Startseite Synthesis and Surface Properties of Anionic Vinylguaiacol Based Surfactants
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Synthesis and Surface Properties of Anionic Vinylguaiacol Based Surfactants

  • Prabhakara Rao Darapureddi , Bijari Anil Kumar , Shruti S. Deshpande , Koude Dhevendar , Sunil Misra und Rati Ranjan Nayak
Veröffentlicht/Copyright: 6. Januar 2017
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Abstract

By changing amino acid head group four biobased anionic surfactants were synthesized using 4-vinylguaiacol and methylbromo undecanoate. The synthesized surfactants were characterized by NMR and mass spectrometry analysis. The surface active properties such as surface tension, wetting power, foaming characteristic, emulsion stability, calcium tolerance were studied and compared with those of sodium lauryl sulfate (SLS). Excellent emulsion stabilities and calcium tolerances were observed for the synthesized surfactants. These surfactants show a lower critical micelle concentration as compared to the conventional surfactants. The bulk micellization properties were studied using dynamic light scattering and fluorescence anisotropy technique. The antimicrobial and cytotoxicity studies were also carried out.

Kurzfassung

Durch Veränderung der Aminosäurekopfgruppe wurden vier anionische biobasierte Tenside aus 4-Vinylguaiacol und Bromdecansäuremethylester synthetisiert. Die synthetisierten Tenside wurden mittels NMR und Massenspektrometrie charakterisiert. Die oberflächenaktiven Eigenschaften wie die Oberflächenspannung, die Benetzungsfähigkeit, die Schaumcharakteristika, die Emulsionsstabilität und die Calciumtoleranz wurden untersucht und mit denen von Natriumlaurylsulfat (SLS) verglichen. Exzellente Emulionsstabilitäten und Calciumtoleranzen wurden für diese Tenside bestimmt. Die Tenside zeigten eine im Vergleich zu konventionellen Tensiden geringere kritische Mizellenbildungskonzentration. Die Mizellisierungseigenschaften der Bulklösungen wurden mit der dynamischen Lichtstreuung und der Fluoreszenzanisotropie untersucht. Antimikrobielle und zytotoxische Studien wurden auch durchgeführt.


*Correspondence address, Dr. Rati Ranjan Nayak, Centre for Lipid Research, Indian Institute of Chemical Technology, Hyderabad 500007, India, Tel.: (91)-40-27191838, Fax: (91)-40-27193370, E-Mail:

Prabhakara Rao Darapureddi is a Senior Research Fellow (SRF) at the Centre for Lipid Research, CSIR-Indian Institute of Chemical Technology, Hyderabad, India. His doctoral research work is on “Studies on surface and micellar properties of bio-based surfactants”.

Bijari Anil Kumar is a Senior Research Fellow (SRF) at the Centre for Lipid Research, CSIR-Indian Institute of Chemical Technology, Hyderabad, India. His doctoral research work is on low molecular weight organogel.

Shruti S Deshpande and Koude Dhevendar are working in Biology division, CSIR-Indian Institute of Chemical Technology, Hyderabad, India as summer project trainee under Dr Sunil Misra.

Sunil Misra received his Ph.D in Zoology from Berhampur University, Berhampur, India. Presently he is working as Senior Scientist at Biology Division, CSIR-Indian Institute of Chemical Technology, Hyderabad, India. His research interest is in genetic toxicology.

Rati Ranjan Nayak received his Ph.D. in organic chemistry from Utkal University, Bhubaneswar, India. Presently he is working as Scientist at Centre for Lipid Research, CSIR-Indian Institute of Chemical Technology, Hyderabad, India. His research interest is in surfactants and nano-emulsions.


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Received: 2016-03-01
Accepted: 2016-06-04
Published Online: 2017-01-06
Published in Print: 2017-01-20

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