Epoxy Resin Catalyzed by Graphite-Based Nanofillers
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C. Esposito Corcione
, M. R. Acocella , A. Giuri and A. Maffezzoli
Abstract
Graphene stacks/epoxy nanocomposites were produced and characterized in order to analyse the effect of different graphene precursors on cure reaction of a model epoxy matrix. A kinetic analysis of the cure mechanism of the epoxy resin associated to the catalytical activity of the graphite based fillers was performed by isothermal DSC measurements. The DSC results showed that the addition of all graphite based fillers greatly increased the enthalpy of epoxy reaction and the reaction rate, confirming the presence of a catalytic activity of graphitic layers on the crosslinking reaction between the epoxy resin components (epoxide oligomer and di-amine). A kinetic modelling analysis, arising from an autocatalyzed reaction mechanism, was finally applied to isothermal DSC data, in order to predict the cure mechanism of the epoxy resin in presence of the graphite based nanofiller.
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© 2016, Carl Hanser Verlag, Munich
Articles in the same Issue
- Contents
- Contents
- Editorial
- The 70th Birthday of Prof. Giuseppe Titomanlio
- New Editor-in-Chief of International Polymer Processing
- Special Issue Contributions
- Electrospinning of Sheath-Core Structured Chitosan/Polylactide Nanofibers for the Removal of Metal Ions
- Effect of Elongational Flow and Polarity of Organomodified Clay on Morphology and Mechanical Properties of a PLA Based Nanobiocomposite
- Epoxy Resin Catalyzed by Graphite-Based Nanofillers
- Synergistic Effects in Thermoplastic Polyurethanes Incorporating Hybrid Carbon Nanofillers
- Laser Welding Process in PP Molding Parts: Evaluation of Seam Performance
- Polymeric Supports for Controlled Release of Ethylene for Food Industry
- Solubility and Durability of Cardanol Derived Plasticizers for Soft PVC
- Polymer Bioprocessing to Fabricate 3D Scaffolds for Tissue Engineering
- Polyoxymethylene/Polyhedral Oligomeric Silsesquioxane Composites: Processing, Crystallization, Morphology and Thermo-Mechanical Behavior
- Development of an Immiscible Polymer/Polymer/Nanoparticle System to Assess the Location of Nanoparticles by Quantitative Optical Microscopy
- Crystallinity-Based Product Design: Utilizing the Polymorphism of Isotactic PP Homo- and Copolymers
- Experimental Test of Tammann's Nuclei Development Approach in Crystallization of Macromolecules
- Fabrication and Characterization of Electrospun Thermoplastic Polyurethane/Fibroin Small-Diameter Vascular Grafts for Vascular Tissue Engineering
- The Three-Phase Structure of Random Butene-1/Ethylene Copolymers
- Thirty Years of Modeling of Injection Molding. A Brief Review of the Contribution of UNISA Code to the Field
- PPS News
- PPS News
- Seikei Kakou Abstracts
- Seikei-Kakou Abstracts
Articles in the same Issue
- Contents
- Contents
- Editorial
- The 70th Birthday of Prof. Giuseppe Titomanlio
- New Editor-in-Chief of International Polymer Processing
- Special Issue Contributions
- Electrospinning of Sheath-Core Structured Chitosan/Polylactide Nanofibers for the Removal of Metal Ions
- Effect of Elongational Flow and Polarity of Organomodified Clay on Morphology and Mechanical Properties of a PLA Based Nanobiocomposite
- Epoxy Resin Catalyzed by Graphite-Based Nanofillers
- Synergistic Effects in Thermoplastic Polyurethanes Incorporating Hybrid Carbon Nanofillers
- Laser Welding Process in PP Molding Parts: Evaluation of Seam Performance
- Polymeric Supports for Controlled Release of Ethylene for Food Industry
- Solubility and Durability of Cardanol Derived Plasticizers for Soft PVC
- Polymer Bioprocessing to Fabricate 3D Scaffolds for Tissue Engineering
- Polyoxymethylene/Polyhedral Oligomeric Silsesquioxane Composites: Processing, Crystallization, Morphology and Thermo-Mechanical Behavior
- Development of an Immiscible Polymer/Polymer/Nanoparticle System to Assess the Location of Nanoparticles by Quantitative Optical Microscopy
- Crystallinity-Based Product Design: Utilizing the Polymorphism of Isotactic PP Homo- and Copolymers
- Experimental Test of Tammann's Nuclei Development Approach in Crystallization of Macromolecules
- Fabrication and Characterization of Electrospun Thermoplastic Polyurethane/Fibroin Small-Diameter Vascular Grafts for Vascular Tissue Engineering
- The Three-Phase Structure of Random Butene-1/Ethylene Copolymers
- Thirty Years of Modeling of Injection Molding. A Brief Review of the Contribution of UNISA Code to the Field
- PPS News
- PPS News
- Seikei Kakou Abstracts
- Seikei-Kakou Abstracts