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Determination of Heavy Metals in Domestic, Commercial and Industrial Soot Samples

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Published/Copyright: April 5, 2013
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Abstract

The heavy metals such as manganese (Mn), cadmium (Cd), zinc (Zn), chromium (Cr), lead (Pb), nickel (Ni), copper (Cu) and iron (Fe) were determined in domestic, commercial and industrial soot samples via atomic absorption spectrophotometer. The vehicle soot samples showed highest concentration of investigated heavy metals as compared to other soot samples. It was also found that the concentration of Fe was high in the soot samples (range 5.75–1105 mg/Kg) followed by Cu (70–990 mg/Kg) while the concentration of Ni was lower (range 0.5–3 mg/Kg). It was also found that the concentration of Mn and Fe was decreased as decreased the size of the soot samples while the concentration of other investigated heavy metals increased as decreased the size fraction.

Kurzfassung

Schwermetalle wie Mangan (Mn), Cadmium (Cd), Zink (Zn), Chrom (Cr), Blei (Pb), Nickel (Ni), Kupfer (Cu) und Eisen (Fe) wurden in Rußproben aus Haushalten, Handel und Industrie mittels Atomadsorptionsspektrometrie bestimmt. Von allen untersuchten Rußproben wiesen die Rußproben von Fahrzeugen die höchsten Konzentrationen der untersuchten Schwermetalle auf. Es wurde auch gefunden, dass die Eisenkonzentration (Bereich: 5,75–1105 mg/kg) in den Rußproben hoch war, gefolgt von Kupfer (Bereich 70–990 mg/kg), wohingegen die Nickelkonzentration (0,5–3 mg/kg) geringer war. Die Konzentration von Mangan und Eisen nahm ab, wenn die Partikelgröße in den Proben abnahm, während die Konzentration der anderen untersuchten Schwermetalle mit abnehmender Partikelgröße anstieg.


Prof. Khalid Saeed, Department of Chemistry, University of Malakand, Chakdara, Dir (L), Khyber Pukhtoonkhwa, Pakistan, E-Mail:

Dr. Yousaf Iqbal received his M.Sc. in 1979 from Department of Chemistry, University of Peshawar and M Phil from the same department in 1983. He went to UK for MS program and completed his MS studies in 1989. He got his PhD in 1997 from Department of Chemistry, University of Peshawar. Currently, he is working as full professor in Institute of Chemical Sciences, University of Peshawar. His research work focuses on the adsorption of Toxic materials using activated carbon and removal/investigation of toxic organic and inorganic materials in drinking and waste water.

Dr. Khalid Saeed completed his M.Sc. and M. Phil from Department of Chemistry, University of Peshawar in 2001 and 2004, respectively. He received his PhD in 2008, from Department of Polymer Science, Kyungpook National University, South Korea. At present he is working as assistant professor in Department of Chemistry. His current research work focuses on preparation of CNT/polymer nanocomposites, Electrospun nanofibers and Polymer Blend, and adsorption of Toxic materials using different adsorbents.

Dr. Imtiaz Ahamd received his M.Sc. in 1989 from Department of Chemistry (Fuel technology), University of Peshawar and PhD from the same department in 1999. Presently he is working as full professor in Institute of Chemical Sciences, University of Peshawar. His research work focuses on Coal, Petroleum, and removal/investigation of toxic organic and inorganic materials in drinking and waste water.

Mr. Syed Muhammad Sohail completed his M. Sc in 2001 from Department of Chemistry, University of Peshawar and M Phil 2009 from the same Department. Currently he is working as a lecturer in Department of Chemistry, Edward College, Peshawar.


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Received: 2011-07-19
Revised: 2012-03-02
Published Online: 2013-04-05
Published in Print: 2012-07-01

© 2012, Carl Hanser Publisher, Munich

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