Abstract
In order to develop a refiner of Mg– Al alloys, an Al – 1C (in wt.%) master alloy was synthesized using a casting method. The microstructure and grain-refining performance of the Al – 1C master alloy were investigated using X-ray diffraction (XRD), electron probe microanalysis (EPMA) and a grain-refining test. The microstructure of the Al – 1C master alloy is composed of α-Al solid solution, Al4C3 particles, and graphite phases. After grain refinement of AZ63B alloy by the Al – 1C master alloy, the mean grain size reached a limit when 2 wt.% Al – C master alloy was added at 800 °C and held for 20 min in the melt before casting. The minimum mean grain size is approximately 48 μm at the one-half radius of the ingot and is about 17% of that of the unrefined alloy. The Al – 1C master alloy results in better grain refinement than C2Cl6 and MgCO3 carbon-containing refiners.
-
This research work was supported by the National Natural Science Foundation of China (No. 50171037) and Key Project of Science and Technology Research of Ministry of Education of China (No. 01105). The authors would like to thank Prof. Li Shitong for his instruction on EPMA.
References
[1] A.K. Dahle, Y.C. Lee, M.D. Nave, P.L. Schaffer, D.H. StJohn: J.Light Metals 1 (2001) 61.10.1016/S1471-5317(00)00007-9Search in Google Scholar
[2] Farbenindustrie IG, British Patent 359425 (1931).Search in Google Scholar
[3] N. Tiner: Met. Technol. 12 (1945) 1.Search in Google Scholar
[4] J.A. Davis, L.W. Eastwood: Trans. AFS. 53 (1945) 352.Search in Google Scholar
[5] H.T. Hall: Magn. Rev. Abs. 3 (1945) 68.Search in Google Scholar
[6] C.E. Nelson: Trans. AFS. 56 (1948) 1.Search in Google Scholar
[7] R.T. Wood: The Foundryman 98 (1953) 256.Search in Google Scholar
[8] Farbenindustrie IG, Belgian Patent 444757 (1942).Search in Google Scholar
[9] Jessup AC, Petch JHT, British Patent 757 326, (1956).Search in Google Scholar
[10] Jessup AC, Petch JHT, US Patent 2 829 973 (1958).Search in Google Scholar
[11] E.F. Emley: Principles of magnesium technology, Oxford: Pergamon Press 209 (1996) 260.Search in Google Scholar
[12] P. Cao, M. Qian, D.H. StJohn: Scripta Mater. 51 (2004) 125.10.1016/j.scriptamat.2004.03.039Search in Google Scholar
[13] R. Hultgren, D.W. Mitchell: Trans. AIME 161 (1945) 323.Search in Google Scholar
[14] V.B. Kurfman: Trans. AIME 221 (1991) 540.Search in Google Scholar
[15] T. Tamura, N. Kohno, T. Motegi, E. Sato: J. JILM 48 (1998) 395.10.2464/jilm.48.395Search in Google Scholar
[16] E. Yano, Y. Tamura, T. Motegi, E. Sato: Mater. Trans. 44 (2003)107.10.2320/matertrans.44.107Search in Google Scholar
[17] Q.L. Jin, J.P. Eom, S.G. Lim, W.W. Park, B.S. You: Scripta mater.49 (2003) 1139.10.1016/j.scriptamat.2003.08.028Search in Google Scholar
[18] Q.L. Jin, J.P. Eom, S.G. Lim, W.W. Park, B.S. You: Scripta mater.52 (2004) 421.10.1016/j.scriptamat.2004.10.030Search in Google Scholar
[19] J.E. Gruzleski, C.A. Aliravci: U.S. Patent No 5 143 564 (1992).Search in Google Scholar
[20] G. Nussbaum, P. Bridot, T.J. Warner, J. Charbonnier, G. Regazzoni,in: B.L. Mordike, Hehmann, et al. (Eds.), Magnesium Alloys and Their Applications, Gamisch-Partenkirchen. DMG Informationsgesellshaft, Oberursel. (1992) 351.Search in Google Scholar
[21] Y.C. Lee, A.K. Dahle, D.H. StJohn: Metall. Mater. Trans. A 31 (2000) 2895.10.1007/BF02830349Search in Google Scholar
[22] A. Cibula: J. Inst Metals 76 (1949 –1950) 321.Search in Google Scholar
© 2005 Carl Hanser Verlag, München
Articles in the same Issue
- Frontmatter
- Articles Basic
- Kinetics of crystallization of amorphous Mg80Cu10Y10
- Thermodynamic description of the Al–Fe–Mg–Mn–Si system and investigation of microstructure and microsegregation during directional solidification of an Al–Fe–Mg–Mn–Si alloy
- Effect of Ca addition on precipitation in the Pb-4 wt.% Sn alloy
- Binary phase diagrams of the rare earth metals with zinc: the Tb–Zn, Ho–Zn and Er–Zn systems
- SEM study on the M7C3 carbide nucleation during eutectic solidification of high-chromium white irons
- Manifestations of dynamic strain ageing in 2090 Al–Li alloy
- Articles Applied
- Study on susceptibility of Al–Si alloy castings to surface refinement with TIG arc
- Grain refinement of an AZ63B magnesium alloy by an Al–1C master alloy
- Retrogression, reaging, and mechanical behaviour of a 1441 Al–Li–Cu–Mg–Zr alloy
- The variation of microstructure by α–β forging and its effect on the strength and ductility in Ti–6Al–4V alloy
- Interfacial reaction and shear strength of Sn–0.7Cu solder/electrolytic Ni joints with reflow time
- Effect of niobium on the mechanical properties of powder-metallurgy processed high-speed steels
- High temperature behaviour of H13 steel
- Notifications/Mitteilungen
- Personal/Personelles
- Conferences/Konferenzen
Articles in the same Issue
- Frontmatter
- Articles Basic
- Kinetics of crystallization of amorphous Mg80Cu10Y10
- Thermodynamic description of the Al–Fe–Mg–Mn–Si system and investigation of microstructure and microsegregation during directional solidification of an Al–Fe–Mg–Mn–Si alloy
- Effect of Ca addition on precipitation in the Pb-4 wt.% Sn alloy
- Binary phase diagrams of the rare earth metals with zinc: the Tb–Zn, Ho–Zn and Er–Zn systems
- SEM study on the M7C3 carbide nucleation during eutectic solidification of high-chromium white irons
- Manifestations of dynamic strain ageing in 2090 Al–Li alloy
- Articles Applied
- Study on susceptibility of Al–Si alloy castings to surface refinement with TIG arc
- Grain refinement of an AZ63B magnesium alloy by an Al–1C master alloy
- Retrogression, reaging, and mechanical behaviour of a 1441 Al–Li–Cu–Mg–Zr alloy
- The variation of microstructure by α–β forging and its effect on the strength and ductility in Ti–6Al–4V alloy
- Interfacial reaction and shear strength of Sn–0.7Cu solder/electrolytic Ni joints with reflow time
- Effect of niobium on the mechanical properties of powder-metallurgy processed high-speed steels
- High temperature behaviour of H13 steel
- Notifications/Mitteilungen
- Personal/Personelles
- Conferences/Konferenzen