. An assessment of the feasibility of ultrasound as a defect detector in lumber
  11. Vibrational properties of green wood in high-temperature water vapor
  12. The stiffness modulus in Norway spruce as a function of year ring
  13. Strain analysis in bulk forming of wood
  14. Decay fungi from playground wood products in service using 28S rDNA sequence analysis
  15. Effect of climatic variables on chromated copper arsenate (CCA) leaching during above-ground exposure
  16. Protic ionic liquids with organic anion as wood preservative
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