Skip to main content
Article
Licensed
Unlicensed Requires Authentication

Grain refinement of an AZ63B magnesium alloy by an Al–1C master alloy

  • EMAIL logo , and
Published/Copyright: February 2, 2022

Abstract

In order to develop a refiner of Mg– Al alloys, an Al – 1C (in wt.%) master alloy was synthesized using a casting method. The microstructure and grain-refining performance of the Al – 1C master alloy were investigated using X-ray diffraction (XRD), electron probe microanalysis (EPMA) and a grain-refining test. The microstructure of the Al – 1C master alloy is composed of α-Al solid solution, Al4C3 particles, and graphite phases. After grain refinement of AZ63B alloy by the Al – 1C master alloy, the mean grain size reached a limit when 2 wt.% Al – C master alloy was added at 800 °C and held for 20 min in the melt before casting. The minimum mean grain size is approximately 48 μm at the one-half radius of the ingot and is about 17% of that of the unrefined alloy. The Al – 1C master alloy results in better grain refinement than C2Cl6 and MgCO3 carbon-containing refiners.


Dr. Pan Yichuan Key Laboratory of Liquid Structure and Heredity of Materials Shandong University (southern campus) No. 73, Jingshi Road, Jinan, 250061 P.R. China Tel. and Fax: +86 531 839 5414

  1. This research work was supported by the National Natural Science Foundation of China (No. 50171037) and Key Project of Science and Technology Research of Ministry of Education of China (No. 01105). The authors would like to thank Prof. Li Shitong for his instruction on EPMA.

References

[1] A.K. Dahle, Y.C. Lee, M.D. Nave, P.L. Schaffer, D.H. StJohn: J.Light Metals 1 (2001) 61.10.1016/S1471-5317(00)00007-9Search in Google Scholar

[2] Farbenindustrie IG, British Patent 359425 (1931).Search in Google Scholar

[3] N. Tiner: Met. Technol. 12 (1945) 1.Search in Google Scholar

[4] J.A. Davis, L.W. Eastwood: Trans. AFS. 53 (1945) 352.Search in Google Scholar

[5] H.T. Hall: Magn. Rev. Abs. 3 (1945) 68.Search in Google Scholar

[6] C.E. Nelson: Trans. AFS. 56 (1948) 1.Search in Google Scholar

[7] R.T. Wood: The Foundryman 98 (1953) 256.Search in Google Scholar

[8] Farbenindustrie IG, Belgian Patent 444757 (1942).Search in Google Scholar

[9] Jessup AC, Petch JHT, British Patent 757 326, (1956).Search in Google Scholar

[10] Jessup AC, Petch JHT, US Patent 2 829 973 (1958).Search in Google Scholar

[11] E.F. Emley: Principles of magnesium technology, Oxford: Pergamon Press 209 (1996) 260.Search in Google Scholar

[12] P. Cao, M. Qian, D.H. StJohn: Scripta Mater. 51 (2004) 125.10.1016/j.scriptamat.2004.03.039Search in Google Scholar

[13] R. Hultgren, D.W. Mitchell: Trans. AIME 161 (1945) 323.Search in Google Scholar

[14] V.B. Kurfman: Trans. AIME 221 (1991) 540.Search in Google Scholar

[15] T. Tamura, N. Kohno, T. Motegi, E. Sato: J. JILM 48 (1998) 395.10.2464/jilm.48.395Search in Google Scholar

[16] E. Yano, Y. Tamura, T. Motegi, E. Sato: Mater. Trans. 44 (2003)107.10.2320/matertrans.44.107Search in Google Scholar

[17] Q.L. Jin, J.P. Eom, S.G. Lim, W.W. Park, B.S. You: Scripta mater.49 (2003) 1139.10.1016/j.scriptamat.2003.08.028Search in Google Scholar

[18] Q.L. Jin, J.P. Eom, S.G. Lim, W.W. Park, B.S. You: Scripta mater.52 (2004) 421.10.1016/j.scriptamat.2004.10.030Search in Google Scholar

[19] J.E. Gruzleski, C.A. Aliravci: U.S. Patent No 5 143 564 (1992).Search in Google Scholar

[20] G. Nussbaum, P. Bridot, T.J. Warner, J. Charbonnier, G. Regazzoni,in: B.L. Mordike, Hehmann, et al. (Eds.), Magnesium Alloys and Their Applications, Gamisch-Partenkirchen. DMG Informationsgesellshaft, Oberursel. (1992) 351.Search in Google Scholar

[21] Y.C. Lee, A.K. Dahle, D.H. StJohn: Metall. Mater. Trans. A 31 (2000) 2895.10.1007/BF02830349Search in Google Scholar

[22] A. Cibula: J. Inst Metals 76 (1949 –1950) 321.Search in Google Scholar

Received: 2005-01-05
Accepted: 2005-07-08
Published Online: 2022-02-02

© 2005 Carl Hanser Verlag, München

Downloaded on 17.4.2026 from https://www.degruyterbrill.com/document/doi/10.3139/ijmr-2005-0241/html
Scroll to top button