Home Technology Structures similar to a quasicrystal in technical aluminum alloys
Article
Licensed
Unlicensed Requires Authentication

Structures similar to a quasicrystal in technical aluminum alloys

  • Michael Ruhnow EMAIL logo , Ingrid Haase and Horst Wendrock
Published/Copyright: December 27, 2021

Abstract

Already during solidification of the melt, in the aluminum alloy AA 6013 occur precipitates, which are a part of a very complex microstructure and have a significant influence on the recrystallization and fracture behaviour. The chemical composition as well as the high value of microhardness suggest that it is a quasicrystal or crystalline approximant. Convergent beam electron diffraction (CBED) and selected area diffraction (SAD) investigations in combination with the interpretation of electron backscatter diffraction (EBSD) patterns led to the conclusion that the precipitates are crystalline approximants. Their chemical composition can bedescribed with the formula Al19Fe4MnSi2 and their crystallographic point group is 2 m 3 ¯ .

Abstract

In der Aluminiumlegierung AA 6013 treten Primärteilchen auf, welche sich bereits bei der Erstarrung der Schmelze bilden. Sowohl ihre chemische Zusammensetzung als auch ihre große Härte legen die Vermutung nahe, dass es sich von der Struktur her dabei um Quasikristalle oder kristalline Approximanten handeln könnte. CBED- und SAD-Untersuchungen in Kombination mit der Interpretation von EBSD-Aufnahmen führten zu der Schlussfolgerung, dass es sich bei diesen Ausscheidungen um einen kristallinenApproximanten handelt. Dessen kristallographische Punktgruppe ist 2 m 3 ¯ . und seine chemische Zusammensetzungkann mit der Formel Al19Fe4MnSi2 beschrieben werden.


Dr. Michael Ruhnow University of Technology Institute of Materials Science 01062 Dresden, Germany Tel.: +49 351 463 33887 Fax: +49 351 463 33207

References

1 Haase, I.; Nocke, K.; Worch, H.; Zouhar, G.; Tempus, G.: Prakt. Metallographie 38, 3 (2001) 119.Search in Google Scholar

2 Haase, I.; Nocke, K.; Ruhnow, M.; Worch, H.: Prakt. Metallographie, in press.Search in Google Scholar

3 Shechtman, D.; Blech, I.; Gratias, D.; Cahn, J.W.: Phys. Rev. Lett. 53 (1984) 1951.10.1103/PhysRevLett.53.1951Search in Google Scholar

4 Steurer, W.: Z. Kristallogr. 190 (1990) 173.Search in Google Scholar

5 Boudard, M.; de Boissieu, M.; Janot, C.; Dubois, J.M.; Dong, C. : Phil. Mag. Lett. 64 (1991) 197.10.1080/09500839108214543Search in Google Scholar

6 de Boissieu, M.; Boudard, M.; Bellisseu, R.; Quilichini, M.; Henniou, B.; Currat, R.; Goldman, A.I.; Janot, C.: Phys. Cond. Matter 5 (1993) 4945.10.1088/0953-8984/5/28/010Search in Google Scholar

7 Elser, V.: Phil. Mag. B 73 (1996) 641.10.1080/13642819608239141Search in Google Scholar

8 Ritsch, S.; Beeli, C.; Nissen, H.-U.; Gödecke, T.; Scheffer, M.; Lück, R.: Phil. Mag. Lett. 78 (1998) 67.10.1080/095008398178048Search in Google Scholar

9 Lück, R.: Mater. Sci. Forum 150–151 (1994) 145.10.4028/www.scientific.net/MSF.150-151.145Search in Google Scholar

10 Lück, R.; Scheffer, M.: Ferroelectrics 250 (2001) 351.10.1080/00150190108225099Search in Google Scholar

11 Gibbons, P.C.; Kelton, K.F.; Ranganathan, S.; Daulton, T.L.: Phil. Mag. A 80 (2000) 843.10.1080/01418610008212085Search in Google Scholar

12 Daulton, T.L.; Kelton, K.F.: Phil. Mag. B 68 (1993) 697.10.1080/13642819308220153Search in Google Scholar

13 Gibbons, P.C. : Private communication (2001).Search in Google Scholar

14 International tables for crystallography, Vol. A, Kluwer Academic Publishers Dordrecht, Boston, London (1996) 787.Search in Google Scholar

15 Villars, P.; Calvert, L.D.: Pearson’s handbook of crystallographic data for intermetallic phases, The Materials Information Society, Materials Park, OH (1991).Search in Google Scholar

16 Kelton, K.F., in: J.H.Westbrook, R.L. Fleischer (eds.): Intermetallic compounds, principles and practice, John Wiley, Chichester, New York, Brisbane, Toronto, Singapore (1995) 453.Search in Google Scholar

17 Donnadieu, P.; Lapasset, G.; Thanaboonsombut, B.; Sanders Jr, T.H., in: S.C. Bergsma, M.E. Kassner (eds.), Proc. 4th Int. Conf. on Aluminum Alloys, Atlanta, GA (1994) 668.Search in Google Scholar

Received: 2001-07-20
Published Online: 2021-12-27

© 2002 Carl Hanser Verlag, München

Downloaded on 1.1.2026 from https://www.degruyterbrill.com/document/doi/10.3139/ijmr-2002-0024/pdf
Scroll to top button