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Synthesis and Surface Properties of Novel Gemini Surfactants

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Published/Copyright: April 5, 2013
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Tenside Surfactants Detergents
From the journal Tenside Surfactants Detergents Volume 49 Issue 5

Abstract

Novel Gemini surfactants containing amide group linkage were prepared with fatty acid, diamine and dihalide by simple organic reaction, and characterized with IR, and elemental analysis (EA). As the results show, the structures of the products obtained correspond to the target compounds designed. By surface tension scanning, these Gemini surfactants have excellent surface activity with low c.m.c. and surface tension, the lowest c.m.c value was 9.12 × 10−6 mol/L for surfactant Bi-18(4).

Kurzfassung

Es wurden neue Geminitenside, die eine Amidgruppe als Verbindungsgruppe besitzen, in einer einfachen organischen Reaktion aus Fettsäure, Diamin und Dihalogenid präpariert. Sie wurden mit IR-Spektrometrie und Elementaranalyse charakterisiert. Wie die Ergebnisse zeigen, entsprechen die Strukturen der erhaltenen Produkte denen der Zielprodukte. Das Scanning der Oberflächenspannung lieferte, dass diese Geminitenside eine hervorragende Oberflächenaktivität besitzen, was aus der niedrigen c.m.c. und Oberflächenspannung deutlich wird. Der niedrigste c.m.c.-Wert beträgt 9.12 × 10−6 mol/L für das Tensid Bi-18(4).

Key words:: Gemini surfactant; cationic surfactant; dimeric surfactant; interfacial tension
Stichwörter:: Geminitensid; kationisches Tensid; dimeres Tensid; Oberflächenspannung
∗ PhD. Zhang Zhang, Department of Chemical Engineering and Technology of Shanghai UniversityNo. 333, Nan-Chen road, Shanghai 200444, P.R. China, Tel.: 0086-021-66137721, Fax: 0086-021-66137721, E-Mail:

Zhang Zhang (Corresponding Author): male, PhD on applied chemistry, an associate professor of the Department of Chemical Engineering and Technology of Shanghai University, Shanghai, China. Main research areas are applied chemistry and green chemical technology.

Zhang Zhen-Xian: Female, a post-graduate of the Department of Chemical Engineering and Technology of Shanghai University, Shanghai, China. Main research area is synthesis of new surfactants.

Liu Yu-rong: male, a post-graduate of the Department of Chemical Engineering and Technology of Shanghai University, Shanghai, China. Main research area is synthesis of new surfactants.

Chen Jie: male, PhD, a professor of the Department of Chemical Engineering and Technology of Shanghai University, Shanghai, China. Main research areas are applied chemistry and polymer.

Zhang Yu: male, BS, undergraduate of the Department of Chemical Engineering and Technology of Shanghai University, Shanghai, China. Main research area is determination of new surfactants.

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Received: 2011-09-26
Revised: 2012-06-16
Published Online: 2013-04-05
Published in Print: 2012-09-01

© 2012, Carl Hanser Publisher, Munich

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  16. Fluorescent-Tagged Double-Hydrophilic Block Copolymer as a Green Inhibitor for Calcium Carbonate Scales
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https://doi.org/10.3139/113.110211
Keywords for this article
Gemini surfactant; cationic surfactant; dimeric surfactant; interfacial tension

Articles in the same Issue

  1. Contents/Inhalt
  2. Contents
  3. Abstracts
  4. Abstracts
  5. Application
  6. Troubles with the Solution: Fabric Softeners and Odour Properties
  7. Micellar Catalysis on 1,10-Phenanthroline Promoted Chromic Acid Oxidation of Glycerol in Aqueous Media
  8. Environmental Chemistry
  9. Kinetics, Equilibrium, and Isotherm of the Adsorption of Chlorine by TDRP
  10. Removal of Synthetic Organic Foulants by Granular Activated Carbon Filters and Ultrafiltration Membrane
  11. Physical Chemistry
  12. Effect of Temperature and Added Counter Ions on Micelle Formation of Guanidine Surfactants
  13. Effect of Molecular Structure on Interfacial Activity and Emulsification Property
  14. Synthesis
  15. Synthesis and Emulsification Properties of Organosilicone Modified Sodium Sulfonate of Alkanolamide Succinic Acid Monoester with Palm Oil
  16. Fluorescent-Tagged Double-Hydrophilic Block Copolymer as a Green Inhibitor for Calcium Carbonate Scales
  17. Synthesis and Surface Properties of Novel Gemini Surfactants
  18. Review
  19. Alkyl Poly Glucosides (APGs) Surfactants and Their Properties: A Review
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