Optical Properties and Structure of Tetrapyrroles: Proceedings of a Symposium held at the University of Konstanz West Germany, August 12–17, 1984

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Optical Properties and Structure of Tetrapyrroles

Proceedings of a Symposium held at the University of Konstanz West Germany, August 12–17, 1984

Edited by: Gideon Blauer and Horst Sund

Language: English

Published/Copyright: 1985

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Industrial Chemistry Analytical Chemistry

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Frontmatter
I

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Preface
V

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Contents
VII

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List Of Contributors
XI

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Section I. General
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An Historical Survey of Porphyrins, their Related Spectra, and their Interpretation
3
Alan D. Adler and Martin Gouterman

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Routes to Functional Porphyrin Assemblies (Molecular Complexes, Covalent Redox Pairs, and Reactive Domains in Vesicles)
19
Jürgen-Hinrich Fuhrhop and Thomas Lehmann

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Organism Dependent Pathways of Tetrapyrrole Biosynthesis
43
Dieter Dörnemann and Horst Senger

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Section II. Porphyrins And Metalloporphyrins
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Transient Absorption Spectra and Excited State Kinetics of Transition Metal Porphyrins
63
Dewey Holten and Martin Gouterman

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Metal Complexes of Tetrapyrrole Ligands. XXXVII. Structure and Optical Spectra of Sandwich-Like Lanthanoid Porphyrins
91
Johann W. Buchler and Martina Knoff

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Excited State Electron Transfer of Carbonyl[mesotetra(p-tolyl) porphyrinato osmium(II)]Complexes. One and Two Electron Photoredox Processes
107
Arnd Vogler, Josef Kisslinger and Johann Walter Buchler

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Photophysical Properties of Hematoporphyrin and its Derivatives and their Use in Tumor Phototherapy
121
A. Andreoni and R. Cubeddu

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Optical Properties of Ferriheme-Quinidine Complexes
137
G. Blauer

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Resonance Raman Studies of Haemoglobin
157
Kiyoshi Nagai

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Optical Properties of Heme Bound to the Central Exon Fragment of Globins and to Corresponding Fragments in Cytochromes
175
Sherman Beychok

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Heme Configuration in Cytochrome c
203
Yash P. Myer

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Correlation between Near-Infrared, ESR Spectra and Oxidation- Reduction Potentials in Low-Spin Heme Proteins
227
Abel Schejter, Ida Vig and William A. Eaton

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Circular Dichroism Contributions of Heme-Heme and Chlorophyll- Chlorophyll Interactions
239
Robert W. Woody

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Optical Properties of Conjugated Proteins which Transport Haem, Porphyrins and Bilirubin
261
Brian Ketterer

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Section III. Bile Pigments
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Light Absorption of Bilatrienes-abc and 2,3-Dihydrobilatrienes-abc
281
Heinz Falk

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Mechanism of Phototherapy of Neonatal Jaundice. Regiospecific Photoisomerization of Bilirubins
297
Antony F. McDonagh and David A. Lightner

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Effects of Environment on Photophysical Processes of Bilirubin
311
Angelo A. Lamola

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The Molecular Model of Phytochrome Deduced from Optical Probes
331
Pill-Soon Song

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Phytochrome, the Visual Pigment of Plants: Chromophore Structure and Chemistry of Photoconversion
349
Wolfhart Rüdiger, Peter Eilfeld and Friedrich Thümmler

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Recent Advances in the Photophysics and Photochemistry of Small, Large, and Native Oat Phytochromes
367
Kurt Schaffner, Silvia E. Braslavsky and Alfred R. Holzwarth

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Contents IX Time-Resolved Fluorescence Depolarisation of Phycocyanins in Different States of Aggregation
383
Siegfried Schneider, Peter Geiselhart, Toni Mindl, Peter Hefferle and Friedrich Dörr

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The Influence of an External Electrical Charge on the Circular Dichroism of Chromopeptides from Phycocyanin
397
Christina Scharnagl, Eliana Köst-Reyes, Siegfried Schneider and Joachim Otto

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Bilins and Bilin-Protein Linkages in Phycobili proteins: Structural and Spectroscopic Studies
411
Henry Rapoport and Alexander N. Glazer

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Structural Organization of Tetrapyrrole Pigments in Light- Harvesting Pigment-Protein Complexes
425
Herbert Zuber

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The Crystal and Molecular Structure of C-Phycocyanin from Mastigocladus laminosus and its Implications for Function and Evolution
445
Tilman Schirmer, Wolfram Bode, Robert Huber, Walter Sidler and Herbert Zuber

