Volume 2, Issue 3

Neogene to Quaternary volcanic/magmatic activity in the Carpathian-Pannonian Region (CPR) occurred between 21 and 0.1 Ma with a distinct migration in time from west to east. It shows a diverse compositional variation in response to a complex interplay of subduction with rollback, back-arc extension, collision, slab break-off, delamination, strike-slip tectonics and microplate rotations, as well as in response to further evolution of magmas in the crustal environment by processes of differentiation, crustal contamination, anatexis and magma mixing. Since most of the primary volcanic forms have been affected by erosion, especially in areas of post-volcanic uplift, based on the level of erosion we distinguish: (1) areas eroded to the basement level, where paleovolcanic reconstruction is not possible; (2) deeply eroded volcanic forms with secondary morphology and possible paleovolcanic reconstruction; (3) eroded volcanic forms with remnants of original morphology preserved; and (4) the least eroded volcanic forms with original morphology quite well preserved. The large variety of volcanic forms present in the area can be grouped in a) monogenetic volcanoes and b) polygenetic volcanoes and their subsurface/intrusive counterparts that belong to various rock series found in the CPR such as calc-alkaline magmatic rock-types (felsic, intermediate and mafic varieties) and alkalic types including K-alkalic, shoshonitic, ultrapotassic and Na-alkalic. The following volcanic/subvolcanic forms have been identified: (i) domes, shield volcanoes, effusive cones, pyroclastic cones, stratovolcanoes and calderas with associated intrusive bodies for intermediate and basic calclkaline volcanism; (ii) domes, calderas and ignimbrite/ash-flow fields for felsic calc-alkaline volcanism and (iii) dome flows, shield volcanoes, maars, tuffcone/tuff-rings, scoria-cones with or without related lava flow/field and their erosional or subsurface forms (necks/ plugs, dykes, shallow intrusions, diatreme, lava lake) for various types of K- and Na-alkalic and ultra-potassic magmatism. Finally, we provide a summary of the eruptive history and distribution of volcanic forms in the CPR using several sub-region schemes.

The Kos Plateau Tuff is a large (>60 km3) and young (160 k.y.) calc-alkaline, high-SiO2 rhyolitic ignimbrite from the active Kos-Nisyros volcanic center in the Aegean arc (Greece). Combined textural, petrological and geochemical information suggest that (1) the system evolved dominantly by crystal fractionation from (mostly unerupted) more mafic parents, (2) the magma chamber grew over ≥ 250 000 years at shallow depth (∼1.5-2.5 kb) and was stored as a H2O-rich crystalline mush close to its solidus (∼670-750°C), (3) the eruption occurred after a reheating event triggered by the intrusion of hydrous mafic magma at the base of the rhyolitic mush. Rare banded pumices indicate that the mafic magma only mingled with a trivial portion of resident crystal-rich rhyolite; most of the mush was remobilized following partial melting of quartz and feldspars induced by advection of heat and volatiles from the underplated, hotter mafic influx.

The Efate Pumice Formation (EPF) is a trachydacitic volcaniclastic succession widespread in the central part of Efate Island and also present on Hat and Lelepa islands to the north. The volcanic succession has been inferred to result from a major, entirely subaqueous explosive event north of Efate Island. The accumulated pumice-rich units were previously interpreted to be subaqueous pyroclastic density current deposits on the basis of their bedding, componentry and stratigraphic characteristics. Here we suggest an alternative eruptive scenario for this widespread succession. The major part of the EPF is distributed in central Efate, where pumiceous pyroclastic rock units several hundred meters thick are found within fault scarp cliffs elevated about 800 m above sea level. The basal 200 m of the pumiceous succession is composed of massive to weakly bedded pumiceous lapilli units, each 2-3 m thick. This succession is interbedded with wavy, undulatory and dune bedded pumiceous ash and fine lapilli units with characteristics of co-ignimbrite surges and ground surges. The presence of the surge beds implies that the intervening units comprise a subaerial ignimbrite-dominated succession. There are no sedimentary indicators in the basal units examined that are consistent with water-supported transportation and/or deposition. The subaerial ignimbrite sequence of the EPF is overlain by a shallow marine volcaniclastic Rentanbau Tuffs. The EPF is topped by reef limestone, which presumably preserved the underlying EPF from erosion. We here propose that the EPF was formed by a combination of initial subaerial ignimbrite-forming eruptions, followed by caldera subsidence. The upper volcaniclastic successions in our model represent intra-caldera pumiceous volcaniclastic deposits accumulated in a shallow marine environment in the resultant caldera. The present day elevated position of the succession is a result of a combination of possible caldera resurgence and ongoing arc-related uplift in the region.

