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High-Strength PET Fibers Produced by Conjugated Melt Spinning and Laser Drawing

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Published/Copyright: April 6, 2013
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Abstract

The mechanical properties of conjugated-spun and laser drawn poly(ethylene terephthalate) (PET) fibers were investigated. The as-spun fibers used for the laser drawing were made by conjugated melt spinning with the copolymer of p-hydroxybenzoicacid and 2-hydroxy-6-naphthoicacid or polystyrene. The PET fibers prepared by conjugated spinning could be laser drawn to higher draw ratios under lower drawing stresses. The drawn fiber could be re-drawn up to a higher total draw ratio. Thus, a PET fiber having a tensile strength of 1.14 N/tex could be produced.


Mail address: Yutaka Ohkoshi, Faculty of Textile Science and Technology, Shinshu University, 3-15-1 Tokida, Ueda City, Nagano 386-8567, Japan. E-mail:

References

Ito, M., et al., “Preparation of High-modulus and High-strength Fibers from High Molecualar Weight Poly(ethylene terephthalate)J. Appl. Polym. Sci., 40, 12571263(1990), http://dx.doi.org/10.1002/app.1990.070400714Search in Google Scholar

Huang, B., et al., “Effects of Draw Conditions on Deformability and Draw Efficiency of High Molecular Weight Poly(ethylene terephthalate) Fibres”. Polymer, 35, 13291331(1994), http://dx.doi.org/10.1016/0032-3861(94)90033-7Search in Google Scholar

Kikutani, T., et al., “High-speed Melt Spinning of Bicomponent Fibers: Mechanism of Fiber Structure Development in Poly(ethylene terephthalate)/Polypropylene System”. J. Appl. Polym. Sci., 62, 19131924(1996), http://dx.doi.org/10.1002/(SICI)1097-4628(19961212)62:11<1913::AID-APP16>3.0.CO;2-ZSearch in Google Scholar

Jeon, H. J., et al., “Effect of Metallic Wire Inserted in Nozzle in High-speed Melt Spinning of Poly(ethylene terephthalate)”. J. Appl. Polym. Sci., 70, 665674(1998)http://dx.doi.org/10.1002/(SICI)1097-4628(19981024)70:4<665::AID-APP5>3.0.CO;2-OSearch in Google Scholar

Takarada, W., et al., “Studies on High-speed Melt Spinning of Noncircular Cross-section Fibers. I. Structural Analysis of As-spun Fibers”. J. Appl. Polym. Sci., 80, 15751581(2001), http://dx.doi.org/10.1002/app.1250Search in Google Scholar

Masuda, M., et al., “Effect of CO2 Laser Irradiation in Spinline on Mechanical Properties of Poly(ethylene terephthalate) Fibers”, Sen'i Gakkaishi, 60, 338345(2004), http://dx.doi.org/10.2115/fiber.60.338Search in Google Scholar

Radhakrishnan, J., et al., “High-speed Melt Spinning of Sheath-core Bicomponent Polyester Fibers: High and Low Molecular Weight Poly(ethylene terephthalate) Systems”, Textile Res. J., 684694(1997)10.1177/004051759706700908Search in Google Scholar

Nakata, K., et al., “Mechanical Properties of Poly(ethylene terephthalate) Fiber produced by Conjugate Melt Spinning with Polystyrene and CO2 Laser-heated Drawing”, Sen'i Gakkaishi, 60, 352355(2004), http://dx.doi.org/10.2115/fiber.60.352Search in Google Scholar

Kunugi, T., et al., “Preparation of High-modulus and High-strength Poly(ethylene terephthalate) Fiber by Zone Annealing”. J. Appl. Polym. Sci., 26, 213221(1981), http://dx.doi.org/10.1002/app.1981.070260120Search in Google Scholar

Ikaga, T., et al., “The Structure of Poly(ethylene terephthalate) Fiber Drawn with CO2 Laser Heating”, Sen'i Gakkaishi, 58, 815(2002), http://dx.doi.org/10.2115/fiber.58.8Search in Google Scholar

Ikaga, T., et al., “Mechanical Properties of Poly(ethylene terephthalate) Fiber Drawn with CO2 Laser Heating”, Sen'i Gakkaishi, 58, 1621(2002), http://dx.doi.org/10.2115/fiber.58.16Search in Google Scholar

Okumura, W., et al., “Correlation between the Tensile Properties and Network Draw Ratio of CO2-Laser-Heated Drawn Poly(ethylene terephthalate) Fibers”. J. Polym. Sci. Polym. Phys., 41, 23222331, (2003), http://dx.doi.org/10.1002/polb.10467Search in Google Scholar

Suzuki, A., Mochizuki, N., “Mechanical Properties and Superstructure of Poly(ethylene terephthalate) Fibers Zone-drawn and Zone-annealed by CO2 Laser Heating”. J. Appl. Polym. Sci., 82, 27752783(2001), http://dx.doi.org/10.1002/app.2131Search in Google Scholar

Nakata, K., et al., “Poly(ethylene terephthalate) Nanofibers Made by Sea-Island-Type Conjugated Melt Spinning and Laser-Heated Flow Drawing”. Macromol. Rapid Commun., 28, 792795(2007)http://dx.doi.org/10.1002/marc.200600624Search in Google Scholar

Masuda, M., et al., “Effect of the Control of Polymer Flow in the Vicinity of Spinning Nozzle on Mechanical Properties of Poly(ethylene terephthalate) Fibers”. Int. Polym. Process., 25, 159169(2010)http://dx.doi.org/10.3139/217.2330Search in Google Scholar

Nakata, K., et al., “Tensile Properties of Poly(ethylene terephthalate) Fiber Produced by Sheath-core Conjugate Melt Spinning and Laser-drawing”, 8th SPSJ International Polymer Conference, 263264(2005)Search in Google Scholar

Hotchi, H., et al., “High-strength Poly(ethylene terephthalate) Fiber Obtained by Conjugated Melt-spinning and Laser-drawing”. Fiber Preprints, Japan, 62, 100100(2007)Search in Google Scholar

Received: 2011-10-04
Accepted: 2012-02-09
Published Online: 2013-04-06
Published in Print: 2012-07-01

© 2012, Carl Hanser Verlag, Munich

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