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Convenient Synthesis and Molecular Structure of PPN[RhCl2(CO)2] (PPN+ = Bis(triphenylphosphane)iminium)
-
Hans-Christian Böttcher
and
Peter Mayer
Published/Copyright:
June 2, 2014
The reaction of hydrated rhodium(III) chloride with formic acid in refluxing ethoxyethanol afforded in a convenient way the known rhodium carbonyl chlorido complex anion cis-[RhCl2(CO)2]-. This species was formed in good yield and was characterized as its PPN salt (PPN+ = bis(triphenylphosphane)iminium cation). The molecular structure of the title compound PPN[RhCl2(CO)2] was confirmed by X-ray diffraction and shown to be isomorphous to PPN[IrCl2(CO)2]
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![Convenient Synthesis and Molecular Structure of PPN[RhCl2(CO)2] (PPN+ = Bis(triphenylphosphane)iminium)](/document/doi/10.5560/znb.2014-3325/asset/graphic/s69b0376.png)
Convenient Synthesis and Molecular Structure of PPN[RhCl2(CO)2] (PPN+ = Bis(triphenylphosphane)iminium)
Received: 2013-12-12
Published Online: 2014-6-2
Published in Print: 2014-3-1
© 1946 – 2014: Verlag der Zeitschrift für Naturforschung
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