Bontâu is a major eroded composite volcano filling the Miocene Zârand extensional basin, near the junction between the Codru-Moma and Highiş-Drocea Mountains, at the tectonic boundary between the South and North Apuseni Mountains. It is a quasi-symmetric structure (16–18 km in diameter) centered on an eroded vent area (9×4 km), buttressed to the south against Mesozoic ophiolites and sedimentary deposits of the South Apuseni Mountains. The volcano was built up in two sub-aerial phases (14–12.5 Ma and 11–10 Ma) from successive eruptions of andesite lava and pyroclastic rocks with a time-increasing volatile budget. The initial phase was dominated by emplacement of pyroxene andesite and resulted in scattered individual volcanic lava domes associated marginally with lava flows and/or pyroclastic block-and-ash flows. The second phase is characterized by amphibole-pyroxene andesite as a succession of pyroclastic eruptions (varying from strombolian to subplinian type) and extrusion of volcanic domes that resulted in the formation of a central vent area. Numerous debris flow deposits accumulated at the periphery of primary pyroclastic deposits. Several intrusive andesitic-dioritic bodies and associated hydrothermal and mineralization processes are known in the volcano vent complex area. Distal epiclastic deposits initially as gravity mass flows and then as alluvial volcaniclastic and terrestrial detritic and coal filled the basin around the volcano in its western and eastern part. Chemical analyses show that lavas are calc-alkaline andesites with SiO2 ranging from 56–61%. The petrographical differences between the two stages are an increase in amphibole content at the expense of two pyroxenes (augite and hypersthene) in the second stage of eruption; CaO and MgO contents decrease with increasing SiO2. In spite of a ∼4 Ma evolution, the compositions of calc-alkaline lavas suggest similar fractionation processes. The extensional setting favored two pulses of short-lived magma chamber processes.

Late Quaternary andesitic magmas in New Zealand contain complexly zoned antecrysts and glomerocrysts that are not in equilibrium with either the host whole rock compositions or siliceous groundmass glass and glass inclusions. Glass inclusions represent partial melts of mafic to gabbroic cumulates in the lower crust that mix with restite crystals, or cumulates from earlier magma batches. Assimilation of partial melts of mid-crustal rocks, represented by glass in crustal xenoliths, contributes a crustal component to the andesites. Magmas at Egmont are stored at about the brittle/ductile transition at about 10 km depth and variability in the composition of erupted material is a function of the composition of the recharging magma, and which parts of the storage system are tapped during the eruption. At Taranaki recharge occurs on a c. 1400 year cycle while interactions within the storage give rise to shorter period events. A similar process on a less well constrained timescale operates at Ruapehu. Andesites are therefore complex mixtures of fractionated mantle basalts, siliceous partial melts of both the lower crust and underplated cumulates, restite and cumulate crystals. Further modification occurs by interaction with partial melts of lower to middle crustal basement as geotherms increase with time.

The Pannonian Basin (Central Europe) hosts numerous alkali basaltic volcanic fields in an area similar to 200 000 km2. These volcanic fields were formed in an approximate time span of 8 million years producing smallvolume volcanoes typically considered to be monogenetic. Polycyclic monogenetic volcanic complexes are also common in each field however. The original morphology of volcanic landforms, especially phreatomagmatic volcanoes, is commonly modified. by erosion, commonly aided by tectonic uplift. The phreatomagmatic volcanoes eroded to the level of their sub-surface architecture expose crater to conduit filling as well as diatreme facies of pyroclastic rock assemblages. Uncertainties due to the strong erosion influenced by tectonic uplifts, fast and broad climatic changes, vegetation cover variations, and rapidly changing fluvio-lacustrine events in the past 8 million years in the Pannonian Basin have created a need to reconstruct and visualise the paleoenvironment into which the monogenetic volcanoes erupted. Here phreatomagmatic volcanic fields of the Miocene to Pleistocene western Hungarian alkali basaltic province have been selected and compared with modern phreatomagmatic fields. It has been concluded that the Auckland Volcanic Field (AVF) in New Zealand could be viewed as a prime modern analogue for the western Hungarian phreatomagmatic fields by sharing similarities in their pyroclastic successions textures such as pyroclast morphology, type, juvenile particle ratio to accidental lithics. Beside the AVF two other, morphologically more modified volcanic fields (Pali Aike, Argentina and Jeju, Korea) show similar features to the western Hungarian examples, highlighting issues such as preservation potential of pyroclastic successions of phreatomagmatic volcanoes.

