Bulk Polymerization of ε-Caprolactone in an Internal Mixer and in a Twin Screw Extruder
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B. J. Kim
Abstract
Bulk polymerization of ε-caprolactone has been carried out both in a laboratory internal mixer (Brabender Plasticorder) and in a modular intermeshing co-rotating twin screw extruder. Various initiators, such as titanium n-butoxide, aluminum triisopropoxide, and sodium hydride were used to polymerize ε-caprolactone in an internal mixer. The continuous polymerization of ε-caprolactone was performed using aluminum triisopropoxide under a range of processing conditions, including barrel temperature profiles, throughput, and screw speed. This polymerization was investigated for various ratios of monomer to initiator. GPC analysis demonstrated that significant quantities of oligomers were produced together with high molecular weight polymer at different reaction temperatures. H NMR detected the hydroxylation of growing chain end group for bulk polymerization at high barrel temperature. The molecular weight was reduced along the screw axis once the maximum molecular weight was obtained after the first kneading disk block. Increasing screw speed caused further reductions in molecular weight.
© 2002, Carl Hanser Verlag, Munich
Articles in the same Issue
- Editorial
- Twelfth of a Series: Father of Synthetic Fiber Industry Wallace Hume Carothers
- Special Paper
- The Matching of Experimental Polymer Processing Flows to Viscoelastic Numerical Simulation
- Single and Twin Screw Extrusion
- Polymer Pellet Flow out of the Hopper into the First Section of a Single Screw
- Estimation of Residence Time Distribution in two Elements of a Ko-Kneader
- Flow Characteristics of Screws and Special Mixing Enhancers in a Co-rotating Twin Screw Extruder
- Reactive Extrusion
- Bulk Polymerization of ε-Caprolactone in an Internal Mixer and in a Twin Screw Extruder
- Die Extrusion
- Flow Instabilities of Linear PE in Capillary Dies
- In-line Ultrasonic Monitoring of Filler Dispersion during Extrusion
- Fibers and Film
- Birefringence and Mechanical Property Development in Melt Spinning Cyclopolyolefin Filaments
- Injection Molding
- An Empirical Study of the Surface Blush in Gas-Assisted Injection Molded Parts
- Use of the Fast-cool pVT Data for Shrinkage Analysis in Injection Molding
- Composite Processing
- Impregnation Behaviors in Composite Processing
Articles in the same Issue
- Editorial
- Twelfth of a Series: Father of Synthetic Fiber Industry Wallace Hume Carothers
- Special Paper
- The Matching of Experimental Polymer Processing Flows to Viscoelastic Numerical Simulation
- Single and Twin Screw Extrusion
- Polymer Pellet Flow out of the Hopper into the First Section of a Single Screw
- Estimation of Residence Time Distribution in two Elements of a Ko-Kneader
- Flow Characteristics of Screws and Special Mixing Enhancers in a Co-rotating Twin Screw Extruder
- Reactive Extrusion
- Bulk Polymerization of ε-Caprolactone in an Internal Mixer and in a Twin Screw Extruder
- Die Extrusion
- Flow Instabilities of Linear PE in Capillary Dies
- In-line Ultrasonic Monitoring of Filler Dispersion during Extrusion
- Fibers and Film
- Birefringence and Mechanical Property Development in Melt Spinning Cyclopolyolefin Filaments
- Injection Molding
- An Empirical Study of the Surface Blush in Gas-Assisted Injection Molded Parts
- Use of the Fast-cool pVT Data for Shrinkage Analysis in Injection Molding
- Composite Processing
- Impregnation Behaviors in Composite Processing
