Preparation and Properties of Novel Asymmetric Gemini Alkyl Polyglycosides
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Feiyu Chen
Abstract
In order to obtain higher surface activity and lower foaming ability, novel asymmetric Gemini alkyl polyglycosides were synthetized based on tertiary dodecyl dimethyl amine and epoxy chloropropane by adopting chlorination, substitution, and quaternization reactions. The structure of synthesis product was characterized by using Fourier transform infrared spectroscopy, 1H nuclear magnetic resonance spectroscopy and elemental analysis. It was confirmed that the synthesis product was an asymmetric glycoside quaternary ammonium salt with double ionic head groups. The critical micelle concentration of the resulting product was 0.025 g/mL at 20°C and its surface tension was low to 22.8 mN/m. The emulsifying ability and wettability of the product were the same as or even better than those of the commonly used surfactants. Moreover, the product revealed low foaming ability.
Kurzfassung
Mit dem Ziel, eine höhere Oberflächenaktivität und eine geringeres Schaumvermögen zu erreichen, wurden neue asymmetrische Gemini-Alkylpolyglycoside auf Basis von tert.-Dodecyldimethylamin und Epoxychlorpropan unter Anwendung von Chlorierung, Substitution und Quaternierungsreaktion erzeugt. Die Struktur der Syntheseprodukte wurde mittels Fourier-Transformations-Infrarotspektroskopie (FT-IR), 1H-Kernspinresonanz-Spektroskopie (1H-NMR) und Elementaranalyse bestimmt. Es konnte bestätigt werden, dass es sich bei dem Syntheseprodukt um ein asymmetrisches, quaternäres Ammoniumglycosid mit zwei ionischen Kopfgruppen handelt. Die kritische Mizellenbildungskonzentration (CMC) des Syntheseprodukts betrug bei 20°C 0,025 g/mL, die Oberflächenspannung an der CMC lag bei 22,8 mN/m. Die Emulgierfähigkeit und das Benetzungsverhalten des Produkts waren gleich oder sogar besser als die der üblich eingesetzten Tenside. Außerdem zeigte das Produkt ein geringes Schaumvermögen.
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© 2017, Carl Hanser Publisher, Munich
Articles in the same Issue
- Contents/Inhalt
- Contents
- Editorial
- Review of the Year 2016
- Review
- Reaction Principle of Alcohol Ether Sulfonates by Sulfonated Alkylation Method – A Review
- Biosurfactants/Novel Surfactants
- Distribution Coefficients of Lipopeptide Biosurfactant in Different Solvents and its Separation from a Surfactant/Polymer Mixture in Aqueous Solutions
- Synthesis and Surface Properties of Anionic Vinylguaiacol Based Surfactants
- Novel Mesoporous ZSM-5 Zeolite with Disparate Morphologies Synthesized by a Double Long-alkyl-chain Organosilane Template
- Environmental Chemistry
- Preparation and Characterization of Glauber's Salt Microcapsules for Thermal Energy Storage
- Physical Chemistry
- Preparation and Characterization of a Humate Surfactant with Hydroxymethylation and Esterification Modification of Lignite
- Properties of Cationic Choline-Derived Surfactant with Photolabile Cinnamate Counterion
- Micellar Catalysis
- Solvent-Free Acetalization of Glycerol with n-Octanal using Combined Brønsted Acid-Surfactant Catalyst
- Synthesis
- Purification, Analysis and Surfactant Synthesis of Waste Cooking Oil
- Application
- Preparation and Properties of Novel Asymmetric Gemini Alkyl Polyglycosides
- Synthesis and Properties of Esterquats as Antibacterial Agent and Fabric Softener
Articles in the same Issue
- Contents/Inhalt
- Contents
- Editorial
- Review of the Year 2016
- Review
- Reaction Principle of Alcohol Ether Sulfonates by Sulfonated Alkylation Method – A Review
- Biosurfactants/Novel Surfactants
- Distribution Coefficients of Lipopeptide Biosurfactant in Different Solvents and its Separation from a Surfactant/Polymer Mixture in Aqueous Solutions
- Synthesis and Surface Properties of Anionic Vinylguaiacol Based Surfactants
- Novel Mesoporous ZSM-5 Zeolite with Disparate Morphologies Synthesized by a Double Long-alkyl-chain Organosilane Template
- Environmental Chemistry
- Preparation and Characterization of Glauber's Salt Microcapsules for Thermal Energy Storage
- Physical Chemistry
- Preparation and Characterization of a Humate Surfactant with Hydroxymethylation and Esterification Modification of Lignite
- Properties of Cationic Choline-Derived Surfactant with Photolabile Cinnamate Counterion
- Micellar Catalysis
- Solvent-Free Acetalization of Glycerol with n-Octanal using Combined Brønsted Acid-Surfactant Catalyst
- Synthesis
- Purification, Analysis and Surfactant Synthesis of Waste Cooking Oil
- Application
- Preparation and Properties of Novel Asymmetric Gemini Alkyl Polyglycosides
- Synthesis and Properties of Esterquats as Antibacterial Agent and Fabric Softener
