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An Alternative Crystal Structure of Yb26B12O57 – X-Ray Structure Determination on Flux-synthesized Single Crystals
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Olaf Reckeweg
,
Armin Schulz
Published/Copyright:
June 2, 2014
Transparent and colorless single crystals of Yb26B12O57 were obtained by reacting Yb2O3 and B powder at 1000 °C in the presence of a KCl flux for 24 h in silica-jacketed Nb ampoules and subsequent removal of the flux by washing with water. Yb26B12O57 crystallizes in the monoclinic space group C2/m (no. 12, Z = 1) with the lattice parameters a = 2454:1(3), b = 357:78(4), c = 1426:7(2) pm and β = 115:111(6)°, and its structure differs slightly from that of a known compound with the same stoichiometry. Raman spectra of single crystals of the title compound were recorded and compared to those of known borate compounds
Graphical Abstract
An Alternative Crystal Structure of Yb26B12O57 – X-Ray Structure Determination on Flux-synthesized Single Crystals
Received: 2013-12-19
Published Online: 2014-6-2
Published in Print: 2014-3-1
© 1946 – 2014: Verlag der Zeitschrift für Naturforschung
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