Thermodynamic Assessment of the V–N System
-
Yong Du
Abstract
A consistent thermodynamic data set for the V–N system is obtained by a computer-aided least squares method applied to all of the experimental phase diagram and thermodynamic data available from the literature. The sublattice model V1(N, Va)a is used to model the phases: fcc (a = 1), bcc (a = 3), and hcp (a = 0.5). The liquid phase is described by the Redlich-Kister formula, and the gas phase is treated as an ideal gas. Special attention is paid to the modeling of the fcc phase with its exceptional bulk of experimental data. This phase is first analyzed by an ideal solution, then by a regular, and finally by a subregular interaction in the nitrogen sublattice. The other solution phases are analyzed with similar modeling procedures. This step-by-step analysis procedure permits insight into reliable estimations for the parameters at each of the higher level models. Comparisons between the calculated and measured phase diagram and thermodynamic quantities show that most of the experimental information is satisfactorily accounted for by the thermodynamic calculation. Inconsistent experimental information is identified and ruled out. The thermo-dynamic property of the fcc phase in the V–N system is compared with those in the Cr–N and Ti–N systems and related to the Neumann-Kopp’s rule.
Funding statement: One of the authors (Yong Du) gratefully acknowledges the grant released by Alexander von Humboldt Foundation. The authors are grateful to Professor W. Lengauer for providing new experimental data [97Tei]. Thanks are also due to Drs. K. J. Zeng, A. Pisch, and F. Goesmann for helpful discussions. This project was partially supported by the BMBF under grant no. 03K72058
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Articles in the same Issue
- Frontmatter
- Aufsätze
- Characterisation of γ′ Precipitates in Single Crystal Nickel-base Superalloy SC16 by Small Angle Neutron Scattering
- The Excess Enthalpies of Liquid Ge–Pb–Te Alloys
- Experimental Investigation and Thermodynamic Calculation of the Ternary System Mn–Y–Zr
- The Fe-Zn-Ti System at 450 °C
- Thermodynamic Assessment of the V–N System
- Schmelzfläche und Phasengleichgewichte mit Beteiligung der Schmelze im System Al-AlCo-AlNi
- Shear Bands In Cold Rolled Al–Mg Alloy Polycrystals
- Rolling and Recrystallization Textures in High Purity Al–Mg Alloys
- Effect of Modified Postweld Heat Treatment on Disbonding of 2.25 Cr-1 Mo Steel Overlay Welded with Austenitic Stainless Steel
- Effect of Vanadium Addition on Disbonding of 2.25Cr–1Mo Steel Overlay Welded with Austenitic Stainless Steel
- Mitteilungen der Deutschen Gesellschaft für Materialkunde e.V.
- Personen
- Mitteilung aus dem Materialprüfungsamt Nordrhein-Westfalen
- Buchbesprechung
- Fortbildungsseminar
Articles in the same Issue
- Frontmatter
- Aufsätze
- Characterisation of γ′ Precipitates in Single Crystal Nickel-base Superalloy SC16 by Small Angle Neutron Scattering
- The Excess Enthalpies of Liquid Ge–Pb–Te Alloys
- Experimental Investigation and Thermodynamic Calculation of the Ternary System Mn–Y–Zr
- The Fe-Zn-Ti System at 450 °C
- Thermodynamic Assessment of the V–N System
- Schmelzfläche und Phasengleichgewichte mit Beteiligung der Schmelze im System Al-AlCo-AlNi
- Shear Bands In Cold Rolled Al–Mg Alloy Polycrystals
- Rolling and Recrystallization Textures in High Purity Al–Mg Alloys
- Effect of Modified Postweld Heat Treatment on Disbonding of 2.25 Cr-1 Mo Steel Overlay Welded with Austenitic Stainless Steel
- Effect of Vanadium Addition on Disbonding of 2.25Cr–1Mo Steel Overlay Welded with Austenitic Stainless Steel
- Mitteilungen der Deutschen Gesellschaft für Materialkunde e.V.
- Personen
- Mitteilung aus dem Materialprüfungsamt Nordrhein-Westfalen
- Buchbesprechung
- Fortbildungsseminar
