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Synergistic Effects Between Sulfo-betain Zwitterionic Surfactant and Alcohol Ether Sulfate

  • Zhang Zhang , Zhu Ri-Li , Dong Bin and Zhang Zhen-Xian
Published/Copyright: November 7, 2013
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Tenside Surfactants Detergents
From the journal Tenside Surfactants Detergents Volume 50 Issue 6

Abstract

Two mixture solutions consisting of sulfo-betain zwitterionic surfactant and alcohol ether sulfate (AES) are designed and prepared; their surface tensions and critical micelle concentrations (cmc) with different mole ratio are determined by surface tensions scanning. With pseudo-regular solution theory, the interaction parameters in the micelle (βm) and at the surface (βσ) are evaluated. As the results reveal two different mixtures of sulfobetaine-(I)/AES and sulfobetaine-(II)/AES show good synergistic behaves in both surface tension reduction effectiveness/efficiency and mixed micelle formation at all mole fractions investigated.

Kurzfassung

Zwei Mischungen aus zwitterionischen Sulfobetaintensiden und Alkoholethersulfaten (AES) wurden entworfen und hergestellt. Ihre Oberflächenspannungen und kritische Mizellbildungskonzentrationen (cmc) bei unterschiedlichen Molverhältnissen wurden mit einem Grenzflächenspannungsscan bestimmt. Mit der Pseudo-regulären Lösungstheorie wurden die Wechselwirkungsparameter in der Mizelle (βm) und an der Grenzfläche (βσ) berechnet. Die Ergebnisse zeigen, dass zwei unterschiedliche Mischungen aus Sulfobetain-(I)/AES und Sulfobetain-(II)/AES gute synergistische Verhaltensweisen aufweisen sowohl bei dem Vermögen, die Oberflächenspannung zu reduzieren, als auch bei der Bildung von Mischmizellen mit allen untersuchten Molenbrüchen.

Key words:: Synergistic effect; interaction parameters; sulfo-betaine; zwitterionic surfactant
Stichwörter:: Synergistischer Effekt; Wechselwirkungsparameter; Sulfobetaine; zwitterionisches Tensid
1Dr. Zhang Zhang, Department of Chemical Engineering & Technology, Shanghai University, Shanghai 200444, P.R. China, Tel. and Fax: +86-021-66137721, E-Mail:

Zhang Zhang, male, PhD on applied chemistry, an associate professor of the Department of Chemical Engineering and Technology of Shanghai University, Shanghai, China. Main research areas are applied chemistry and green chemical technology.

Zhu Ri-Li, female, a post-graduate of the Department of Chemical Engineering and Technology of Shanghai University, Shanghai, China. Main research area is synthesis of new surfactants and study on their surface properties.

Dong Bin, female, a post-graduate of the Department of Chemical Engineering and Technology of Shanghai University, Shanghai, China. Main research area is synthesis of new surfactants and study on their surface properties.

Zhang Zhen-Xian, female, a post-graduate of the Department of Chemical Engineering and Technology of Shanghai University, Shanghai, China. Main research area is synthesis of new surfactants.

Chen Jie, male, PhD, a professor of the Department of Chemical Engineering and Technology of Shanghai University, Shanghai, China. Main research areas are applied chemistry and polymer.

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Received: 2013-02-01
Revised: 2013-03-21
Published Online: 2013-11-07
Published in Print: 2013-11-15

© 2013, Carl Hanser Publisher, Munich

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https://doi.org/10.3139/113.110276
Keywords for this article
Synergistic effect; interaction parameters; sulfo-betaine; zwitterionic surfactant

Articles in the same Issue

  1. Contents/Inhalt
  2. Contents
  3. Abstracts
  4. Abstracts
  5. Application
  6. Water-Dilutable Biocompatible Microemulsion Systems: Design and Characterisation
  7. Coal – Mycobacterium phlei Interaction and its Effect on Coal Cleaning
  8. Novel Surfactant
  9. Synthesis and Properties of N,N′-Bis(Sodium Lauryl Acyl Proyl Acid) Ethylenediamine
  10. Physical Chemistry
  11. Research of Surface Chemical Properties and Micellization Behavior of Sodium N-Lauroylglycine
  12. Synergistic Effects Between Sulfo-betain Zwitterionic Surfactant and Alcohol Ether Sulfate
  13. Research on the Emulsifying Ability of Surfactants in Crude Oil
  14. Selection of Promoter and Micellar Catalyst for Chromic Acid Oxidation of Tartaric Acid in Aqueous Medium at Room Temperature
  15. Synthesis
  16. Oligomerization of Glycerol on Layered Sodium Silicate Catalysts
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