Phase Equilibria and Thermodynamics in the Y2O3–Al2O3–SiO2 System

Olga Fabrichnaya; Hans Jürgen Seifert; Reinhold Weiland; Thomas Ludwig; Fritz Aldinger; Alexandra Navrotsky

doi:10.3139/ijmr-2001-0197

Article

Phase Equilibria and Thermodynamics in the Y₂O₃–Al₂O₃–SiO₂ System

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Published/Copyright: January 12, 2022

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From the journal International Journal of Materials Research Volume 92 Issue 9

Abstract

The enthalpy of formation of YAM (Y₄Al₂O₉) and Y₂Si₂O₇ (γ) has been derived using high-temperature drop solution calorimetry at 1073 K in molten alkali borate. The enthalpy of formation from oxides at 298 K is -6.24 ± 6.21 and -67.08 ± 5.98 kJ/mol for YAM and disilicate, respectively. The thermodynamic functions in the Y₂O₃-Al₂O₃ and Y₂O₃-SiO₂ systems are assessed from phase equilibrium data and calorimetric measurements for YAG (Y₃Al₅O₁₂), YAP (YAlO₃), YAM (Y₄Al₂O₉), Y₂SiO₅ and Y₂Si₂O₇ phases. The calculated phase diagrams of the Al₂O₃-Y₂O₃ and Y₂O₃-SiO₂ systems are in reasonable agreement with the experimental data. Suggestions for further experimental measurements on solid phases are given. Using limited phase equilibrium data for the ternary system Y₂O₃-Al₂O₃-SiO₂, the thermodynamic functions are assessed. The liquidus surface, an isothermal section at 1673 K and isopleths in the systems Y₃Al₅O₁₂-SiO₂, YAlO₃-SiO₂, Y₄Al₂O₉-SiO₂, Y₂SiO₅-Al₆Si₂O₁₃ and Y₂Si₂O₇-Al₆Si₂O₁₃ are presented.

Keywords: Phase equilibria; Calorimetry; Assessment of thermodynamic parameters

Dr. Olga Fabrichnaya Max-Planck-Institut für Metallforschung Heisenbergstr. 5, D-70569 Stuttgart, Germany Fax: +49 711 686 11 31

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Received: 2001-04-09

Published Online: 2022-01-12

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https://doi.org/10.3139/ijmr-2001-0197

Keywords for this article

Phase equilibria; Calorimetry; Assessment of thermodynamic parameters