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Section IV. Chlorophylls
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Optical Spectra of Photosynthetic Reaction Centers. Theoretical and Experimental Aspects
453
A.J. Hoff

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Circular Dichroism of Chlorophylls in Protein Complexes from Chloroplasts of Higher Plants: A Critical Assessment
475
R.P.F. Gregory

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Optical Properties and Structure of Chlorophyll RC I
489
Dieter Dörnemann and Horst Senger

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Long-Wavelength Absorbing Forms of BacteriochlorophylIs. II. Structural Requirements for Formation in Triton X-100 Micelles and in Aqueous Methanol and Acetone
507
Hugo Scheer, Berndt Paulke and Jörg Gottstein

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Concluding Remarks
523
Martin Gouterman

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Index of Contributors
525

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Subject Index
527

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Backmatter
537

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Publishing information

Pages and Images/Illustrations in book

eBook published on:

May 18, 2020

eBook ISBN:

9783112321997

Hardcover published on:

December 31, 1985

Hardcover ISBN:

9783112310724

Edition:

Reprint 2020

Pages and Images/Illustrations in book

Front matter:

13

Main content:

536

https://doi.org/10.1515/9783112321997

eBook ISBN: 9783112321997

Hardcover ISBN: 9783112310724

Keywords for this book

Tetrapyrrole; Medizin; Chemie

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Optical Properties and Structure of Tetrapyrroles

Overview

Topics

Table of contents

Frontmatter

Preface

Contents

List Of Contributors

An Historical Survey of Porphyrins, their Related Spectra, and their Interpretation

Routes to Functional Porphyrin Assemblies (Molecular Complexes, Covalent Redox Pairs, and Reactive Domains in Vesicles)

Organism Dependent Pathways of Tetrapyrrole Biosynthesis

Transient Absorption Spectra and Excited State Kinetics of Transition Metal Porphyrins

Metal Complexes of Tetrapyrrole Ligands. XXXVII. Structure and Optical Spectra of Sandwich-Like Lanthanoid Porphyrins

Excited State Electron Transfer of Carbonyl[mesotetra(p-tolyl) porphyrinato osmium(II)]Complexes. One and Two Electron Photoredox Processes

Photophysical Properties of Hematoporphyrin and its Derivatives and their Use in Tumor Phototherapy

Optical Properties of Ferriheme-Quinidine Complexes

Resonance Raman Studies of Haemoglobin

Optical Properties of Heme Bound to the Central Exon Fragment of Globins and to Corresponding Fragments in Cytochromes

Heme Configuration in Cytochrome c

Correlation between Near-Infrared, ESR Spectra and Oxidation- Reduction Potentials in Low-Spin Heme Proteins

Circular Dichroism Contributions of Heme-Heme and Chlorophyll- Chlorophyll Interactions

Optical Properties of Conjugated Proteins which Transport Haem, Porphyrins and Bilirubin

Light Absorption of Bilatrienes-abc and 2,3-Dihydrobilatrienes-abc

Mechanism of Phototherapy of Neonatal Jaundice. Regiospecific Photoisomerization of Bilirubins

Effects of Environment on Photophysical Processes of Bilirubin

The Molecular Model of Phytochrome Deduced from Optical Probes

Phytochrome, the Visual Pigment of Plants: Chromophore Structure and Chemistry of Photoconversion

Recent Advances in the Photophysics and Photochemistry of Small, Large, and Native Oat Phytochromes

Contents IX Time-Resolved Fluorescence Depolarisation of Phycocyanins in Different States of Aggregation

The Influence of an External Electrical Charge on the Circular Dichroism of Chromopeptides from Phycocyanin

Bilins and Bilin-Protein Linkages in Phycobili proteins: Structural and Spectroscopic Studies

Structural Organization of Tetrapyrrole Pigments in Light- Harvesting Pigment-Protein Complexes

The Crystal and Molecular Structure of C-Phycocyanin from Mastigocladus laminosus and its Implications for Function and Evolution

Optical Spectra of Photosynthetic Reaction Centers. Theoretical and Experimental Aspects

Circular Dichroism of Chlorophylls in Protein Complexes from Chloroplasts of Higher Plants: A Critical Assessment

Optical Properties and Structure of Chlorophyll RC I

Long-Wavelength Absorbing Forms of BacteriochlorophylIs. II. Structural Requirements for Formation in Triton X-100 Micelles and in Aqueous Methanol and Acetone

Concluding Remarks

Index of Contributors

Subject Index

Backmatter

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