Bondoró Volcanic Complex (shortly Bondoró) is one of the most complex eruption centre of Bakony-Balaton Highland Volcanic Field, which made up from basaltic pyroclastics sequences, a capping confined lava field (~4 km2) and an additional scoria cone. Here we document and describe the main evolutional phases of the Bondoró on the basis of facies analysis, drill core descriptions and geomorphic studies and provide a general model for this complex monogenetic volcano. Based on the distinguished 13 individual volcanic facies, we infer that the eruption history of Bondoró contained several stages including initial phreatomagmatic eruptions, Strombolian-type scoria cones forming as well as effusive phases. The existing and newly obtained K-Ar radiometric data have confirmed that the entire formation of the Bondoró volcano finished at about 2.3 Ma ago, and the time of its onset cannot be older than 3.8 Ma. Still K-Ar ages on neighbouring formations (e.g. Kab-hegy, Agár-teto) do not exclude a long-lasting eruptive period with multiple eruptions and potential rejuvenation of volcanic activity in the same place indicating stable melt production beneath this location. The prolonged volcanic activity and the complex volcanic facies architecture of Bondoró suggest that this volcano is a polycyclic volcano, composed of at least two monogenetic volcanoes formed more or less in the same place, each erupted through distinct, but short lived eruption episodes. The total estimated eruption volume, the volcanic facies characteristics and geomorphology also suggests that Bondoró is rather a small-volume polycyclic basaltic volcano than a polygenetic one and can be interpreted as a nested monogenetic volcanic complex with multiple eruption episodes. It seems that Bondoró is rather a “rule” than an “exception” in regard of its polycyclic nature not only among the volcanoes of the Bakony-Balaton Highland Volcanic Field but also in the Neogene basaltic volcanoes of the Pannonian Basin.

The Bakony-Balaton Highland Volcanic Field (BBHVF) is located in the central part of Transdanubia, Pannonian Basin, with over 50 alkali basaltic volcanoes. The basanite plug of Hegyestu erupted in the first phase of volcanic activity. K/Ar and Ar/Ar ages were published for the BBHVF. K/Ar and Ar/Ar ages of the leucite-bearing basanite of Hegyestás were conflicting. This is caused by the special Ar retention feature of leucite in this basanite. K/Ar ages measured in the usual way were 25–45% younger, but after HCl treatment of the rock, or after reducing the baking temperature of the argon extraction line from 250°C to 150°C, they became similar to the Ar/Ar ages. All Ar/Ar determinations were performed after HF treatment. HCl treatment dissolved olivine, nepheline, leucite, magnetite and from 1-1 sample analcime or calcite. K dissolution studies from different locations of Hegyestü have shown that K content is mostly ≈2%, but it may decrease to ≈0.3%. HCl treatment dissolved 28.0–63.5% of the K content. The calculated K concentration for the dissolved part of samples with ~2%K was 4.02-6.42%: showing that leucite is responsible for the low temperature loss of 40Ar(rad). Ar may release at low temperature from very finegrained mineral, or when the Ar release mechanism changes. A 40Ar(rad) degassing spectrum has been recorded in the 55–295°C range of baking temperature and the data were plotted in the Arrhenius diagram. The diagram shows that a change of the structure in the 145–295°C range caused the loss of 40Ar(rad). On fractions of HCl treated rock 7.56±0.17 Ma isochron K/Ar age has been determined. This is regarded as minimum age of eruption and it is similar to the Ar/Ar isochron age (7.78±0.07 Ma).

The majority of the Mio-Pleistocene monogenetic volcanoes in Western Hungary had, at least in their initial eruptive phase, phreatomagmatic eruptions that produced pyroclastic deposits rich in volcanic glass shards. Electron microprobe studies on fresh samples of volcanic glass from the pyroclastic deposits revealed a primarily tephritic composition. A shape analysis of the volcanic glass shards indicated that the fine-ash fractions of the phreatomagmatic material fragmented in a brittle fashion. In general, the glass shards are blocky in shape, low in vesicularity, and have a low-to-moderate microlite content. The glass-shape analysis was supplemented by fractal dimension calculations of the glassy pyroclasts. The fractal dimensions of the glass shards range from 1.06802 to 1.50088, with an average value of 1.237072876, based on fractal dimension tests of 157 individual glass shards. The average and mean fractal-dimension values are similar to the theoretical Koch-flake (snowflake) value of 1.262, suggesting that the majority of the glass shards are bulky with complex boundaries. Light-microscopy and backscattered-electron-microscopy images confirm that the glass shards are typically bulky with fractured and complex particle outlines and low vesicularity; features that are observed in glass shards generated in either a laboratory setting or naturally through the interaction of hot melt and external water. Textural features identified in fine- and coarse-ash particles suggest that they were formed by brittle fragmentation both at the hot melt-water interface (forming active particles) as well as in the vicinity of the interaction interface. Brittle fragmentation may have occurred when hot melt rapidly penetrated abundant water-rich zones causing the melt to cool rapidly and rupture explosively.

Lack of age dates in the terrigenous Cenozoic sediments of the Duero and the Ebro sedimentary basins has complicated tecto-stratic correlation across the two basins. We tentatively synthesize a range of existing studies and new data to construct a rough general paleogeography throughout Upper Cenozoic times. The more extensive erosion of the Ebro has been previously attributed to the earlier moment of opening. We tentatively analyse lithostratic data to conclude that the lower knick-point and different lithologies have also contributed to the deeper erosion in the Ebro Basin. We conclude from lithostratic data and field evidence that the W half of the Rioja was part of the Duero in earlier times and that the escarpment retreated westward through the Rioja in four subsequent episodes of erosion. The tilt of the NW Duero is a consequence of isostatic rebound to this erosion.