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Thermodynamic description of the ternary Pd–Sn–Zn system

  • Zuoan Li , Sabine Knott and Adolf Mikula
Published/Copyright: March 1, 2013
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International Journal of Materials Research
From the journal International Journal of Materials Research Volume 99 Issue 2

Abstract

The thermodynamic properties of the liquid Pd–Sn–Zn ternary system were investigated, because the Sn–Zn alloy is a promising lead-free solder and Pd can be used as a substrate material. Using an appropriate galvanic cell, the partial free energies of Zn in liquid Pd–Sn–Zn alloys were determined as a function of concentration and temperature. Thermodynamic properties were obtained for 18 alloys. Their composition was situated on two cross-sections with the constant molar ratios of Pd: Sn = 1:3 and 1:9. The integral Gibbs free energy and the integral enthalpy for the ternary system at 1000 K were calculated by Gibbs–Duhem integration. For the liquid binary Pd–Sn system, some inconsistencies were found in previous CALPHAD results. Considering the latest experimental information, the interaction parameters of the liquid phase were reevaluated. The liquidus temperatures were also determined from EMF measurements.

Keywords:: Palladium–tin–zinc; Lead-free solders; EMF measurements; Thermodynamic properties
2 Correspondence address: Mag. Dr. Sabine Knott, Institut für Anorganische Chemie–Materialchemie, Universität Wien, Währinger Straße 42, A-1090 Wien, Austria, Tel.: +43 1 4277 52913, Fax: +43 1 4277 9529. E-mail:

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Received: 2007-05-02
Accepted: 2007-11-22
Published Online: 2013-03-01
Published in Print: 2008-02-01

© 2008, Carl Hanser Verlag, Munich

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https://doi.org/10.3139/146.101627
Keywords for this article
Palladium–tin–zinc; Lead-free solders; EMF measurements; Thermodynamic properties

Articles in the same Issue

  1. Contents
  2. Contents
  3. Editorial
  4. IJMR wishes all its readers and contributors a belated Happy New Year
  5. Basic
  6. Experimental study of the phase relations in the Fe–Zn–Cr system at 600°C
  7. Thermodynamic description of the ternary Pd–Sn–Zn system
  8. The morphology of nitrided iron–chromium alloys; influence of chromium content and nitrogen supersaturation
  9. The surface tension and density of Ag–Bi–Sn alloys
  10. Density and thermal expansion of liquid binary Al–Ag and Al–Cu alloys
  11. Hardening precipitation and mechanical properties in new Mg–Mn–Y–Gd alloys
  12. On recrystallization texture formation in polycrystalline fcc alloys with low stacking fault energies
  13. A numerical study of grain size effects on the strength and elongation of Al polycrystals using strain gradient plasticity theory
  14. Applied
  15. Thermodynamic simulation of the Bayer process
  16. The anisotropy of deformation for friction stir processed Mg alloy due to the existence of onion rings
  17. A study of the Si-phase growth mechanismin thixocast (A356) alloy during hot deformation
  18. Study of hydrogen absorption of aluminum melt
  19. Modelling of work-hardening behaviour for laser welded magnesium alloy
  20. Tribological behavior of short carbon fiber or hybrid with SiCp reinforced Al alloy composites
  21. Elevated temperature compressive behavior of Nb-22Ti-16Si-7Cr-3Al-3Ta-2Hf alloy with minor Ho addition
  22. Notifications
  23. News
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